Heat budget of the surface mixed layer south of Africa

ARGO hydrographic profiles, two hydrographic transects and satellite measurements of air–sea exchange parameters were used to characterize the properties and seasonal heat budget variations of the Surface Mixed Layer (SML) south of Africa. The analysis distinguishes the Subtropical domain (STZ) and the Subantarctic Zone (SAZ), Polar Frontal Zone (PFZ) and Antarctic Zone (AZ) of the Antarctic Circumpolar Current. While no Subantarctic Mode Water forms in that region, occurrences of deep SML (up to ∼450 m) are observed in the SAZ in anticyclones detached from the Agulhas Current retroflection or Agulhas Return Current. These are present latitudinally throughout the SAZ, but preferentially at longitudes 10–20° E where, according to previous results, the Subtropical Front is interrupted. Likely owing to this exchange window and to transfers at the Subantarctic Front also enhanced by the anticyclones, the SAZ shows a wide range of properties largely encroaching upon those of the neighbouring domains. Heat budget computations in each zone reveal significant meridional changes of regime. While air–sea heat fluxes dictate the heat budget seasonal variability everywhere, heat is mostly brought through lateral geostrophic advection by the Agulhas Current in the STZ, through lateral diffusion in the SAZ and through air–sea fluxes in the PFZ and AZ. The cooling contributions are by Ekman advection everywhere, lateral diffusion in the STZ (also favoured by the ∼10° breach in the Subtropical Front) and geostrophic advection in the SAZ. The latter likely reflects an eastward draining of water warmed through mixing of the subtropical eddies.     

Sorption-desorption kinetics and toxic cell concentration in marine phytoplankton microalgae exposed to Linear Alkylbenzene Sulfonate

Linear Alkylbenzene Sulfonates (LAS) are ubiquitous surfactants. Traces can be found in coastal environments. Sorption and toxicity of C₁₂-LAS congeners were studied in controlled conditions (2-3500 μg C₁₂LAS/L) in five marine phytoplanktonic species, using standardized methods. IC₅₀ values ranged from 0.5 to 2 mg LAS/L. Sorption of ¹⁴C₁₂-6 LAS isomer was measured at environmentally relevant trace levels (4 μg/L) using liquid scintillation counting. Steady-state sorption on algae was reached within 5 h in the order dinoflagellate > diatoms > green algae. The sorption data, fitted a L-type Freundlich isotherm, indicating saturation. Desorption was rapid but a low LAS fraction was still sorbed after 24 h. Toxic cell concentration was 0.38 ± 0.09 mg/g for the studied species. LAS toxicity results from sorption on biological membranes leading to non-specific disturbance of algal growth. Results indicate that LAS concentrations in coastal environments do not represent a risk for these organisms.     

A tracer study in an Alaskan gravel beach and its implications on the persistence of the Exxon Valdez oil

Despite great efforts including bioremediation, the 1989 Exxon Valdez oil spills persist in many gravel beaches in Prince William Sound, Alaska, USA. To explore this mystery, a lithium tracer study was conducted along two transects on one of these beaches. The tracer injections and transports were successfully simulated using the 2-dimensional numerical model MARUN. The tracer stayed much longer in the oil-persisting, right transect (facing landwand) than in the clean, left transect. If the tracer is approximately regarded as oils, oils in the upper layer would have more opportunities to enter the lower layer in the right transect than in the left one. This may qualitatively explain the oil persistence within the right transect. When the tracer is regarded as nutrients, the long stay of nutrients within the right transect implies that the oil persistence along the right transect was not due to the lack of nutrients during the bioremediation.     

1999年土耳其Izmit Mw7.6地震的持续成核过程

实验室和理论研究表明,地震之前会出现一个渐进性的滑动不稳定阶段,在此期间,断层缓慢滑动,而后突然加速并最终导致动态破裂.本文中,我们报道了迄今记录最为完整的大地震之一,即1999年土耳其Izmit Mw7.6地震之前出现了持续时间很久的源自震源的地震信号.这种信号包含一连串的地震破裂,破裂随时间和低频地震噪声的增加而加...     

Residence times in river basins as determined by analysis of long-term tritium records

The US Geological Survey has maintained a network of stations to collect samples for the measurement of tritium concentrations in precipitation and streamflow since the early 1960s. Tritium data from outflow waters of river basins draining 4500–75000 km² are used to determine average residence times of water within the basins. The basins studied are the Colorado River above Cisco, Utah; the Kissimmee River above Lake Okeechobee, Florida; the Mississippi River above Anoka, Minnesota; the Neuse River above Streets Ferry Bridge near Vanceboro, North Carolina; the Potomac River above Point of Rocks, Maryland; the Sacramento River above Sacramento, California; the Susquehanna River above Harrisburg, Pennsylvania. The basins are modeled with the assumption that the outflow in the river comes from two sources—prompt (within-year) runoff from precipitation, and flow from the long-term reservoirs of the basin. Tritium concentration in the outflow water of the basin is dependent on three factors: (1) tritium concentration in runoff from the long-term reservoir, which depends on the residence time for the reservoir and historical tritium concentrations in precipitation; (2) tritium concentrations in precipitation (the within-year runoff component); (3) relative contributions of flow from the long-term and within-year components. Predicted tritium concentrations for the outflow water in the river basins were calculated for different residence times and for different relative contributions from the two reservoirs. A box model was used to calculate tritium concentrations in the long-term reservoir. Calculated values of outflow tritium concentrations for the basin were regressed against the measured data to obtain a slope as close as possible to 1. These regressions assumed an intercept of zero and were carried out for different values of residence time and reservoir contribution to maximize the fit of modeled versus actual data for all the above rivers. The final slopes of the fitted regression lines ranged from 0.95 to 1.01 (correlation coefficient > 0.96) for the basins studied. Values for the residence time of waters within the basins and average relative contributions of the within-year and long-term reservoirs to outflow were obtained. Values for river basin residence times ranged from 2 years for the Kissimmee River basin to 20 years for the Potomac River basin. The residence times indicate the time scale in which the basin responds to anthropogenic inputs. The modeled tritium concentrations for the basins also furnish input data for urban and agricultural settings where these river waters are used.     

