Compaction in a mantle with a very small melt concentration: Implications for the generation of carbonatitic and carbonate-bearing high alkaline mafic melt impregnations

Xenoliths entrained in alkaline basalts and kimberlites give strong evidence that mantle carbonatitic and carbonated high alkaline mafic silicate melts, which are initially produced at very low degrees of partial melting (?1%), percolate and accumulate to form impregnations with a melt concentration of up to 10%. At present no compaction model has explained such huge local amplification of melt concentration. Recently, Bercovici et al. [1] have shown that the commonly used equations of compaction are not sufficiently general to describe all melt percolation processes in the mantle. In particular, they show that, when the melt concentration in the mantle is very low, the pressure jump ΔP between the solid and liquid fractions of the mantle mush is very important and plays a driving role during compaction. 1-D compaction waves generated with two different systems of equations are computed. Three types of wave-trains are observed, i.e. (1) sinusoidal waves; (2) periodic waves with flat minima and very acute maxima (‘witch hat waves’); (3) periodic solitary waves with flat maxima and extremely narrow minima (‘bowler hat waves’). When the initial melt distribution in the mantle is quite homogeneous, the compaction waves have sinusoidal shapes and can locally amplify the melt concentration by a factor less than two. When there is a drastic obstruction at the top of the wetted domain, the pressure jump ΔP between solid and liquid controls the shape of the waves. If the computation assumes the equality of pressure between the two phases (ΔP=0), the compaction wave has a ‘bowler hat shape’, and locally amplifies the melt concentration by a factor less than 5. Alternatively, simulations taking into account the pressure jump between phases ΔP predict compaction waves with ‘witch hat shape’. These waves collect a large quantity of melt promoting the development of magmons with local melt concentration exceeding 100× the background melt concentration. It is inferred that in a mantle with very low concentrations of carbonatitic or high alkaline mafic silicate melt the magmons are about 1 km thick and reach, in less than 1 Ma, a melt concentration of about 10%. The magmons are likely generated below the lithosphere at some distance away from the center of hot spots. This can explain the development of mantle carbonatitic eruptions in the African rift and the carbonatite and high alkaline mafic silicate volcanic activity in oceanic islands.     

Early and late Holocene water-level fluctuations of Lake Annecy, France: sediment and pollen evidence and climatic implications

Early and late Holocene water-level changes in Lake Annecy, France, were reconstructed from a sediment sequence from Annecy. Two early Holocene successive rises in lake level at ca. 8900-8700 BP are recorded. Another increase in lake level, beginning at ca. 780 BP, is documented. The higher lake-level conditions in Lake Annecy during the 9th millennium BP, i.e. between the Preboreal oscillation and the 8200 yr event, appear to coincide with a more widespread cooling period which has been recorded in western Europe, in the Greenland ice-sheet and the North Atlantic ocean. The rise in lake level at ca. 780 BP can be related to the early Little Ice Age.     

Surface Matching and Change Detection Using a Modified Hough Transformation for Robust Parameter Estimation

Many photogrammetric and GIS applications, such as city modelling, change detection and object recognition, deal with surfaces. Change detection involves looking for differences between two surface models that are obtained from different sensors, for example an optical sensor and a laser scanner, or by the same sensor at different epochs. Surfaces obtained through a sampling process may also have to be compared for future processing (for example transformation parameter estimation and change detection). Surface matching is therefore an essential task in these applications. The matching of surfaces involves two steps. The first step deals with finding the correspondences between two surface points and/or patches. The second step requires the determination of transformation parameters between the two surfaces. However, since most surfaces consist of randomly distributed discrete points and may have different reference systems, finding the correspondences cannot be achieved without knowing the transformation parameters between the two surfaces. Conversely, deriving the transformation parameters requires the knowledge of the correspondence between the two point sets. The suggested approach for surface matching deals with randomly distributed data sets without the need for error prone interpolation and requires no point-to-point correspondence between the two surfaces under consideration. This research simultaneously solves for the correspondence and the transformation parameters using a Modified Iterated Hough Transform for robust parameter estimation. Several experiments are conducted to prove the feasibility and the robustness of the suggested approach, even when a high percentage of change exists.     

