Multivariate statistical techniques applied to pisolitic laterite geochemistry at Golden Grove, Western Australia

Multivariate statistical procedures are applied to pisolitic laterite geochemistry in a study of the Golden Grove massive sulphide district. The objective is to optimize identification of geochemical anomalies caused by base metal mineral deposits.The statistical approach used in this paper depends upon geochemical data for appropriate reference groups (or training sets) being available. The target group consists of orientation data from pisolitic laterite about the Gossan Hill Cu-Zn massive sulphide deposit. A group representing background sequence was selected by combining three subareas in a geochemically quiet part of the prospective acid volcano-sedimentary sequence.A multi-element allocation procedure was set up using data from the reference groups. The exploration samples are then allocated, one sample at a time, to either one of the reference group categories, using the probability of group membership. A map showing the relative probability values for each sample site is the final product for interpretation, aided by ancillary use of an index of typicality.The allocation procedures were carried out using different element combinations, these being based on a procedure for subset selection to give maximum separation of reference groups, and on geochemical insight. Whilst many versions of the allocation procedure gave positive identification of the anomaly related to the blind Scuddles Cu-Zn deposit, allocation using only Cu, Pb, Zn and Ag did not. The results emphasize the importance of pathfinder elements in geochemical studies in weathered terrain.The allocation procedure using the most appropriate element combinations provided more positive identification of the main areas of known mineralization than had the previously used empirically derived methods of Smith and Perdrix (1983). The formal allocation procedure has the following additional advantages: results are not markedly affected by a very high value for any single element since robust procedures are incorporated into the analysis; better discrimination appears to be possible for weaker anomalies; separation of target from background can be optimized by formal calculations instead of by trial and error; and better suppression of background variation results.     

The difference between oceanic and continental tholeiites: a fluid dynamic explanation

Continental tholeiites have higher SiO₂, K₂O and light rare earth element contents and more evolved isotopic characteristics than their oceanic counterparts. These differences can be explained if the compositions of the parent magmas to both types of tholeiites are similar but if continental magmas assimilate significant amounts of continental crust en route to the surface. Although there is little doubt that most continental tholeiites have assimilated crustal material, the lcoation and mechanism of assimilation remain uncertain. Longhi (1981) has argued that magmas derived directly from the mantle should crystallize little orthopyroxene. The abundance of orthopyroxene in most continental layered intrusions suggests that they have crystallized from magmas which have assimilated continental crust. Since orthopyroxene is an early crystallizing phase in layered intrusions, this assimilation must occur early, before the magma enters the chamber. Assimilation can occur at the margins of the dykes which feed magma chambers, depending on the nature of the flow. If the flow is turbulent the high temperatures at the centre of the dyke will extend to the margins and the magma will erode the dyke walls. If the flow is laminar, a conductive profile develops at the margin and the flowing magma chills against the walls, protecting them from thermal erosion. The nature of flow in a dyke can be predicted from the Reynolds number, the criteria for turbulence. Reynolds number calculations suggest that the flow of primitive magmas in continental dykes will be fully turbulent and, if this is the case, assimilation of low melting point components in the walls of the dyke is inevitable. It is therefore suggested that many of the geochemical characteristics of continental tholeiites result from melting at the walls of dykes as primitive magmas ascend through the crust.     

The potential for agricultural land use change to reduce flood risk in a large watershed

Effects of agricultural land management practices on surface runoff are evident at local scales, but evidence for watershed‐scale impacts is limited. In this study, we used the Soil and Water Assessment Tool model to assess changes in downstream flood risks under different land uses for the large, intensely agricultural, Raccoon River watershed in Iowa. We first developed a baseline model for flood risk based on current land use and typical weather patterns and then simulated the effects of varying levels of increased perennials on the landscape under the same weather patterns. Results suggest that land use changes in the Raccoon River could reduce the likelihood of flood events, decreasing both the number of flood events and the frequency of severe floods. The duration of flood events were not substantially affected by land use change in our assessment. The greatest flood risk reduction was associated with converting all cropland to perennial vegetation, but we found that converting half of the land to perennial vegetation or extended rotations (and leaving the remaining area in cropland) could also have major effects on reducing downstream flooding potential. We discuss the potential costs of adopting the land use change in the watershed to illustrate the scale of subsidies required to induce large‐scale conversion to perennially based systems needed for flood risk reduction. Copyright © 2013 John Wiley & Sons, Ltd.     

Classifying coastal waters: Current necessity and historical perspective

Coastal ecosystems are ecologically and commercially valuable, productive habitats that are experiencing escalating compromises of their structural and functional integrity. The Clean Water Act (USC 1972) requires identification of impaired water bodies and determination of the causes of impairment. Classification simplifies these determinations, because estuaries within a class are more likely to respond similarly to particular stressors. We reviewed existing classification systems for their applicability to grouping coastal marine and Great Lakes water bodies based on their responses to aquatic stressors, including nutrients, toxic substances, suspended sediments, habitat alteration, and combinations of stressors. Classification research historically addressed terrestrial and freshwater habitats rather than coastal habitats. Few efforts focused on stressor response, although many well-researched classification frameworks provide information pertinent to stressor response. Early coastal classifications relied on physical and hydrological properties, including geomorphology, general circulation patterns, and salinity. More recent classifications sort ecosystems into a few broad types and may integrate physical and biological factors. Among current efforts are those designed for conservation of sensitive habitats based on ecological processes that support patterns of biological diversity. Physical factors, including freshwater inflow, residence time, and flushing rates, affect sensitivity to stressors. Biological factors, such as primary production, grazing rates, and mineral cycling, also need to be considered in classification. We evaluate each existing classification system with respect to objectives, defining factors, extent of spatial and temporal applicability, existing sources of data, and relevance to aquatic stressors. We also consider classification methods in a generic sense and discuss their strengths and weaknesses for our purposes. Although few existing classifications are based on responses to stressors, may well-researched paradigms provide important information for improving our capabilities for classification, as an investigative and predictive management tool.     

