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171.
Matteo Ardit Michele Dondi Marco Merlini Giuseppe Cruciani 《Physics and Chemistry of Minerals》2012,39(3):199-211
The structural variations along the solid solution Sr2−x
Ba
x
MgSi2O7 (0 ≤ x ≤ 2), combined to the high-pressure characterization of the two end-members, have been studied. A topological change from
the tetragonal (melilite-type) to the monoclinic (melilite-related) structure along the join Sr2MgSi2O7 (e.g., P[`4]21 m P\bar{4}2_{1} m )–Ba2MgSi2O7 (e.g., C2/c) occurs with a Ba content higher than 1.6 apfu. Favored in the crystallization from a melt, the tetragonal form has a tetrahedral
sheet topology exclusively based on five-membered rings, which provide a regular “4 up + 4 down” ligand arrangement. In contrast,
the melilite-related structure, favored by solid-state reaction synthesis, is made by alternating six- and four-membered tetrahedral
rings, which give an asymmetric arrangement of alternated “5 up + 3 down” and “3 up + 5 down” ligands around Sr or Ba. This
latter configuration is characterized by an additional degree of freedom with Ba polyhedra hosted in the interlayer with a
more irregular and compact coordination and longer Ba–O bond distances. Further insights into the relationships between the
two melilite typologies were achieved by investigating the in situ high-pressure behavior of these systems. The synchrotron
high-pressure experiments allowed to calculate the elastic moduli for the Sr melilite-type end-member and for the Ba monoclinic
polymorph (Sr2MgSi2O7: K
T0 = 107, K
a=b
= 121, and K
c
= 84 GPa; m-Ba2MgSi2O7: K
T0 = 85, K
a
= 96, K
b
= 72, and K
c
= 117 GPa) and compare them with those reported in the literature for ?kermanite (Ca2MgSi2O7). The results show that, although the volume of Ba polyhedron in tetragonal polymorphs is larger than in the monoclinic forms,
the interlayer compressibility is significantly lower in the former structures due to the occurrence of very short Ba–O distances.
This unfavored Ba environment also makes tetragonal Ba2MgSi2O7 a metastable phase at room conditions, possibly favored by high pressure. However, no phase transition occurs from monoclinic
to tetragonal form due to kinetic hindrance in reconstructing the sheet topology. 相似文献
172.
Michele Mattioli Marco Menichetti Alberto Renzulli Lorenzo Toscani Emma Salvioli-Mariani Pedro Suarez Alessandro Murroni 《International Journal of Earth Sciences》2014,103(3):901-928
The Canan area (Honduras) is characterized by a gold-bearing ore deposit that is associated with quartz-veined shear zones. Gold mineralization occurs in low-to medium-grade metamorphic host-rocks (graphitic and sericitic schists). Hydrothermal fluids, which are associated with the emplacement of Cretaceous-Tertiary granodioritic intrusions, are responsible for the formation of quartz veins and the hydrothermal alteration of wall-rocks. Three main altered zones have been detected in the wall-rocks as far as 150 cm from the quartz veins. The distal zone (up to 50-cm thick) contains quartz, chlorite and illite. The intermediate zone is the thickest (up to 80 cm) and is marked by quartz, muscovite, sulphides, kaolinite and native elements such as Au and Ag. The proximal zone, which is close to the quartz veins, is rather thin (up to 25 cm) and contains clay minerals, Al-oxides-hydroxides and sulphides. The transition from the distal to the proximal zone is accompanied by the enrichment of SiO2 and the depletion of all other major elements, except for Fe2O3(tot). Precious metals occur in the highest concentrations in the intermediate zone (Au up to 7.6 ppm and Ag up to 11 ppm). We suggest that gold was transported as a reduced sulphur complex and was precipitated from the hydrothermal solution by the reaction of the sulphur complexes with Fe2+ from the alteration of the mafic minerals of the host-rock. Fluid–wall-rock interactions seem to be the main cause of gold mineralization. Genetic relationships with a strike-slip fault system, hydrothermal alteration zones within the metamorphic wall-rocks, and an entire set of geochemical anomalies are consistent with orogenic-type gold deposits of the epizonal class. 相似文献
173.