Telescoped porphyry Cu-Mo-Au mineralisation, advanced argillic alteration and quartz-sulphide-gold-anhydrite veins in the Thames District, New Zealand

Porphyry Cu-Mo-Au mineralisation with associated potassic and phyllic alteration, an advanced argillic alteration cap and epithermal quartz-sulphide-gold-anhydrite veins, are telescoped within a vertical interval of 400-800 m on the northeastern margin of the Thames district, New Zealand. The geological setting is Jurassic greywacke basement overlain by Late Miocene andesitic-dacitic rocks that are extensively altered to propylitic and argillic assemblages. The porphyry Cu-Mo-Au mineralisation is hosted in a dacite porphyry stock and surrounding intrusion breccia. Relicts of a core zone of potassic K-feldspar-magnetite-biotite alteration are overprinted by phyllic quartz-sericite-pyrite or intermediate argillic chlorite-sericite alteration assemblages. Some copper occurs in quartz-magnetite-chlorite-pyrite-chalcopyrite veinlets in the core zone, but the bulk of the copper and the molybdenum are associated with the phyllic alteration as disseminated chalcopyrite and as molybdenite-sericite-carbonate veinlets. The advanced argillic cap has a quartz-alunite-dickite core, which is enveloped by an extensive pyrophyllite-diaspore-dickite-kaolinite assemblage that overlaps with the upper part of the phyllic alteration zone. Later quartz-sphalerite-galena-pyrite-chalcopyrite-gold-anhydrite-carbonate veins occur within and around the margins of the porphyry intrusion, and are associated with widespread illite-carbonate (argillic) alteration. Multiphase fluid inclusions in quartz stockwork veins associated with the potassic alteration trapped a highly saline (50-84 wt% NaCl equiv.) magmatic fluid at high temperatures (450 to >600 °C). These hypersaline brines were probably trapped at a pressure of about 300 bar, corresponding to a depth of 1.2 km under lithostatic conditions. This shallow depth is consistent with textures of the host dacite porphyry and reconstruction of the volcanic stratigraphy. Liquid-rich fluid inclusions in the quartz stockwork veins and quartz phenocrysts trapped a lower salinity (3-20 wt% NaCl equiv.), moderate temperature (300-400 °C) fluid that may have caused the phyllic alteration. Fluid inclusions in the quartz-sphalerite-galena-pyrite-chalcopyrite-gold-anhydrite-carbonate veins trapped dilute (1-3 wt% NaCl equiv.) fluids at 250 to 320 °C, at a minimum depth of 1.0 km under hydrostatic conditions. Oxygen isotopic compositions of the fluids that deposited the quartz stockwork veins fall within the 6 to 10‰ range of magmatic waters, whereas the quartz-sulphide-gold-anhydrite veins have lower '¹⁸O_water values (-0.6 to 0.5‰), reflecting a local meteoric water (-6‰) influence. A '¹⁸O versus 'D plot shows a trend from magmatic water in the quartz stockwork veins to a near meteoric water composition in kaolinite from the advanced argillic alteration. Data points for pyrophyllite and the quartz-sulphide-gold-anhydrite veins lie about midway between the magmatic and meteoric water end-member compositions. The spatial association between porphyry Cu-Mo-Au mineralisation, advanced argillic alteration and quartz-sulphide-gold-anhydrite veins suggests that they are all genetically part of the same hydrothermal system. This is consistent with K-Ar dates of 11.6-10.7 Ma for the intrusive porphyry, for alunite in the advanced argillic alteration, and for sericite selvages from quartz-gold veins in the Thames district.     

