Evaluating crude oil chemical dispersion efficacy in a flow-through wave tank under regular non-breaking wave and breaking wave conditions

Testing dispersant effectiveness under conditions similar to that of the open environment is required for improvements in operational procedures and the formulation of regulatory guidelines. To this end, a novel wave tank facility was fabricated to study the dispersion of crude oil under regular non-breaking and irregular breaking wave conditions. This wave tank facility was designed for operation in a flow-through mode to simulate both wave- and current-driven hydrodynamic conditions. We report here an evaluation of the effectiveness of chemical dispersants (Corexit^® EC9500A and SPC 1000^™) on two crude oils (Medium South American [MESA] and Alaska North Slope [ANS]) under two different wave conditions (regular non-breaking and plunging breaking waves) in this wave tank. The dispersant effectiveness was assessed by measuring the water column oil concentration and dispersed oil droplet size distribution. In the absence of dispersants, nearly 8-19% of the test crude oils were dispersed and diluted under regular wave and breaking wave conditions. In the presence of dispersants, about 21-36% of the crude oils were dispersed and diluted under regular waves, and 42-62% under breaking waves. Consistently, physical dispersion under regular waves produced large oil droplets (volumetric mean diameter or VMD ? 300 μm), whereas chemical dispersion under breaking waves created small droplets (VMD ? 50 μm). The data can provide useful information for developing better operational guidelines for dispersant use and improved predictive models on dispersant effectiveness in the field.     

Recovery of interior brackish marshes seven years after the chalk point oil spill

Seven years after the April 2000 spill of 140,000 gallons of a mixture of No. 6 and No. 2 fuel oils in the Patuxent River, Maryland, heavily oiled brackish marshes showed continuing effects. Stem density and stem height were significantly lower in oiled versus unoiled sites for Spartina alterniflora but not Spartina cynosuroides habitats. In contrast, belowground biomass was significantly lower in S. cynosuroides habitats but not S. alterniflora habitats. Total PAH concentrations were up to 453 mg/kg in surficial soils (0-10 cm) and 2921 mg/kg with depth (10-20 cm). The oil had lost 22-76% of its initial PAH content after seven years, although the oil in marsh soils has undergone little to no additional weathering since Fall 2000. Based on amphipod acute toxicity tests and sediment quality guidelines, 25% of the soils in the marsh are expected to be toxic (ESB-TU_FCV values > 3.0; P_Max > 0.65).     

Widespread occurrence of aquifers currently undetectable with the MRS technique in the Grenville geological province, Canada

In the summer of 2003, a series of field tests were made over aquifers within or next to the Grenville geological province, Canada. Twelve sites distributed within three general areas of the province and nearby to its southern border were surveyed with the MRS (Magnetic Resonance Sounding) technique. Each site was characterized by saturated shallow water bearing layers of high effective porosity. The tests were planned to evaluate the MRS technology in such environments for groundwater resources quantification and aquifer/aquitard media characterization. A priori, the environmental conditions in Eastern Canada were assumed favorable for MRS work such as low to moderate ambient noise, earth's field value above 55,000 nT, targets consisting of shallow and high porosity aquifers. Despite such conditions, no clear MRS responses were observed. Following supplementary investigations, this is now attributed to the wide-scale occurrence of disseminated magnetite within the aquifers which shorten the signal decay time. Although the lack of MRS response over aquifers has been reported before, this was not the case for such widespread occurrence. This also supports the adaptation of the MRS technology to conditions similar to those observed in the Grenville province.     

