Phase and Correlation in `Random' Seismic Fields and the Reconstruction of the Green Function

We first present a summary of recent results on coda interpretation. We emphasize the observation of the stabilization of P to S energy ratio indicating the modal equipartition of the wavefield. This property clearly shows that the coda waves are in the regime of multiple scattering. Numerical solutions of the elastic radiative transfer equation are used to illustrate the evolution of the wave-field towards P-to-S energy stabilization, and asymptotically to complete isotropy. The energy properties of the coda have been widely studied but the phase properties have often been neglected. The recently observed coherent backscattering enhancement, an expression of the so-called `weak localization', demonstrates that interference effects still persist for multiple diffracted waves. Another manifestation of the persistence of the phase is the possibility to reconstruct the Green function between two stations by averaging the cross correlation of coda waves produced by distant earthquakes and recorded at those two stations. This reconstruction is directly related to the properties of reciprocity and time reversal of any wavefield. Using broadband seismic coda waves, we show that the dominant phases of the Green function in the band 2 s–10 s, namely fundamental mode Rayleigh and Love waves, are reconstructed. We analyze the time symmetry of the cross correlation and show how the level of symmetry evolves with the isotropization of the diffuse field with lapse time. Similarly we investigate the correlation in continuous ambient noise records. Whereas the randomness of the coda results from multiple scattering by randomly distributed scatterers, we assume that the seismic noise is random mostly because of the distribution of sources at the surface of the Earth. Surface waves can be extracted from long time series. The dispersion curves of Rayleigh waves are deduced from the correlations. On paths where measurements from earthquake data are also available, we show that they are in good agreement with those deduced from noise correlation. The measurement of velocities from correlation of noise along paths crossing different crustal structures opens the way for a `passive imaging' of the Earth's structure.     

The carbon dioxide solubility in alkali basalts: an experimental study

Experiments were conducted to determine CO₂ solubilities in alkali basalts from Vesuvius, Etna and Stromboli volcanoes. The basaltic melts were equilibrated with nearly pure CO₂ at 1,200°C under oxidizing conditions and at pressures ranging from 269 to 2,060 bars. CO₂ solubility was determined by FTIR measurements. The results show that alkalis have a strong effect on the CO₂ solubility and confirm and refine the relationship between the compositional parameter Π devised by Dixon (Am Mineral 82:368–378, 1997) and the CO₂ solubility. A general thermodynamic model for CO₂ solubility in basaltic melts is defined for pressures up to 2 kbars. Based on the assumption that O²⁻ and CO₃²⁻ mix ideally, we have:

Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Determination of Boron Concentration in Geochemical Reference Materials Extracted by Pyrohydrolysis and Measured by ICP‐MS

This article presents new boron concentrations for nine geochemical reference materials (GS‐N, FK‐N, GL‐O, BX‐N, DT‐N, AN‐G, GH, Mica‐Fe, Mica‐Mg). After extraction by a modified pyrohydrolysis technique, boron concentrations were measured by ICP‐MS. The blank levels for the whole procedure were 0.091 ± 0.020 ng ml^?1 or 14 ± 5 ng of boron in total. The method was first validated by measuring nine reference materials with known boron concentrations. The determined boron concentrations are all within the range of recommended or published values, which means that the yields were 100%, and show precisions below 10% for samples containing over 2 μg g^?1 of boron.     

Evolution of calc-alkaline to alkaline magmatism through Carboniferous convergence to Permian transcurrent tectonics,western Chinese Tianshan

Continuous magmatic activity occurred in the western Chinese Tianshan, Central Asia, from the Carboniferous to the Permian, i.e. before and after the Late Carboniferous amalgamation of Junggar and the Yili Blocks. Zircon U–Pb LA-ICPMS and Ar–Ar data reveal a coincidence in time between regional wrench faulting and granitoid emplacement. Permian post-collisional granitoids crop out within or at the margins of large-scale dextral strike-slip shear zones, some of them show synkinematic fabrics. The whole rock geochemical features of the Early-Middle Permian granitoids indicate an evolution from high-K calc-alkaline towards alkaline series. In other places of the North Tianshan, alkaline magmatism occurred together with deep marine sedimentation within elongated troughs controlled by wrench faults. Therefore, in contrast with previous interpretations that forwarded continental rift or mantle plume hypotheses, the coexistence of diverse magmatic sources during the same tectonic episode suggests that post-collisional lithosphere-scale transcurrent shearing tightly controlled the magmatic activity during the transition from convergent margin to intraplate anorogenic processes.     