Coarse carbonate breccias as a result of water-wave cyclic loading (uppermost Jurassic – South-East Basin, France)

In the uppermost Jurassic of the central part of the South-East Basin of France, an association of lime mudstone beds, calcarenite beds and coarse carbonate breccia bodies form an informal stratigraphical unit called the 'Barre Tithonique'. In the 'Barre Tithonique', gradual transitions from lime mudstone or calcarenite to breccia show different stages of deformation leading to progressive brecciation of the original lithologies. The study of the breccia facies, and the observed gradual transitions as a whole, document a new early diagenetic process in carbonate environments, resulting from water-wave and seabed interaction. Water-wave induced brecciation and its abundance in the 'Barre Tithonique' indicate that sea–seabed interaction was significant. Comparison with modern studies of the mechanics of wave–seabed interaction suggests that water depth was less than 200 m. It is demonstrated that sedimentary features such as channel-like structures, previously interpreted as being the result of erosion and deposition of mud-flows, were in fact produced by wave-induced, in situ reworking of lime mud, without any significant unidirectional flow or gravity induced displacement.     

Modelling metolachlor exports in subsurface drainage water from two structured soils under maize (eastern France)

The study investigated the processes involved in metolachlor transport in two artificially drained, structured soils in eastern France. Measured losses of bromide and metolachlor in drainage water were compared with results simulated by the mechanistic, stochastic AgriFlux model. Simulated drainage water volumes were generally similar to the measured volumes when the spatial variability of the soil water properties was taken into account. When such variability was disregarded, cumulative water volumes of the clay soil were over- or underestimated by more than 20%. Two types of adsorption were tested. For instantaneous, reversible adsorption, using the partition coefficient Koc, metolachlor losses were underestimated in the first drainage water volumes and overestimated for the total study period. The use of slow adsorption and desorption kinetics (ADK) produced an export pattern similar to the observed one. A sensitivity analysis indicated that the simulated results are very sensitive to the values of the ADK rates, especially for the silty loam soil. The effect of ADK on the attenuation of metolachlor exports was more significant than the effect of degradation (2.3 and 6.7 times higher for the clay and silty loam soils, respectively). For the same four-month period, the bromide and metolachlor losses (using ADK) in the clay soil were 2.1 and 1.3 times greater, respectively, if the macroporosity was set at 10% than if it was not simulated. Conversely, macroporosity did not significantly affect these losses in the silty loam. The main factors involved in the metolachlor transport in the studied soils were: (i) the macroporosity, especially in the clay soil because of the low hydraulic conductivity of the matrix and (ii) the sorption kinetics rates which varied according to the soil physico-chemical characteristics.     

Testing etching hypothesis for the shaping of granite dome structures beneath lateritic weathering landsurfaces using ERT method

An Erratum has been published for this article in Earth Surface Processes and Landforms 28(13) 2003, 1491. Granite domes, boulders and knobs buried within saprolite have been detected beneath lateritic weathering landsurfaces using 2D electrical resistivity tomography (ERT). This technique provides a valuable means of mapping the bedrock topography and the regolith structures underneath landsurfaces, as it is intrinsically very sensitive to the electrical properties of superimposed pedological, hydrological and geological layers, allowing the determination of their relative geometry and spatial relationships. For instance, 2D inverse electrical resistivity models including topographic data permit the de?nition of lithostratigraphic cross‐sections. It shows that resistive layers, such as the more or less hardened ferruginous horizons and/or the bedrock, are generally well differentiated from poorly resistive layers, such as saprolite, including water‐saturated lenses, as has been corroborated by past and actual borehole observations. The analysis of the 2D geometrical relations between the weathering front, i.e. the bedrock topography, and the erosion surface, i.e. the landsurface topography, documents the weathering and erosion processes governing the development of the landforms and the underlying structures, thus allowing the etching hypothesis to be tested. The in?ltration waters are diverted by bedrock protrusions, which behave as structural thresholds compartmentalizing the saprolite domain, and also the regolith water table, into distinct perched saturated subdomains. The diverted waters are thus accumulated in bedrock troughs, which behave like underground channels where the saprolite production rate may be enhanced, provided that the water drainage is ef?cient. If the landsurface topography controls the runoff dynamics, the actual bedrock topography as depicted by ERT imaging in?uences the hydrodynamics beneath the landsurface. In some way, this may control the actual weathering rate and the shaping of bedrock protrusions as granite domes and knobs within thick saprolite, before their eventual future exposure. Copyright © 2003 John Wiley & Sons, Ltd.