Amount and reactivity of dissolved organic matter export are affected by land cover change from old-growth to second-growth forests in headwater ecosystems

Headwater forest ecosystems of the western USA generate a large portion of the dissolved organic matter (DOM) transported in streams across North America. Land cover changes that alter forest structure and species composition affect the quantity and composition of DOM transferred to aquatic ecosystems. Clear-cut harvesting affects ~1% of the forest area of North America annually, leaving most western forests in varying stages of regrowth and the total area of old-growth forest is decreasing. The consequences of this widespread management practice on watershed carbon cycling remain unknown. We investigated the role of land cover change, because of clear-cut harvesting, from mixed-species old-growth to lodgepole pine-dominated second-growth forest on the character and reactivity of hillslope DOM exports. We evaluated inputs of DOM from litter leachates and export of DOM collected at the base of trenched hillslopes during a 3-year period (2016–2018) at the Fraser Experimental Forest in north-central Colorado, USA. Dissolved organic carbon and total dissolved nitrogen were higher in lateral subsurface flow draining old- versus second-growth forest. Fluorescence spectroscopy showed that the DOM exported from the old-growth forest was more heterogeneous and aromatic and that proteinaceous, microbially processed DOM components were more prevalent in the second-growth forest. Biological oxygen demand assays revealed much lower microbial metabolism of DOM in litter leachate and subsurface exports from the old-growth forest relative to second growth. Old-growth and second-growth forests are co-mingled in managed ecosystems, and our findings demonstrate that land cover change from a mixture of conifer species to lodgepole pine dominance influences DOM inputs that can increase the reactivity of DOM transferred from terrestrial to aquatic ecosystems.     

Quantification of fundamental frequency drop for unreinforced masonry buildings from dynamic tests

The knowledge of fundamental frequency and damping ratio of structures is of uppermost importance in earthquake engineering, especially to estimate the seismic demand. However, elastic and plastic frequency drops and damping variations make their estimation complex. This study quantifies and models the relative frequency drop affecting low‐rise modern masonry buildings and discusses the damping variations based on two experimental data sets: Pseudo‐dynamic tests at ELSA laboratory in the frame of the ESECMaSE project and in situ forced vibration tests by EMPA and EPFL. The relative structural frequency drop is shown to depend mainly on shaking amplitude, whereas the damping ratio variations could not be explained by the shaking amplitude only. Therefore, the absolute frequency value depends mostly on the frequency at low amplitude level, the amplitude of shaking and the construction material. The decrease in shape does not vary significantly with increasing damage. Hence, this study makes a link between structural dynamic properties, either under ambient vibrations or under strong motions, for low‐rise modern masonry buildings. A value of 2/3 of the ambient vibration frequency is found to be relevant for the earthquake engineering assessment for this building type. However, the effect of soil–structure interaction that is shown to also affect these parameters has to be taken into account. Therefore, an analytical methodology is proposed to derive first the fixed‐base frequency before using these results. Copyright © 2010 John Wiley & Sons, Ltd.     

Combining suspended sediment monitoring and fingerprinting to determine the spatial origin of fine sediment in a mountainous river catchment

An excess of fine sediment (grain size <2 mm) supply to rivers leads to reservoir siltation, water contamination and operational problems for hydroelectric power plants in many catchments of the world, such as in the French Alps. These problems are exacerbated in mountainous environments characterized by large sediment exports during very short periods. This study combined river flow records, sediment geochemistry and associated radionuclide concentrations as input properties to a Monte Carlo mixing model to quantify the contribution of different geologic sources to river sediment. Overall, between 2007 and 2009, erosion rates reached 249 ± 75 t km^?2 yr^?1 at the outlet of the Bléone catchment, but this mean value masked important spatial variations of erosion intensity within the catchment (85–5000 t km^?2 yr^?1). Quantifying the contribution of different potential sources to river sediment required the application of sediment fingerprinting using a Monte Carlo mixing model. This model allowed the specific contributions of different geological sub‐types (i.e. black marls, marly limestones, conglomerates and Quaternary deposits) to be determined. Even though they generate locally very high erosion rates, black marls supplied only a minor fraction (5–20%) of the fine sediment collected on the riverbed in the vicinity of the 907 km² catchment outlet. The bulk of sediment was provided by Quaternary deposits (21–66%), conglomerates (3–44%) and limestones (9–27%). Even though bioengineering works conducted currently to stabilize gullies in black marl terrains are undoubtedly useful to limit sediment supply to the Bléone river, erosion generated by other substrate sources dominated between 2007 and 2009 in this catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

An evaporated seawater origin for the ore-forming brines in unconformity-related uranium deposits (Athabasca Basin, Canada): Cl/Br and δCl analysis of fluid inclusions