The Euganean thermal basin, located in the Eastern Po plain (Italy), is one of the most important thermal districts of Italy (Euganean–Berician Thermal District). The presence of hot water in the basin has brought about its exploitation over time. The thermal area has been known since the Roman Empire and is still of crucial interest for the profitable use of its hydro-geological resources. For these reasons the water cycle of the thermal area has been thoroughly studied, in particular with regard to its chemical and hydrogeological properties. The effects of well pumping, such as subsidence and water temperature steadiness, have been monitored over time. In the present work, the Horizontal to Vertical Spectral Ratio (HVSR) single station microtremor technique was applied as a non-invasive geophysical tool for the characterization of a part of the Euganean–Berician thermal district involving the municipalities of Abano and Montegrotto towns. This study represents the first correlation between the results from microtremor geophysical surveys and the thermal basin geological structure, including remote sensing data and thermal well information. More than 50 HVSR measurements from single stations were collected and analysed, in close correlation with the vast amount of available borehole logs, well exploitation data and SAR interferometry measurements collected for the monitoring of land subsidence induced by thermal water pumping. The aim of the work was to evaluate the suitability of the microtremor technique for the preliminary characterization of a thermal basin, in terms of resonance properties of the alluvial deposits covering the rocky bedrock, evaluated by means of HVSR methods. HVSR results were interpreted in terms of regional geological setting and hydrogeological properties of the subsoil. Our field results confirmed the existence of significant correlations between the resonance behaviour of the basin determined by the HVSR technique and the geological structures, suggesting that single station measurements are a promising tool for creating a rapid and preliminary non-invasive contribution to the characterization of the geothermal basin. 相似文献
174.
Matteo Lelli Sergio Grassi Michele Amadori Fabrizio Franceschini 《Environmental Earth Sciences》2014,71(9):3907-3919
A detailed hydrogeochemical study of groundwater in the Cecina coastal plain (Livorno province, Italy) and its inner sectors was undertaken in 2008, as chemical analyses carried out on groundwater since 2006 have revealed Cr(VI) concentrations of up to 49 μg/L (well above the permissible limit of 5 μg/L). Ophiolite outcrops are present throughout the study area, and their fragments likely represent a significant portion of the existing multilayered aquifer skeleton. Waters delivered by the serpentinite outcrops have a typically Mg–HCO3 composition, whereas those of the coastal plain are prevailingly of the Ca/Mg–HCO3 type with significant Mg contents. Significant NO3 contamination characterises the studied coastal plain, and an interesting negative correlation exists between Cr(VI) and both NO3 and SO4 deriving from the widespread use of (NH4)2SO4 as a farm fertilizer. Chromium speciation calculations carried out using the EQ3NR code reveal that the prevailing Cr(VI) species in solution is CrO4 2?; however, CaCrO4° and MgCrO4° neutral complexes represent significant percentages (up to 42 %). These findings suggest that the mobility and consequently the bioavailability of Cr(VI) can be significantly enhanced by these neutral complexes, which are not considered to be affected by adsorption/desorption processes. The Cr(VI) source, investigated by means of the Mg/SiO2 molar ratio, seems to be represented mainly by Mg-bearing minerals of the chlorite group. Petrographic observations confirm the occurrence of this mineral group. The interaction between rainwater and the local serpentinite rock was simulated at different $P_{{{\text{CO}}_{ 2} }}$ and $P_{{{\text{O}}_{ 2} }}$ conditions by reaction path modelling using the EQ3/6 software package. $P_{{{\text{O}}_{ 2} }}$ was varied in accordance with the assumption that redox conditions are determined in part by NO3. Results are in good agreement with experimental data on spring waters and subordinately with data on some coastal plain groundwater, which plot in a rather wide $P_{{{\text{CO}}_{ 2} }}$ and $P_{{{\text{O}}_{ 2} }}$ field. Although the dissolved Cr content is mostly of natural origin, fertilization may affect its fate. 相似文献
175.
Copper is currently the most common biocide in antifouling paints. Levels of this metal were measured in the water, particulate matter and sediments from a shellfish farming area in the Sacca di Goro (Northern Adriatic Sea) over one year. With respect to the 1980s, copper environmental level increased twofold. The release of copper from shellfish farmers' boats was also estimated to be > 250 kg Cu y(-1). Clams Tapes philippinarum were collected in the same area and seasonally exposed to a sublethal (10 microg Cu l(-1)) concentration of copper. Physiological traits were significantly affected by copper exposure (scope for growth declined as a result of reduced clearance rate, increased oxygen consumption and a generally lower absorption efficiency). The results of this study are cause for concern for shellfish farming activities at least in Northern Adriatic, where shellfish farming is a monoculture of T. philippinarum. A strict interpretation of the precautionary principle might suggest that more rigorous regulatory action to control copper inputs in the field would be justified. 相似文献
176.
