The lattice energy of forsterite. Charge distribution and formation enthalpy of the SiO 4 4− ion

In the lattice energy expression of forsterite, based on a Born-Mayer (electrostatic+repulsive+dispersive) potential, the oxygen charge z _o, the hardness parameter ρ and the repulsive radii r _Mg and r _Si appear as unknown parameters. These were determined by calculating the first and second partial derivatives of the energy with respect to the cell edges, and equalizing them to quantities related to the crystal elastic constants; the overdetermined system of equations was solved numerically, minimizing the root-mean-square deviation. To test the results obtained, the SiO ₄ ^4? ion was assumed to move in the unit-cell, and the least-energy configuration was sought and compared with the experimental one. By combining the two methods, the optimum set of parameters was: z _o=?1.34, ρ=0.27 Å, r _Mg=0.72 Å, r _Si=0.64 Å. The values ?8565.12 and ?8927.28 kJ mol^?1 were obtained, respectively, for the lattice energy E _Land for its ionic component E _L ⁰ ,which accounts for interactions between Mg²⁺ and SiO ₄ ^4? ions only. The charge distribution calculated on the SiO ₄ ^4? ion was discussed and compared with other results. Using appropriate thermochemical cycles, the formation enthalpy and the binding energy of SiO ₄ ^4? were estimated to be: ΔH _f(SiO ₄ ^4? )=2117.6 and E(SiO ₄ ^4? )=708.6 kJ mol^?1, respectively.     

Statistical assessment of trends and oscillations in rainfall dynamics: Analysis of long daily Italian series

Since the 18th century systematic measurements of rainfall have been collected in Italy. The daily rainfall series observed in Milan (1835–2001), Genoa (1833–2000), Bologna (1813–2001) and Palermo (1797–1999) are examples of available long rainfall records. These data series can help analyzing the evolution of precipitation. The present paper deals with long term evolution of: (i) annual rainfall amount; (ii) annual number of rainy events; (iii) intensity of rainfall, (iv) inter-annual rainfall partitioning, i.e. the duration of wet and dry periods, and (v) maximum annual values of daily rainfall amount, duration of wet and dry periods. The evolution is studied analyzing the first two order statistics and the 30-year return period quantiles via moving window analysis. Confidence intervals are introduced to check the statistical significance of the estimated statistics and quantiles. The results are compared with those provided by the traditional Mann-Kendall test. The analysis shows how the annual precipitation exhibits a negative trend in the first half of 20th century, with a subsequent positive trend in northern Italy (Genoa, Milan and Bologna). Conversely, the dataset for Palermo (southern Italy) displays only a negative trend. Because the number of precipitation episodes is found to decrease in the investigated period, the average rain rate is significantly increasing especially in northern Italy. This is also associated with shorter duration of rain episodes with an evident effect on rainfall extremes. Dry periods tend to be longer with increasing variability. The Mann-Kendall test and its progressive form have shown to be well suited for monotonic trend, but the confidence interval analysis, introduced here, is more appropriate if oscillations are significant.     

Analysis with C- and X-band satellite SAR data of the Portalet landslide area

This paper describes the use of the Stable Point Network technique, a Persistent Scatterer Interferometry SAR technique, for the analysis of the Portalet landslide area (Central Pyrenees, Spain). For this purpose, different SAR datasets acquired by ERS-1, ERS-2, ENVISAT and TerraSAR-X satellites have been analysed. The use of different SAR images acquired by satellite radar sensors operating at different microwave lengths has allowed for a comparative assessment and illustration of the advantages and disadvantages of these satellites for landslide detection and monitoring. In the introduction, differential interferometry and the study area are briefly described. Then the specifics of the SPN processing and the results of the different datasets are described and compared. In Analysis of the results: the Portalet landslide area, the Portalet landslide area is introduced and the radar displacement measurements are analysed with available geo-information data. Additionally, X-band measurements are compared with those gathered by a ground-based SAR for a previous project. Finally, the most relevant conclusions of this work are discussed.     

