Quantification of peatland water storage capacity using the water table fluctuation method

Peat specific yield (S_Y) is an important parameter involved in many peatland hydrological functions such as flood attenuation, baseflow contribution to rivers, and maintaining groundwater levels in surficial aquifers. However, general knowledge on peatland water storage capacity is still very limited, due in part to the technical difficulties related to in situ measurements. The objectives of this study were to quantify vertical S_Y variations of water tables in peatlands using the water table fluctuation (WTF) method and to better understand the factors controlling peatland water storage capacity. The method was tested in five ombrotrophic peatlands located in the St. Lawrence Lowlands (southern Québec, Canada). In each peatland, water table wells were installed at three locations (up‐gradient, mid‐gradient, and down‐gradient). Near each well, a 1‐m long peat core (8 cm × 8 cm) was sampled, and subsamples were used to determine S_Y with standard gravitational drainage method. A larger peat sample (25 cm × 60 cm × 40 cm) was also collected in one peatland to estimate S_Y using a laboratory drainage method. In all sites, the mean water table depth ranged from 9 to 49 cm below the peat surface, with annual fluctuations varying between 15 and 29 cm for all locations. The WTF method produced similar results to the gravitational drainage experiments, with values ranging between 0.13 and 0.99 for the WTF method and between 0.01 and 0.95 for the gravitational drainage experiments. S_Y was found to rapidly decrease with depth within 20 cm, independently of the within‐site location and the mean annual water table depth. Dominant factors explaining S_Y variations were identified using analysis of variance. The most important factor was peatland site, followed by peat depth and seasonality. Variations in storage capacity considering site and seasonality followed regional effective growing degree days and evapotranspiration patterns. This work provides new data on spatial variations of peatland water storage capacity using an easily implemented method that requires only water table measurements and precipitation data.     

Laboratory simulations of prebiotic molecule stability in the jarosite mineral group; end member evaluation of detection and decomposition behavior related to Mars sample return

Recently, the prebiotic amino acid glycine has been found associated with natural jarosite samples from locations around the world. Since the discovery of jarosite on Mars, extensive research focuses on linking this mineral group with possible detection of biosignatures in the geologic record on Earth and Mars. Multiple analytical methods, including extraction and mass spectrometry techniques, have identified glycine and other biomolecules in jarosite samples. The jarosite end members jarosite (sensu stricto-potassium jarosite), natrojarosite (sodium jarosite), and ammoniojarosite (ammonium jarosite) have different thermodynamic stabilities, decompose at different rates, and have potentially different susceptibilities to substitution. The relationship between the thermodynamic stability of the jarosite end members and the effect that glycine has on the thermal decomposition behavior of each end member was investigated using thermal gravimetric analysis. Introducing glycine into the synthesis procedure (75 ppm) of the potassium, sodium, and ammonium jarosite end member has elucidated the effects that glycine has on the thermal stability of the mineral group. Potassium jarosite appears to be the least susceptible to the effects of glycine, with the sodium and ammonium end members showing marked changes in thermal decomposition behavior and decomposition rates. These results suggest that the sodium and ammonium jarosites are more suitable targets for identifying signs of prebiotic or biotic activity on Mars and Earth than the potassium jarosites. These results have implications for current in situ investigations of the martian surface and future sample return missions.     

Transport of elemental mercury in the unsaturated zone from a waste disposal site in an arid region

Mercury contained in buried landfill waste may be released via upward emission to the atmosphere or downward leaching to groundwater. Data from the US Geological Survey’s Amargosa Desert Research Site (ADRS) in arid southwestern Nevada reveal another potential pathway of Hg release: long-distance (10² m) lateral migration of elemental Hg (Hg⁰) through the unsaturated zone. Gas collected from multiple depths from two instrumented boreholes that sample the entire 110-m unsaturated zone thickness and are located 100 and 160 m away from the closest waste burial trench exhibit gaseous Hg concentrations of up to 33 and 11 ng m⁻³, respectively. The vertical distribution of gaseous Hg in the borehole closest to the disposal site shows distinct subsurface peaks in concentration at depths of 1.5 and 24 m that cannot be explained by radial diffusive transport through a heterogeneous layered unsaturated zone. The inability of current models to explain gaseous Hg distribution at the ADRS highlights the need to advance the understanding of gas-phase contaminant transport in unsaturated zones to attain a comprehensive model of landfill Hg release.     

A Borehole Test for Chlorinated Solvent Diffusion and Degradation Rates in Sedimentary Rock

We present a new field measurement and numerical interpretation method (combined termed “test”) to parameterize the diffusion of trichloroethene (TCE) and its biodegradation products (DPs) from the matrix of sedimentary rock. The method uses a dual-packer system to interrogate a low-permeability section of the rock matrix adjacent to a previously contaminated borehole and uses the borehole monitoring history to establish the pretest condition. TCE and its DPs are removed from the groundwater between the packers at the onset of the testing. The parameters estimated by fitting a radial diffusion model to the concentration history and borehole concentration data, also termed back diffusion, are the tortuosity factor and sorption coefficients of TCE and DPs in the rock matrix and the TCE and DP biodegradation rate coefficients in the borehole. We demonstrate the equipment design and the interpretive method using a borehole accessing the gray mudstone at a TCE contaminated site in the Newark Basin. In this test, both nonreactive (bromide) and reactive (trichlorofluoroethene) tracers are used to constrain the estimated parameters; however, the bromide tracer was not needed to estimate the parameters in this test. The parameters estimated from the field test are consistent with values measured independently in laboratory experiments using field samples of similar lithology. From the interpretation, we compute the TCE and DP concentration distributions in the rock matrix prior to the test to illustrate how the results can be used to enhance understanding of contaminant distribution in the rock matrix.     