Analyses of halogen concentration and stable chlorine isotope composition of fluid inclusions from hydrothermal quartz and carbonate veins spatially and temporally associated with giant unconformity-related uranium deposits from the Paleoproterozoic Athabasca Basin (Canada) were performed in order to determine the origin of chloride in the ore-forming brines. Microthermometric analyses show that samples contain variable amounts of a NaCl-rich brine (Cl concentration between 120,000 and 180,000 ppm) and a CaCl₂-rich brine (Cl concentration between 160,000 and 220,000 ppm). Molar Cl/Br ratios of fluid inclusion leachates range from ∼100 to ∼900, with most values between 150 and 350. Cl/Br ratios below 650 (seawater value) indicate that the high salinities were acquired by evaporation of seawater. Most δ³⁷Cl values are between −0.6‰ and 0‰ (seawater value) which is also compatible with a common evaporated seawater origin for both NaCl- and CaCl₂-rich brines.Slight discrepancies between the Cl concentration, Cl/Br, δ³⁷Cl data and seawater evaporation trends, indicate that the evaporated seawater underwent secondary minor modification of its composition by: (i) mixing with a minor amount of halite-dissolution brine or re-equilibration with halite during burial; (ii) dilution in a maximum of 30% of connate and/or formation waters during its migration towards the base of the Athabasca sandstones; (iii) leaching of chloride from biotites within basement rocks and (iv) water loss by hydration reactions in alteration haloes linked to uranium deposition.The chloride in uranium ore-forming brines of the Athabasca Basin has an unambiguous dominantly marine origin and has required large-scale seawater evaporation and evaporite deposition. Although the direct evidence for evaporative environments in the Athabasca Basin are lacking due to the erosion of ∼80% of the sedimentary pile, Cl/Br ratios and δ³⁷Cl values of brines have behaved conservatively at the basin scale and throughout basin history.     

The H<Subscript>2</Subscript>O solubility of alkali basaltic melts: an experimental study

Experiments were conducted to determine the water solubility of alkali basalts from Etna, Stromboli and Vesuvius volcanoes, Italy. The basaltic melts were equilibrated at 1,200°C with pure water, under oxidized conditions, and at pressures ranging from 163 to 3,842 bars. Our results show that at pressures above 1 kbar, alkali basalts dissolve more water than typical mid-ocean ridge basalts (MORB). Combination of our data with those from previous studies allows the following simple empirical model for the water solubility of basalts of varying alkalinity and fO₂ to be derived: \textH ₂ \textO( \textwt% ) = \text H ₂ \textO_\textMORB ( \textwt% ) + ( 5.84 ×10 ^{- 5} *\textP - 2.29 ×10 ^{- 2} ) ×( \textNa₂ \textO + \textK₂ \textO )( \textwt% ) + 4.67 ×10 ^{- 2} ×\Updelta \textNNO - 2.29 ×10 ^{- 1} {\text{H}}_{ 2} {\text{O}}\left( {{\text{wt}}\% } \right) = {\text{ H}}_{ 2} {\text{O}}_{\text{MORB}} \left( {{\text{wt}}\% } \right) + \left( {5.84 \times 10^{ - 5} *{\text{P}} - 2.29 \times 10^{ - 2} } \right) \times \left( {{\text{Na}}_{2} {\text{O}} + {\text{K}}_{2} {\text{O}}} \right)\left( {{\text{wt}}\% } \right) + 4.67 \times 10^{ - 2} \times \Updelta {\text{NNO}} - 2.29 \times 10^{ - 1} where H₂O_MORB is the water solubility at the calculated P, using the model of Dixon et al. (1995). This equation reproduces the existing database on water solubilities in basaltic melts to within 5%. Interpretation of the speciation data in the context of the glass transition theory shows that water speciation in basalt melts is severely modified during quench. At magmatic temperatures, more than 90% of dissolved water forms hydroxyl groups at all water contents, whilst in natural or synthetic glasses, the amount of molecular water is much larger. A regular solution model with an explicit temperature dependence reproduces well-observed water species. Derivation of the partial molar volume of molecular water using standard thermodynamic considerations yields values close to previous findings if room temperature water species are used. When high temperature species proportions are used, a negative partial molar volume is obtained for molecular water. Calculation of the partial molar volume of total water using H₂O solubility data on basaltic melts at pressures above 1 kbar yields a value of 19 cm³/mol in reasonable agreement with estimates obtained from density measurements.     

