Geochemical mapping of magmatic gas–water–rock interactions in the aquifer of Mount Etna volcano

Systematic analysis of major and minor elements in groundwaters from springs and wells on the slopes of Mt. Etna in 1995–1998 provides a detailed geochemical mapping of the aquifer of the volcano and of the interactions between magmatic gas, water bodies and their host rocks. Strong spatial correlations between the largest anomalies in pCO₂ (pH and alkalinity) K, Rb, Mg, Ca and Sr suggest a dominating control by magmatic gas (CO₂) and consequent basalt leaching by acidified waters of the shallow (meteoric) Etnean aquifer. Most groundwaters displaying this magmatic-type interaction discharge within active faulted zones on the S–SW and E lower flanks of the volcanic pile, but also in a newly recognised area on the northern flank, possibly tracking a main N–S volcano-tectonic structure. In the same time, the spatial distribution of T°C, TDS, Na, Li, Cl and B allows us to identify the existence of a deeper thermal brine with high salinity, high content of B, Cl and gases (CO₂, H₂S, CH₄) and low K/Na ratio, which is likely hosted in the sedimentary basement. This hot brine reaches the surface only at the periphery of the volcano near the Village of Paternò, where it gives rise to mud volcanoes called “Salinelle di Paternò”. However, the contribution of similar brines to shallower groundwaters is also detected in other sectors to the W (Bronte, Maletto), SW (Adrano) and SE (Acireale), suggesting its possible widespread occurrence beneath Etna. This thermal brine is also closely associated with hydrocarbon fields all around the volcano and its rise, generally masked by the high outflow of the shallow aquifer, may be driven by the ascent of mixed sedimentary–magmatic gases through the main faults cutting the sedimentary basement.     

Impact of imperfect rainfall knowledge on the efficiency and the parameters of watershed models

It is crucial to analyze the sensitivity of watershed (rainfall-runoff) models to imperfect knowledge of rainfall input, in order to judge whether or not they are reliable and robust, especially if they are to be used for operational purposes. In this paper, a new approach to sensitivity analysis is proposed, based on a comparison between the efficiency ratings and parameter values of the models and the quality of rainfall input estimate (GORE and BALANCE indexes, assessing the quality of rainfall time distribution and the total depth respectively). Data from three watersheds of increasing size (71, 1120, and 10700 km²), are used to test three watershed models of varying complexity (three-parameter GR3J model and six-parameter modified versions of TOPMODEL and IHACRES).

These models are able to cope with imperfect rainfall input estimates, and react to improvements in rainfall input accuracy by better performance and reduced variability of efficiency. Two different types of model behavior were identified: the models either benefit from improved rainfall data by producing more consistent parameter values, or they are unable to take advantage of the improvements. Although the watershed size seems to be immaterial, the smaller watersheds appear to need more precise areal rainfall estimates (a higher concentration of raingages) to ensure good modeling results.     

Tritium in the Caspian Sea

The tritium content of the surface water on the south shore of the Caspian Sea was determined in samples taken in two- to three-month intervals for the period of time from 1960 to 1970. Tritium concentrations following the massive H-bomb testing in 1962 and 1963 were particularly high in this water, much higher than in the surface waters of the open oceans. The data are interesting in connection with the tritium inventories on the continents and with the persistence of inert chemical pollutants in the surface layers of water masses.     

Découverte de coulées pyroclastiques sous-marines dans la zone de l’Iran Central — Mécanisme de mise en place

Study of these submarine pyroclastic flows is important for two reasons:

1. From a regional point of view, submarine pyroclastic flows partially explain the origin of widespread argillized glasses in the Eocene sedimentary series of Central Iran, which have diversely been described by earlier workers as Green Tuffs, Tuffaceous Muds, Green Series.
2. More generally, in contrast to basaltic volcanism, submarine acid volcanism is still very poorly-known. The mechanism here proposed is as follows: starting with a submarine, highly vesiculated lava containing idiomorphic phenocrysts, gas expansion gives rise to a vitroclastic shardy facies, whereas phenocrysts are fragmented. The whole makes up a gravitational flow that is rich in pumice, glassy shards, broken crystals, and gases; it becomes increasingly turbulent and able to tear-up sea-bottom sediments in its down-stream course. This flow evolves into turbidity currents at its distal reaches.