Non-volatile vs volatile behaviours of halogens during the AD 79 plinian eruption of Mt. Vesuvius, Italy

Pre-eruptive conditions and degassing processes of the AD 79 plinian eruption of Mt. Vesuvius are constrained by systematic F and Cl measurements in melt inclusions and matrix glass of pumice clasts from a complete sequence of the pumice-fallout deposits. The entire ‘white pumice’ (WP) magma and the upper part of the ‘grey pumice’ (GP) magma were saturated relative to sub-critical fluids (a Cl-rich H₂O vapour phase and a brine), with a Cl melt content buffered at ~ 5300 ppm, and a mean H₂O content of ~ 5%. The majority of the GP magma was not fluid-saturated. From these results it can be estimated that the WP magma chamber had a low vertical extent (< 500 m) and was located at a depth of ~ 7.5 km while the GP magma reservoir was located just beneath the WP one, but its vertical extent cannot be constrained. This is approximately two times deeper than previous estimates. H₂O degassing during the WP eruption followed a typical closed-system evolution, whereas GP clasts followed a more complex degassing path. Contrary to H₂O, Cl was not efficiently degassed during the plinian phase of the eruption.

This study shows that F and Cl behave as incompatible elements in fluid-undersaturated phonolitic melts. H₂O saturation is necessary for a significant partitioning of Cl into the fluid phase. However, Cl cannot be extracted in significant quantity from phonolitic melts during rapid H₂O degassing, e.g. during plinian eruptions, due to kinetics effects. Halogen contents are better preserved in volcanic glass (melt inclusions or matrix glass) than H₂O, therefore the combined analysis of both volatile species is required for reliable determination of pre-eruptive conditions and syn-eruptive degassing processes in magmas stored at shallow depths.     

Paleomagnetism,magnetic fabric,and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of Pliocene and Quaternary ignimbrites in the Arequipa area,southern Peru

⁴⁰Ar/³⁹Ar ages and paleomagnetic correlations using characteristic remanent magnetizations (ChRM) show that two main ignimbrite sheets were deposited at 4.86 ± 0.07 Ma (La Joya Ignimbrite: LJI) and at 1.63 ± 0.07 Ma (Arequipa Airport Ignimbrite: AAI) in the Arequipa area, southern Peru. The AAI is a 20–100 m-thick ignimbrite that fills in the Arequipa depression to the west of the city of Arequipa. The AAI is made up of two cooling units: an underlying white unit and an overlying weakly consolidated pink unit. Radiometric data provide the same age for the two units. As both units record exactly the same well-defined paleomagnetic direction (16 sites in the white unit of AAI: Dec = 173.7; Inc = 31.2; α95 = 0.7; k = 2749; and 10 sites in the pink unit of AAI; Dec = 173.6; Inc = 30.3; α95 = 1.2; k = 1634), showing no evidence of secular variation, the time gap between emplacement of the two units is unlikely to exceed a few years. The >50 m thick well-consolidated white underlying unit of the Arequipa airport ignimbrite provides a very specific magnetic zonation with low magnetic susceptibilities, high coercivities and unblocking temperatures of NRM above 580°C indicating a Ti-poor titanohematite signature. The Anisotropy of Magnetic Susceptibility (AMS) is strongly enhanced in this layer with anisotropy values up to 1.25. The fabric delineated by AMS was not recognized neither in the field nor in thin sections, because most of the AAI consists in a massive and isotrope deposit with no visible textural fabric. Pumices deformation due to welding is only observed at the base of the thickest sections. AMS within the AAI ignimbrite show a very well defined pattern of apparent imbrications correlated to the paleotopography, with planes of foliation and lineation dipping often at more than 20° toward the expected vent, buried beneath the Nevado Chachani volcanic complex. In contrast with the relatively small extent of the thick AAI, the La Joya ignimbrite covers large areas from the Altipano down the Piedmont. Ti-poor titanomagnetites are the dominant magnetic carriers and AMS values are generally lower than 1.05. Magnetic foliations are sub horizontal and lineations directions are scattered in the LJI. The AMS fabrics are probably controlled by post-depositional compaction and welding of the deposit rather than transport dynamics. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Late Pleistocene and Holocene activity of the Atacazo–Ninahuilca Volcanic Complex (Ecuador)