An explanation for salinity- and SPM-induced vertical countergradient buoyancy fluxes

Measurements of turbulent fluctuations of velocity, salinity, and suspended particulate matter (SPM) are presented. The data show persistent countergradient buoyancy fluxes. These countergradient fluxes are controlled by the ratio of vertical turbulent kinetic energy (VKE) and available potential energy (APE) terms in the buoyancy flux equation. The onset of countergradient fluxes is found to approximately coincide with larger APE than VKE. It is shown here that the ratio of VKE to APE can be written as the square of a vertical Froude number. This number signifies the onset of the dynamical significance of buoyancy in the transport of mass. That is when motions driven by buoyancy begin to actively determine the vertical turbulent transport of mass. Spectral and quadrant analyses show that the occurrence of countergradient fluxes coincides with a change in the relative importance of turbulent energetic structures and buoyancy-driven motions in the transport of mass. Furthermore, these analyses show that with increasing salinity-induced Richardson number (Ri), countergradient contributions expand to the larger scales of motions and the relative importance of outward and inward interactions increases. At the smaller scales, at moderate Ri, the countergradient buoyancy fluxes are physically associated with an asymmetry in transport of fluid parcels by energetic turbulent motions. At the large scales, at large Ri, the countergradient buoyancy fluxes are physically associated with convective motions induced by buoyancy of incompletely dispersed fluid parcels which have been transported by energetic motions in the past. Moreover, these convective motions induce restratification and enhanced settling of SPM. The latter is generally the result of salinity-induced convective motions, but SPM-induced buoyancy is also found to play a role.     

Failure of dams arranged in series or in complex

A practical methodology has been developed for predicting flows generated by dam failures or malfunctions in a complex or a series of dams. A twofold approach is followed. First, the waves induced in the downstream reservoirs are computed, as well as hydrodynamic impacts induced on downstream dams and dikes are estimated. Second, the flood wave propagation and the inundation process are simulated in the downstream valley, accounting for possible dam collapse or breaching in cascade. Two complementary flow models are combined: a two-dimensional fully dynamic model and a simplified lumped model. At each stage, the methodology provides guidelines to select the most appropriate model for efficiently computing the induced flows. Both models handle parametric modeling of gradual dam breaching. The procedure also incorporates prediction of breach formation time and final width, as well as sensitivity analysis to compensate for the high uncertainties remaining in the estimation of breach parameters. The applicability of the modeling procedure is demonstrated for a case study involving a 70-m high-gravity concrete dam located upstream of four other dams.     

Evaluation of the regional climate model ALADIN to simulate the climate over North America in the CORDEX framework

In this study, an ensemble of four multi-year climate simulations is performed with the regional climate model ALADIN to evaluate its ability to simulate the climate over North America in the CORDEX framework. The simulations differ in their driving fields (ERA-40 or ERA-Interim) and the nudging technique (with or without large-scale nudging). The validation of the simulated 2-m temperature and precipitation with observationally-based gridded data sets shows that ALADIN performs similarly to other regional climate models that are commonly used over North America. Large-scale nudging improves the temporal correlation of the atmospheric circulation between ALADIN and its driving field, and also reduces the warm and dry summer biases in central North America. The differences between the simulations driven with different reanalyses are small and are likely related to the regional climate model’s induced internal variability. In general, the impact of different driving fields on ALADIN is smaller than that of large-scale nudging. The analysis of the multi-year simulations over the prairie and the east taiga indicates that the ALADIN 2-m temperature and precipitation interannual variability is similar or larger than that observed. Finally, a comparison of the simulations with observations for the summer 1993 shows that ALADIN underestimates the flood in central North America mainly due to its systematic dry bias in this region. Overall, the results indicate that ALADIN can produce a valuable contribution to CORDEX over North America.     

Electron density and temperature in the Io plasma torus from Ulysses thermal noise measurements

During the Ulysses flyby of Jupiter, the spacecraft crossed the outer part of the Io plasma torus along a basically North-to-South trajectory at a Jovicentric distance of about 8R_J. The quasi-thermal noise measured by the Unified Radio and Plasma Wave (URAP) experiment is used to deduce the electron density and temperature along the trajectory. The density is deduced from the upper hybrid frequency line and the temperature from the spin modulation of Bernstein waves. These results are used to build a simplified Gaussian model of the torus. The density profile is roughly symmetric with respect to the centrifugal equator, with a scale height of about 0.9R_J. The density at equator crossing is twice as large as that expected from the Divine-Garrett Voyager-based model at the same radial distance. The density scale height is lower than that found by Voyager 1; it is consistent with an ion temperature of about 5 × 10⁵K, assuming an effective mass of about 20 proton masses. The fitting of the pressure distribution, symmetric with respect to the centrifugal equator, yields a cold electron temperature of about 1.4 × 10⁵K at the equator, which is of the same order of magnitude as found by Voyager 1.