Evaluation of the applicability of a fuzzy index of ecosystem integrity (FINE) to characterize the status of Tyrrhenian lagoons

The new index FINE, a multimetric, fuzzy-based index for the evaluation of environmental quality for Mediterranean transitional waters, was calculated using biotic data gathered between 2000 and 2006 at 15 stations in 4 Tyrrhenian transitional water ecosystems (Orbetello Lagoon, Padrongiano Delta, Stagno di S. Teodoro, and Stagno di Tortolì), i.e. in a different biogeographic sub-province respect to the one in which the index was developed and validated. The rationale of FINE is that certain attributes, selected on the basis of established principles of benthic ecology, are fundamental for lagoon ecosystem function. A set of other indices (Simpson's 1-lambda', the W-statistics, AMBI, and BOPA) was also calculated and compared to FINE outputs. FINE, 1-lambda', and the W-statistics were significantly correlated with sedimentary organic matter content. Some stations were unequivocally assigned to the same ecological status, independently from the index used; for others, some discrepancies were evident. Mediterranean transitional waters probably share ecosystem complexities which are not yet fully captured by indices developed and validated elsewhere.     

Neogene volcanic activity of western Syria and its relationship with Arabian plate kinematics

The Cenozoic (mostly Neogene) volcanic activity in Syria is part of the extensive magmatism that took place in the Mashrek Region, Middle East, from upper Eocene to Holocene (40–0.0005 Ma). Samples in western Syria are mostly high TiO₂ (TiO₂ 1.8–3.7 wt.%) alkaline mafic rocks (basanites, hawaiites and alkali basalts) plus rare transitional/tholeiitic basalts and basaltic andesites) with within-plate-like trace element signature.On the basis of incompatible trace element content, the volcanic activity in Syria has been divided into two stages: the first lasting from 25 to 5 Ma and the second from 5 to recent times. Indeed, the Syrian lavas show incompatible trace element content increasing with decreasing age from 25 to 5 Ma, followed by an abrupt decrease to low values roughly at the Miocene–Pliocene boundary. This temporal shift in composition is related to major tectonic re-organization occurred during upper Miocene.The proposed petrogenetic model invokes three steps: (a) passive upwelling of the shallow asthenosphere during the development of the Dead Sea transform fault system. Different degrees of partial melting were followed by variable extents of fractional crystallization and limited upper crustal contamination; (b) the Miocene–Pliocene boundary tectonic change enhanced passive decompression of the same sources and a consequent increase in degree of partial melting resulting in low incompatible trace element content of the relatively high-volume liquids; (c) after this phase, the incompatible trace element content in the basaltic magmas increased as consequence of fractional crystallization processes.Major and trace element content similarities with the rest of the circum-Mediterranean igneous rocks are consistent with a common relatively shallow origin for the Cenozoic anorogenic magmatism of the entire circum-Mediterranean area (the so-called Common Magmatic Reservoir). Because much of the igneous activity in the studied area is concentrated near the Dead Sea fault, the origin of Cenozoic magmatism in Syria (and in the rest of the circum-Mediterranean area) reflects a strong lithospheric control on the loci of partial melting. Mantle plumes from lower mantle and/or north-westward channelling of the Afar mantle plume is not needed to explain volcanic activity in Syria and the Mashrek area.     

Mesozoic to Tertiary tectonic history of the Mirdita ophiolites, northern Albania