A field study of the coupled effects of aquifer stratification,fluid density,and groundwater fluctuations on dispersivity assessments

A number of experimental studies have tackled the issue of solute transport parameter assessments either in the laboratory or in the field. But yet, the behavior of a plume in the field under density driven forces, is not well known due to possible development of instabilities. Some field tracer tests on the fate of plumes denser than native groundwater such as those encountered under waste disposal facilities, have pointed out the processes of sinking and splitting at the early stage of migration. The process of dispersion was widely investigated, but the range of dispersivity values obtained from either experimental tests, or numerical and theoretical calculations is still very large, even for the same type of aquifers. These discrepancies were considered to be essentially caused by soil heterogeneities and scale effects. In the meantime, studies on the influence of sinking and fingering have remained more scarce. The objective of the work is to analyze how transport parameters such as dispersivities can be affected by unstable conditions, which lead to plume sinking and fingering. A series of tracer tests were carried out to study under natural conditions, the transport of a dense chloride solution injected in a shallow two-layered aquifer. Two types of experiments were performed: in the first type, source injection was such that the plume could travel downward from one layer to the other of higher pore velocity, and in the second one, the migration took place only in the faster layer. The results suggest some new insights in the processes occurring at the early stages of a dense plume migration moving in a stratified aquifer under groundwater fluctuations, which can be summarized through the following points: (i) Above a stability criterion threshold, a fingering process and a multi modal plume transport take place, but local dispersivities can be cautiously derived, using breakthrough curves matching. (ii) When water table is subject to some cycling or rising, the plume can be significantly distorted in the transverse direction, leading to unusual values of the ratio between longitudinal and transverse dispersivities. (iii) Under stable conditions, for example in the case of straightforward injection in the faster aquifer layer, longitudinal dispersivity is greater than the transverse component as usually encountered, and the obtained transport parameters are closed to macro dispersivity values, which reach their asymptotic limit at very short distances. (iv) The classical scale effect about the varying dispersivity at short distances could be a process mainly due to the distance required for a plume stabilization.     

Effect of particle density and inflow concentration of suspended sediment on bedload transport in rill flow

Laboratory flume experiments were carried out to evaluate the effect of particle density on bedload transport of sand‐sized particles and the effect of a suspended load of clay particles (kaolinite) on bedload transport of sand‐sized particles in rill flow conditions. Three materials in the range 400–600 µm were selected to simulate bedload transport of primary particles and aggregates: sand (2650 kg/m³), crushed brick (2450 kg/m³) and anthracite (1300–1700 kg/m³). In the two first experiments, two different methods were applied to determine bedload transport capacity of coarse particles for various conditions of flow discharge (from 2 to 15 L/min) and slope (2.2, 3 and 4%). In the third experiment, clear water was replaced with kaolinite–water mixture and bedload transport capacity of crushed brick particles was determined for a 4% slope and different concentrations of kaolinite (0, 7, 41 and 84 g/L). The results showed that bedload transport increased significantly with the decrease in particle density but the effect of particle density on transport rates was much less important than flow discharge. Velocity measurements of clear flow, flow mixed with coarse particles and coarse particles confirmed the existence of a differentiation between suspended load and bedload. In these experimental conditions, suspended load of kaolinite did not affect bedload rates of crushed brick particles. Three transport capacity formulae were tested against observed bedload rates. A calibration of the Foster formula revealed that the shear stress exponent should be greater than 1.5. The Low and the Govers unit stream power (USP) equations were then evaluated. The Low equation was preferred for the prediction of bedload rates of primary particles but it was not recommended in the case of aggregates of low density because of the limited experimental conditions applied to derive this equation. Copyright © 2008 John Wiley & Sons, Ltd.     

Deriving fragility functions from bilinearized capacity curves for earthquake scenario modelling using the conditional spectrum

The development of fragility curves to perform seismic scenario-based risk assessment requires a fully probabilistic procedure in order to account for uncertainties at each step of the computation. This is especially true when developing fragility curves conditional on an Intensity Measure that is directly available from a ground-motion prediction equation. In this study, we propose a new derivation method that uses realistic spectra instead of design spectral shapes or uniform hazard spectra and allows one to easily account for the features of the site-specific hazard that influences the fragility, without using non-linear dynamic analysis. The proposed method has been applied to typical school building types in the city of Basel (Switzerland) and the results have been compared to the standard practice in Europe. The results confirm that fragility curves are scenario dependent and are particularly sensitive to the magnitude of the earthquake scenario. The same background theory used for the derivation of the fragility curves has allowed an innovative method to be proposed for the conversion of fragility curves to a common IM (i.e. spectral acceleration or PGA). This conversion is the only way direct comparisons of fragility curves can be made and is useful when inter-period correlation cannot be used in scenario loss assessment. Moreover, such conversion is necessary to compare and verify newly developed curves against those from previous studies. Conversion to macroseismic intensity is also relevant for the comparison between mechanical-based and empirical fragility curves, in order to detect possible biases.