Jesús Falcón-Barroso Roland Bacon Martin Bureau Michele Cappellari Roger L. Davies P. T. de Zeeuw Eric Emsellem Kambiz Fathi Davor Krajnovi Harald Kuntschner Richard M. McDermid Reynier F. Peletier Marc Sarzi 《Monthly notices of the Royal Astronomical Society》2006,369(2):529-566
We present observations of the stellar and gas kinematics for a representative sample of 24 Sa galaxies obtained with our custom-built integral-field spectrograph SAURON operating on the William Herschel Telescope. The data have been homogeneously reduced and analysed by means of a dedicated pipeline. All resulting data cubes were spatially binned to a minimum mean signal-to-noise ratio of 60 per spatial and spectral resolution element. Our maps typically cover the bulge-dominated region. We find a significant fraction of kinematically decoupled components (12/24), many of them displaying central velocity dispersion minima. They are mostly aligned and co-rotating with the main body of the galaxies, and are usually associated with dust discs and rings detected in unsharp-masked images. Almost all the galaxies in the sample (22/24) contain significant amounts of ionized gas which, in general, is accompanied by the presence of dust. The kinematics of the ionized gas are consistent with circular rotation in a disc co-rotating with respect to the stars. The distribution of mean misalignments between the stellar and gaseous angular momenta in the sample suggests that the gas has an internal origin. The [O iii ]/Hβ ratio is usually very low, indicative of current star formation, and shows various morphologies (ring-like structures, alignments with dust lanes or amorphous shapes). The star formation rates (SFRs) in the sample are comparable with that of normal disc galaxies. Low gas velocity dispersion values appear to be linked to regions of intense star formation activity. We interpret this result as stars being formed from dynamically cold gas in those regions. In the case of NGC 5953, the data suggest that we are witnessing the formation of a kinematically decoupled component from cold gas being acquired during the ongoing interaction with NGC 5954. 相似文献
177.
Douglas C. Heggie Michele Trenti Piet Hut 《Monthly notices of the Royal Astronomical Society》2006,368(2):677-689
In order to interpret the results of complex realistic star cluster simulations, which rely on many simplifying approximations and assumptions, it is essential to study the behaviour of even more idealized models, which can highlight the essential physical effects and are amenable to more exact methods. With this aim, we present the results of N -body calculations of the evolution of equal-mass models, starting with primordial binary fractions of 0–100 per cent, with values of N ranging from 256 to 16 384. This allows us to extrapolate the main features of the evolution to systems comparable in particle number with globular clusters.
In this range, we find that the steady-state 'deuterium main sequence' is characterized by a ratio of the core radius to half-mass radius that follows qualitatively the analytical estimate by Vesperini & Chernoff, although the N dependence is steeper than expected. Interestingly, for an initial binary fraction f greater than 10 per cent, the binary heating in the core during the post-collapse phase almost saturates (becoming nearly independent of f ), and so little variation in the structural properties is observed. Thus, although we observe a significantly lower binary abundance in the core with respect to the Fokker–Planck simulations by Gao et al., this is of little dynamical consequence.
At variance with the study of Gao et al., we see no sign of gravothermal oscillations before 150 half-mass relaxation times. At later times, however, oscillations become prominent. We demonstrate the gravothermal nature of these oscillations. 相似文献
In this range, we find that the steady-state 'deuterium main sequence' is characterized by a ratio of the core radius to half-mass radius that follows qualitatively the analytical estimate by Vesperini & Chernoff, although the N dependence is steeper than expected. Interestingly, for an initial binary fraction f greater than 10 per cent, the binary heating in the core during the post-collapse phase almost saturates (becoming nearly independent of f ), and so little variation in the structural properties is observed. Thus, although we observe a significantly lower binary abundance in the core with respect to the Fokker–Planck simulations by Gao et al., this is of little dynamical consequence.