Fragmentation Energy in Rock Blasting

The theoretical explosive energy used in blasting is a common issue in many recent research works (Spathis 1999; Sanchidrian 2003). It is currently admitted that the theoretical available energy of the explosives is split into several parts during a blast: seismic, kinetic, backbreaks, heave, heat and fragmentation energies. Concerning this last one, the energy devoted to the breakage and to the creation of blocks within the muckpile can be separated from the microcracking energy which is devoted to developing new and/or extending existing micro cracks within the blocks (Hamdi et al. 2001; López et al. 2002). In order to investigate these two types of energy, a first and important task is to precisely study the main parameters characterising the two constitutive elements of the rock mass (rock matrix and discontinuity system). This should provide useful guidelines for the choice of the blasting parameters (type of explosive, blasting pattern, etc.), in order to finally control the comminution process. Within the frame of the EU LESS FINES research project, devoted to the control of fines production, the methodology was developed in order to: (1) characterize the in situ rock mass, by evaluating the density, anisotropy, interconnectivity and fractal dimension of the discontinuity system and (2) evaluate fragmentation (both micro and macro) energy spent during the blasting operation. The methodology was applied to three production blasts performed in the Klinthagen quarry (Sweden) allowing to estimate the part of the fragmentation energy devoted to the formation of muck pile blocks on one side and to the muckpile blocks microcracking on the other side.     

Uraniferous bitumen nodules in the Talvivaara Ni–Zn–Cu–Co deposit (Finland): influence of metamorphism on uranium mineralization in black shales

In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.     

Evidence of a large upper-Cretaceous depocentre across the Continent-Ocean boundary of the Congo-Angola basin. Implications for palaeo-drainage and potential ultra-deep source rocks

The analysis of 2D deep-seismic-reflection profiles across the slope and abyssal plain of the Angola oceanic basin reveals the existence of a significant and formerly unknown depocentre beneath the giant Cenozoic Congo deep-sea fan, between 7000 m and 9000 m depth, deposited directly onto the Aptian oceanic crust. The unit, which is up to 2.5 km thick and extends for more than 200 km basinwards of the Continent-Ocean boundary, is probably aged Albian–Turonian. Its radial fan-shaped depocentre is centred on the present-day Congo River outlet and contains at least 0.2 Mio km³ of sediments. These observations and the results from flexural modelling indicate that (1) the location of the Congo River's outlet has remained fairly stable since the Late Cretaceous, and (2) the basal unit was indeed sourced by a palaeo-Congo River probably located nearby the present-day one. Thus, the Atlantic sedimentary system related to the exoreism of the Congo River is much older than previously thought. Thermal modelling indicates that the maturation history of this upper-Cretaceous deposits is highly influenced by the interaction between the initial high heat flow of the young oceanic crust and further increase in sediment supply due to the progradation of the overlying Tertiary deep-sea fan during the Miocene. Hence, despite low present-day heat-flow values, should the unit have source rock potential, its basal section may be currently generating hydrocarbons.     

Phases d'érosion—comblement de la vallée de la Papenoo et volcanisme subrécent à Tahiti,en relation avec l'évolution des iles de la Société (Pacifique Sud)

A detailed mapping and data from borings support the conclusion that there is a late lava flow inside the Papenoo valley, the main valley of Tahiti island. This last volcanic manifestation which took place 400,000 years ago came after the phase of erosion corresponding to the Illinoian glacial period. It is one of the four phases of erosion followed by filling observed in the cross section of the Papenoo valley.     

A theoretical and numerical framework for modeling gypsum cavity dissolution

In this paper, a large‐scale diffuse interface model is used to describe the evolution of a gypsum cavity formation induced by dissolution. The method is based upon the assumption of a pseudo‐component dissolving with a thermodynamic equilibrium boundary condition. A methodology is proposed based on numerical computations with fixed boundaries in order to choose suitable parameters for the diffuse interface model, and hence predict the correct dissolution fluxes and surface recession velocity. Additional simulations were performed to check which type of momentum balance equation should be used. The numerical results did not show a strong impact of this choice for the typical initial boundary value problems under consideration. Calculations with a variable density and Boussinesq approximation were also performed to evaluate the potential for natural convection. The results showed that the impact of density driven flows was negligible in the cases under investigation. The potential of the methodology is illustrated on two large‐scale configurations: one corresponding to a gypsum lens located strictly within a porous rock formation and the other to an isolated pillar in a flooded gypsum room and pillar quarry. Copyright © 2016 John Wiley & Sons, Ltd.