Hydrothermal pattern of frozen soil in Nam Co lake basin,the Tibetan Plateau

Hydrothermal processes and the regimes of frozen soil formed in alpine regions with glaciers and lake area are complex and important for ecological environment but have not been studied in Tibet. Based on soil temperature and moisture data from October 2005 to September 2006 collected in the Nam Co lake basin, Tibetan Plateau (TP), those questions were discussed. The mean annual air temperature was −3.4°C with 8 months below 0°C. Air and soil temperature varied between −25.3~13.1°C and −10.3~8.8°C, respectively. Soil moisture variations in the active layer were small with the minimum value of 1.4%, but were influenced greatly by snowmelt, rainfall and evaporation, varying up to 53.8%. The active layer froze later, thawed earlier and was thinner, however, the lower altitude limit of permafrost is higher than that in most areas of TP. The effects of soil moisture (unfrozen water content) on soil temperature, which were estimated through proposed models, were more significant near ground surface than the other layers. The surface soil temperature decreased with snowcover, the effect of cold snow meltwater infiltration on soil thermal conditions was negligible, however, the effect of rainfall infiltration was evident causing thermal disruptions.     

Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.     

Marine cements in mid-Tertiary cool-water shelf limestones of New Zealand and southern Australia

Large areas of southern Australia and New Zealand are covered by mid‐Tertiary limestones formed in cool‐water, shelf environments. The generally destructive character of sea‐floor diagenesis in such settings precludes ubiquitous inorganic precipitation of carbonates, yet these limestones include occasional units with marine cements: (1) within rare in situ biomounds; (2) within some stacked, cross‐bedded sand bodies; (3) at the top of metre‐scale, subtidal, carbonate cycles; and (4) most commonly, associated with certain unconformities. The marine cements are dominated by isopachous rinds of fibrous to bladed spar, interstitial homogeneous micrite and interstitial micropeloidal micrite, often precipitated sequentially in that order. Internal sedimentation of microbioclastic micrite may occur at any stage. The paradox of marine‐cemented limestone units in an overall destructive cool‐water diagenetic regime may be explained by the precipitation of cement as intermediate Mg‐calcite from marine waters undersaturated with respect to aragonite. In some of the marine‐cemented limestones, aragonite biomoulds may include marine cement/sediment internally, suggesting that dissolution of aragonite can at times be wholly marine and not always involve meteoric influences. We suggest that marine cementation occurred preferentially, but not exclusively, during periods of relatively lowered sea level, probably glacio‐eustatically driven in the mid‐Tertiary. At times of reduced sea level, there was a relative increase in both the temperature and the carbonate saturation state of the shelf waters, and the locus of carbonate sedimentation shifted towards formerly deeper shelf sites, which now experienced increased swell wave and/or tidal energy levels, fostering sediment abrasion and reworking, reduced sedimentation rates and freer exchange of sediment pore‐waters. Energy levels were probably also enhanced by increased upwelling of cold, deep waters onto the Southern Ocean margins of the Australasian carbonate platforms, where water‐mass mixing, warming and loss of CO₂ locally maintained critical levels of carbonate saturation for sea‐floor cement precipitation and promoted the phosphate‐glauconite mineralization associated with some of the marine‐cemented limestone units.     

Energy balance and transpiration from tussock grassland in New Zealand

The energy balance was measured for the dry canopy of narrow-leaved snow tussock (Chionochloa rigida), and measurements of transpiration were obtained from a large weighing lysimeter.Typical maximum summer transpiration rates of 0.21–0.43 mmhr^-1 (140–290 W m^-2) were recorded. The latent heat flux accounted for less than 40% of net radiation. The estimated value of the bulk stomatal resistance (r _ST) for 29 days was 158 s m^-1, and the decoupling parameter () was 0.17. Transpiration rates were not driven directly by net radiation, but were closely linked to the size of the regional saturation deficit imposed at the level of the canopy by efficient overhead mixing, and were constrained by a large bulk stomatal resistance. A linear relationship between r _ST and the saturation deficit is proposed as a realistic method for estimating transpiration for water yield studies of tussock catchments.     

Regional variations in cleavage and fold development in North Wales

The arcuate pattern of the main Caledonian cleavage and associated fold axial plane traces in North Wales is due partly to NW-SE compression with tectonic transport to the southeast against the concealed crop of the Tan y grisiau Microgranite. Low-angle cleavage close to the microgranite is shown to be a local variant of the regional cleavage formed during the main deformation and not an earlier phase as previously supposed. Transcurrent movements along several major fault systems are also related to compression around the microgranite and the Harlech Dome block.