At variance with the study of Gao et al., we see no sign of gravothermal oscillations before 150 half-mass relaxation times. At later times, however, oscillations become prominent. We demonstrate the gravothermal nature of these oscillations. 相似文献
178.
Francisco Javier Hern��ndez-Molina Dorrik A. V. Stow Estefan��a Llave Michele Rebesco Gemma Ercilla David Van Rooij Anxo Mena Juan-Tom��s V��zquez Antje H. L. Voelker 《Geo-Marine Letters》2011,31(5-6):285-300
Deep-water circulation is a critical part of the global conveyor belt that regulates Earth??s climate. The bottom (contour)-current component of this circulation is of key significance in shaping the deep seafloor through erosion, transport, and deposition. As a result, there exists a high variety of large-scale erosional and depositional features (drifts) that together form more complex contourite depositional systems on continental slopes and rises as well as in ocean basins, generated by different water masses flowing at different depths and at different speeds either in the same or in opposite directions. Yet, the nature of these deep-water processes and the deposited contourites is still poorly understood in detail. Their ultimate decoding will undoubtedly yield information of fundamental importance to the earth and ocean sciences. The international congress Deep-water Circulation: Processes & Products was held from 16?C18 June 2010 in Baiona, Spain, hosted by the University of Vigo. Volume 31(5/6) of Geo-Marine Letters is a special double issue containing 17 selected contributions from the congress, guest edited by F.J. Hernández-Molina, D.A.V. Stow, E. Llave, M. Rebesco, G. Ercilla, D. Van Rooij, A. Mena, J.-T. Vázquez and A.H.L. Voelker. The papers and discussions at the congress and the articles in this special issue provide a truly multidisciplinary perspective of interest to both academic and industrial participants, contributing to the advancement of knowledge on deep-water bottom circulation and related processes, as well as contourite sedimentation. The multidisciplinary contributions (including geomorphology, tectonics, stratigraphy, sedimentology, paleoceanography, physical oceanography, and deep-water ecology) have demonstrated that advances in paleoceanographic reconstructions and our understanding of the ocean??s role in the global climate system depend largely on the feedbacks among disciplines. New insights into the link between the biota of deep-water ecosystems and bottom currents confirm the need for this field to be investigated and mapped in detail. Likewise, it is confirmed that deep-water contourites are not only of academic interest but also potential resources of economic value. Cumulatively, both the congress and the present volume serve to demonstrate that the role of bottom currents in shaping the seafloor has to date been generally underestimated, and that our understanding of such systems is still in its infancy. Future research on contourites, using new and more advanced techniques, should focus on a more detailed visualization of water-mass circulation and its variability, in order to decipher the physical processes involved and the associations between drifts and other common bedforms. Moreover, contourite facies models should be better established, including their associations with other deep-water sedimentary environments both in modern and ancient submarine domains. The rapid increase in deep-water exploration and the new deep-water technologies available to the oil industry and academic institutions will undoubtedly lead to spectacular advances in contourite research in terms of processes, morphology, sediment stacking patterns, facies, and their relationships with other deep-marine depositional systems. 相似文献
179.
Marco Brandano Michele Lustrino Irene Cornacchia Mario Sprovieri 《Geological Journal》2015,50(5):575-591
This work discusses and interprets the factors responsible for the Oligocene–Miocene drowning of the Central Apennine platform deposits, based on facies and stable‐isotope analyses of two representative stratigraphic sections. The Mediterranean carbonate platforms were affected during the Oligocene–Miocene boundary by a carbonate production crisis that was induced by global factors and amplified by regional events, such as volcanic activity. The positive δ13C shift observed in the studied sections corresponds to vertical facies changes reflecting the evolution from middle carbonate ramp to outer ramp‐hemipelagic depositional environments. This drowning event is recorded not only in the Apennine platforms, but also in other Mediterranean platforms such as in southern Apulia, Sicily and Malta, and outside the Mediterranean Basin. The ~24–23.5 Ma Mi‐1 glacial maximum may have had a significant influence on this drowning event because it was associated with high rates of accumulation of continent‐derived sediments. The increased continental weathering and runoff sustained high trophic conditions. These probably were a consequence of the Aquitanian–Burdigalian volcanic activity in the Central‐Western Mediterranean, that may have led to an increase in nutrient content in seawater and an increase in atmospheric and marine CO2 concentrations. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
180.