Predominant period and equivalent viscous damping ratio identification for a full‐scale building shake table test

The predominant period and corresponding equivalent viscous damping ratio, also known in various loading codes as effective period and effective damping coefficient, are two important parameters employed in the seismic design of base‐isolated and conventional building structures. Accurate determination of these two parameters can reduce the uncertainty in the computation of lateral displacement demands and interstory drifts for a given seismic design spectrum. This paper estimates these two parameters from data sets recorded from a full‐scale five‐story reinforced concrete building subjected to seismic base excitations of various intensities in base‐isolated and fixed‐base configurations on the outdoor shake table at the University of California, San Diego. The scope of this paper includes all test motions in which the yielding of the reinforcement has not occurred and the response can still be considered ‘elastic’. The data sets are used with three system identification methods to determine the predominant period of response for each of the test configurations. One of the methods also determines the equivalent viscous damping ratio corresponding to the predominant period. It was found that the predominant period of the fixed‐base building lengthened from 0.52 to 1.30 s. This corresponded to a significant reduction in effective system stiffness to about 16% of the original stiffness. The paper then establishes a correlation between predominant period and peak ground velocity. Finally, the predominant periods and equivalent viscous damping ratios recommended by the ASCE 7‐10 loading standard are compared with those determined from the test building. Copyright © 2017 John Wiley & Sons, Ltd.     

The influence of a season of extreme wet weather events on exposure of the World Heritage Area Great Barrier Reef to pesticides

The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times).     

Inter-annual variability of wet season freshwater plume extent into the Great Barrier Reef lagoon based on satellite coastal ocean colour observations

Riverine freshwater plumes are the major transport mechanism for nutrients, sediments and pollutants into the Great Barrier Reef (GBR) lagoon and connect the land with the receiving coastal and marine waters. Knowledge of the variability of the freshwater extent into the GBR lagoon is relevant for marine park management to develop strategies for improving ecosystem health and risk assessments. In this study, freshwater extent has been estimated for the entire GBR lagoon area from daily satellite observations of the Moderate Resolution Imaging Spectroradiometer (MODIS) between 2002 and 2010. To enable a reliable mapping of freshwater plumes we applied a physics-based coastal ocean colour algorithm, that simultaneously retrieves chlorophyll-a, non-algal particulate matter and coloured dissolved organic matter (CDOM), from which we used CDOM as a surrogate for salinity (S) for mapping the freshwater extent.     

Land, ethnic, and gender change: Transnational migration and its effects on Guatemalan lives and landscapes

Migration to the United States of America from Guatemala effects many aspects of Guatemalan life. We document, through extensive ethnographic fieldwork, how migrants and their remittances effect gender relations, ethnicity, land use, and land distribution. Our evidence is drawn from research in four communities. San Pedro Pinula and Gualán represent communities of eastern Guatemala. San Cristóbal Totonicapán is an Indigenous town in Guatemala’s western highlands, and San Lucas is a lowland frontier community in the Guatemalan department of Ixcán, which borders Chiapas, Mexico. Our results reveal that migrants and their remittances, both social and tangible, result in significant changes in land use and land distribution in Ixcán. Migrant money permits the conversion of rainforest into cattle pasture and also results in the accumulation of land in the hands of migrants. In terms of land use, we see in San Pedro Pinula that migrant money also allows the Pokoman Maya to make small entries into the Ladino (non-indigenous) dominated cattle business. In San Pedro Pinula, the migration and return of Maya residents also permits them to slowly challenge ethnic roles that have developed over the last five centuries. When we look at how migration effects gender roles in Gualán and San Cristóbal we also note that migration and social remittances permit a gradual challenge and erosion of traditional gender roles in Guatemala. We point out, however, that migration-related changes to traditional gender and ethnic roles is gradual because migrants, despite their increased earnings and awareness, run into a social structure that resists rapid change. This is not the case when we examine land transformations in Ixcán. Here, migrants encounter few barriers when they attempt to put their new money and ideas to work. Despite the advantages that migration brings to many families, especially in the face of a faltering national economy and state inactivity regarding national development, we conclude that migration and remittances do not result in community or nation-wide development. At this stage migrant remittances are used for personal advancement and very little money and effort is invested in works that benefit communities or neighborhoods. We call for continued studies of the effects of international migration on Guatemalan hometowns that build on our initial studies to better understand the longer-term ramifications of migration in a country where no community is without migrants.     

Splintered networks: The colonial and contemporary waters of Jakarta

This paper queries the relevance of the ‘splintering urbanism’ thesis to postcolonial cities of the South, and responds to calls for the production of a decentered theory of urbanization through a case study of Jakarta. Drawing on archival and interview data, the paper demonstrates that Jakarta has, since its inception, been characterized by a high degree of differentiation of access to water supply, and of fragmentation of water supply networks. We document the origins of this fragmentation in the colonial era, and trace the legacy of the colonial constructions within the postcolonial city. Moreover, we demonstrate that the introduction of private sector management (in 1988) has not significantly disrupted, and certainly not caused, this pattern. In short, we provide evidence to support our claim that Jakarta’s water supply system is ‘splintered’ rather than ‘splintering’, and demonstrate that this phenomenon was not caused by the rise (or fall) of the ‘modern infrastructural ideal’. In order to explain this sustained fragmentation of infrastructure and access, the paper develops a conceptual framework of postcolonial governmentality that emphasizes the interrelationship between materiality, governmentality, identity, and urbanization, in particular through demonstrating how contested and evolving process of social differentiation are linked to the differentiation of water supply infrastructures and of urban spaces. Although we are wary of any simplistic comparisons between the colonial past and present, we argue that the optic of postcolonial governmentality provides a powerful lens for dissecting the power relations that continue to structure access to water supply and urban space in cities in the South.