     

Ilot de chaleur a Quebec: Cas d'ete

This paper studies the urban heat island in Quebec City and its suburbs on one summer night. The region under study covers an area of 20 km by 20 km which streches from lake Saint-Charles on the north to Levis on the south and from the western suburb of Cap-Rouge to Beauport on the east. The total population of the region is about 400 000.On August 22, 1979 from 22:00 to 23:30 EDT, 109 measurements of wet- and dry-bulb temperatures were taken at preselected points. On that day, a large high pressure system gave clear skies to central Quebec while Quebec City Airport recorded a maximum temperature of 23 °C. The average wind measured at Duberger meteorological tower between 6 and 121 m above ground was 1.8 m s^-1 at 22:00 EDT and 0.9 m s^-1 at 23:30 EDT. Additional data were obtained from three thermographs installed at strategic points and five regular climatological stations, which were used to estimate cooling rates.During the period of measurement, the cooling rate averaged over the eight reference points was about 0.7 °C h^-1. However, the maximum cooling rate, which occured earlier, ranged from 2.2 °C h^-1 at Duberger to 4.4 °C h^-1 at Courville-de-Poissy. No relation seems to exist, in our case, between the maximum cooling rate and the heat island spatial structure. Comparison of these results with the ones given by Oke et al. (1972) shows that the eight stations behaved more like rural stations than urban ones.The temperature gradient measured between the center of old Quebec City and the suburbs averaged 6 °C while it was 9 °C for the coldest spot. Clo units were used to characterize the microclimates prevailing on the region for that night; 1 clo would be sufficient for comfort downtown while 1.5 clo is needed in the coldest spot for a slowly walking person. Large open areas like parks or the Laval University campus had a definite effect on temperature.The humidity was calculated for each point using standard psychrometric tables; no significant difference could be found over the area expect at points near or above the St. Laurent river where the average dew point was 1.5 °C higher.Each point was classified into 6 categories according to its predominant land-use as reported by the observers. A multiple regression between temperature on the one hand and altitude and land-use on the other hand was tried; it showed that temperature was significantly correlated with both. Such an equation could be used by town-planners to locate temperature gradients in future urban development over the area; land uses could be planned to enhance or reduce these gradients.This study confirms the idea that urban climate is a mosaic of interacting micro-climates. More measurements, including possibly airborne infra-red thermal imagery, will be taken during winter in order to assess the winter urban climate of Quebec City.     

Magnesian ilmenitite xenoliths in a basanite from Tahalra,Ahaggar (Southern Algeria)

Large magnesian ilmenite nodules occur in a quaternary basanitic volcano near Silet in the Tahalra volcanic area (Central Ahaggar, Southern Algeria). Their texture, from foliated to polygonal, is ascribed to solid state flow and dynamic recrystallization in upper mantle conditions.Their composition is similar to that of kimberlitic Mg-ilmenite nodules, as regards Mg, Fe, Al and Cr contents; the geikielite content ranges from 25 to 37 mol %. No outwards Mg enrichment of the nodules has been observed. Peripheral secundary products (pseudobrookite, magnetite and hematite) result from reaction with the host magma.From textural relationships and microprobe analyses, the Mg-ilmenite nodules from Tahalra are thought to be early cumulates from a mafic melt fractionnated in the upper-mantle; later, after solid-state deformation, these ilmenitite rocks were sampled and carried up to the surface by a fast-rising basanitic liquid.Rocks almost exclusively made of ilmenite do therefore presently exist within the upper-mantle and form a new type of petrological heterogeneity.     

A method for the study of the zonal kinetic energy balance in the atmosphere

Summary The atmospheric balance of the kinetic energy of the zonally averaged zonal motion is investigated from five years of daily data at 800 stations for the northern hemisphere. The basic equation for such energy is used, together with the simplifying assumption that the frictional destruction is due in the main to stresses acting across horizontal surfaces, being thus presumably related to the vertical shear of the mean zonal wind, although no further details are needed in the analysis. The five-year averages of various terms as well as their seasonal means appear to give reasonable results.The research reported in this paper was sponsored by the U.S. National Science Foundation under Grant No. GA-1310X.