The Atacazo–Ninahuilca Volcanic Complex (ANVC) is located in the Western Cordillera of Ecuador, 10 km southwest of Quito. At least six periods of Pleistocene to Holocene activity (N1 to N6) have been preserved in the geologic record as tephra fallouts and pyroclastic flow deposits. New field data, including petrographic and whole-rock geochemical analyses of over forty soil and tephra sections, 100 pumice and lithic samples, and 10 new ¹⁴C ages allow us to constrain: (1) the tephra fall isopachs and detailed characteristics of the last two events (N5–N6) including volume estimates of the tephra and pyroclastic flow deposits and the corresponding volcanic explosivity index (VEI); (2) the petrographical and geochemical correlations between domes, tephras, and pyroclastic flow deposits; and, (3) the timing of the last 4 eruptive events and a period of quiescence that endured a few thousand years (1000–4000).     

Dynamics and fluxes of organic carbon and nitrogen in two Guiana Shield river basins impacted by deforestation and mining activities

Deforestation and mining activities have proven to be very damaging to rivers because these activities disturb the environmental characteristics of rivers. Thus, the concentrations of dissolved organic carbon (DOC), particulate organic carbon (POC), particulate nitrogen (PN), and Chlorophyll‐a (Chl‐a) were measured monthly during 2 hydrological years in the Maroni and Oyapock Rivers to assess the dynamics and fluxes of organic carbon and nitrogen in these 2 Guiana Shield basins, which have been strongly (Maroni) and weakly (Oyapock) impacted by deforestation and mining activities. The 2‐year time series show that DOC, POC, PN, and Chl‐a concentrations vary seasonally with discharge in both rivers, indicating a hydrologically dominated control. Temporal patterns of DOC, POC, and PN indicate that these variables show maximum concentrations in rising waters due to the yield of organic matter and nitrogen accumulated in soils, which are incorporated into the rivers during rainfall. However, the Chl‐a concentrations were at a maximum during low‐water stages. The C/N and C/Chl‐a ratios also showed a seasonal trend, with lower values during the low water periods due to an increase in algal biomass. During high water, the POC in both rivers is the result of terrestrial organic matter, whereas during low‐water autochthonous organic matter can reach up to 34% of the POC. The mean annual fluxes of TOC and PN were higher (4.56 × 10⁵ tonC year^?1 and 1.77 × 10⁴ tonN year^?1, respectively) in the Maroni River than those (1.84 × 10⁵ tonC year^?1 and 0.54 × 10⁴ tonN year^?1, respectively) in the Oyapock River. However, the specific fluxes of DOC, POC, and PN from both basins were nearly the same. Although gold mining activities are performed in both basins, there is no conclusive evidence regarding the impact of these activities on the dynamics of organic matter and particulate nitrogen in the Maroni and Oyapock Rivers.     

Photometric investigation and orbital period analyses of the W UMa binaries FP Lyn,FV CVn and V354 UMa

New light curves and photometric solutions of FP Lyn, FV CVn and V354 UMa are presented.We found that these three systems are W-subtype shallow contact binaries. In addition, it is obvious that the light curves of FP Lyn and V354 UMa are asymmetric. Therefore, a hot spot was added on the primary star of FP Lyn and a dark spot was added on the secondary star of V354 UMa. At the same time, we added a third light to the photometric solution of FP Lyn for the final result. The obtained mass ratios and fill-out factors are q = 1.153 and f = 13.4% for FP Lyn, q = 1.075 and f = 4.6% for FV CVn, and q = 3.623 and f = 10.7% for V354 UMa respectively. The investigations of orbital period for these three systems indicate that the periods are variable. FP Lyn and V354 UMa were discovered to have secularly increasing components with rates of dp/dt = 4.19 × 10~(-7) d yr~(-1) and dp/dt = 7.70 × 10~(-7) d yr~(-1) respectively,which are feasibly caused by conservative mass transfer from the less massive component to the more massive component. In addition, some variable components were discovered for FV CVn, including a rate of dp/dt =~(-1).13 × 10~(-6) d yr~(-1) accompanied by a cyclic oscillation with amplitude and period of 0.0069 d and 10.65 yr respectively. The most likely explanation for the long-term decrease is angular momentum loss.The existence of an additional star is the most plausible explanation for the periodic variation.     