Abstract In this paper, a summary of the tectonic history of the Mirdita ophiolitic nappe, northern Albania, is proposed by geological and structural data. The Mirdita ophiolitic nappe includes a subophiolite mélange, the Rubik complex, overlain by two ophiolite units, referred to as the Western and Eastern units. Its history started in the Early Triassic with a rifting stage followed by a Middle to Late Triassic oceanic opening between the Adria and Eurasia continental margins. Subsequently, in Early Jurassic time, the oceanic basin was affected by convergence with the development of a subduction zone. The existence of this subduction zone is provided by the occurrence of the supra‐subduction‐zone‐related magmatic sequences found in both the Western and Eastern units of the Mirdita ophiolitic nappe. During the Middle Jurassic, continuous convergence resulted in the obduction of the oceanic lithosphere, in two different stages – the intraoceanic and marginal stages. The intraoceanic stage is characterized by the westward thrusting of a young and still hot section of oceanic lithosphere leading to the development of a metamorphic sole. In the Late Jurassic, the marginal stage developed by the emplacement of the ophiolitic nappe onto the continental margin. During this second stage, the emplacement of the ophiolites resulted in the development of the Rubik complex. In the Early Cretaceous, the final emplacement of the ophiolites was followed by the unconformable sedimentation of the Barremian–Senonian platform carbonate. From the Late Cretaceous to the Middle Miocene, the Mirdita ophiolitic nappe was translated westward during the progressive migration of the deformation front toward the Adria Plate. In the Middle to Late Miocene, a thinning of the whole nappe pile was achieved by extensional tectonics, while the compression was still active in the westernmost areas of the Adria Plate. On the whole, the Miocene deformations resulted in the uplift and exposition of the Mirdita ophiolites as observed today.     

Equilibrium isotopic fractionation in the kaolinite, quartz, water system: Prediction from first-principles density-functional theory

Isotopic fractionation factors for oxygen, hydrogen and silicon have been calculated using first-principles methods for the kaolinite, quartz, water (ice and gas water) system. Good agreement between theory and experiment is obtained for mineral-water oxygen isotope fractionation. This approach gives reliable results on isotopic fractionation factors as a function of temperature, within a relative precision of typically 5%. These calculations provide independent quantitative constraints on the internal fractionation of oxygen in kaolinite, the fractionation of silicon isotopes at equilibrium, or hydrogen fractionation between kaolinite and water. Calculated fractionation factors at 300 K are 12.5‰ for the kaolinite internal-fractionation of oxygen, and 1.6‰ for silicon fractionation between quartz and kaolinite.     

Water quality in the inshore Great Barrier Reef lagoon: Implications for long-term monitoring and management

Coastal and inshore areas of the Great Barrier Reef lagoon receive substantial amounts of material from adjacent developed catchments, which can affect the ecological integrity of coral reefs and other inshore ecosystems. A 5-year water quality monitoring dataset provides a 'base range' of water quality conditions for the inshore GBR lagoon and illustrates the considerable temporal and spatial variability in this system. Typical at many sites were high turbidity levels and elevated chlorophyll a and phosphorus concentrations, especially close to river mouths. Water quality variability was mainly driven by seasonal processes such as river floods and sporadic wind-driven resuspension as well as by regional differences such as land use. Extreme events, such as floods, caused large and sustained increases in water quality variables. Given the highly variable climate in the GBR region, long-term monitoring of marine water quality will be essential to detect future changes due to improved catchment management.     

Melted snow volume control in the snowmelt runoff model using a snow water equivalent statistically based model

Snowmelt is an important component of the river discharge in mountain environments. In the past 40 years, the snowmelt dynamics has been mostly evaluated using degree‐day‐based models like the snowmelt runoff model (SRM). This model has no control on the volume of the melting snow, even if SRM includes as data input the snow‐covered area. This lack explains why the application of SRM may lead to inaccurate snowmelt volume estimations, even if the discharge volumes are accurately reproduced. Here we introduce in SRM the control on the melted snow volume and consider it in the determination of SRM parameters. The total snow volume, accumulated at the end of winter season, is evaluated by a snow water equivalent statistically based model, SWE‐SEM, and used as an estimate of the melting snow during the summer season. The benefit derived from the introduction of the control on the melting snow volume was investigated in the Mallero basin (northern Italy) for the 2003 and 2004 snow melting seasons. The analysis compares the model's results adopting different parameter sets, both considering and ignoring the control on the melting snow volume. Copyright © 2011 John Wiley & Sons, Ltd.