The location of infinite electrodes in pole–pole electrical surveys: consequences for 2D imaging

In 2D-multielectrode electrical surveys using the pole–pole array, the distance to ‘infinite electrodes' is actually finite. As a matter of fact, the available cable length generally imposes a poor approximation of theoretical location of these electrodes at infinity. This study shows that in most of the cases, the resulting apparent resistivity pseudosection is strongly distorted. Numerical simulation validated by field test also shows that a particular finite array provides results that are as close as possible to the ones of the ideal pole–pole array. This is achieved when two conditions that are weaker than an infinite location are fulfilled: (i) the ‘infinite electrodes' are placed symmetrically on both sides of the in-line electrodes with a spread angle of 30° and (ii) the length of ‘infinite lines' is at least 20 times the greatest distance between in-line electrodes. The electrical 2D image obtained with this enhanced array is the least distorted one with respect to the pole–pole image. The apparent resistivities are generally underestimated, but this deviation is almost homogeneous. Though the shift cannot be determined a priori, the interpretation of such an image with direct or inverse software designed for pole–pole data provides an accurate interpretation of the ground geometry.     

Sangay volcano, Ecuador: structural development, present activity and petrology

Sangay (5230 m), the southernmost active volcano of the Andean Northern Volcanic Zone (NVZ), sits 130 km above a >32-Ma-old slab, close to a major tear that separates two distinct subducting oceanic crusts. Southwards, Quaternary volcanism is absent along a 1600-km-long segment of the Andes. Three successive edifices of decreasing volume have formed the Sangay volcanic complex during the last 500 ka. Two former cones (Sangay I and II) have been largely destroyed by sector collapses that resulted in large debris avalanches that flowed out upon the Amazon plain. Sangay III, being constructed within the last avalanche amphitheater, has been active at least since 14 ka BP. Only the largest eruptions with unusually high Plinian columns are likely to represent a major hazard for the inhabited areas located 30 to 100 km west of the volcano. However, given the volcano's relief and unbuttressed eastern side, a future collapse must be considered, that would seriously affect an area of present-day colonization in the Amazon plain, 30 km east of the summit. Andesites greatly predominate at Sangay, there being few dacites and basalts. In order to explain the unusual characteristics of the Sangay suite—highest content of incompatible elements (except Y and HREE) of any NVZ suite, low Y and HREE values in the andesites and dacites, and high Nb/La of the only basalt found—a preliminary five-step model is proposed: (1) an enriched mantle (in comparison with an MORB source), or maybe a variably enriched mantle, at the site of the Sangay, prior to Quaternary volcanism; (2) metasomatism of this mantle by important volumes of slab-derived fluids enriched in soluble incompatible elements, due to the subduction of major oceanic fracture zones; (3) partial melting of this metasomatized mantle and generation of primitive basaltic melts with Nb/La values typical of the NVZ, which are parental to the entire Sangay suite but apparently never reach the surface and subordinate production of high Nb/La basaltic melts, maybe by lower degrees of melting at the periphery of the main site of magma formation, that only infrequently reach the surface; (4) AFC processes at the base of a 50-km-thick crust, where parental melts pond and fractionate while assimilating remelts of similar basaltic material previously underplated, producing andesites with low Y and HREE contents, due to garnet stability at this depth; (5) low-pressure fractionation and mixing processes higher in the crust. Both an enriched mantle under Sangay prior to volcanism and an important slab-derived input of fluids enriched in soluble incompatible elements, two parameters certainly related to the unique setting of the volcano at the southern termination of the NVZ, apparently account for the exceptionally high contents of incompatible elements of the Sangay suite. In addition, the low Cr/Ni values of the entire suite—another unique characteristic of the NVZ—also requires unusual fractionation processes involving Cr-spinel and/or clinopyroxene, either in the upper mantle or at the base of the crust.