The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

Guided wave propagation in laterally varying media - II. Lg-waves in north-western Europe

Summary. Lg -wave observations at NORSAR from a sequence of explosions straddling the Central Graben in the North Sea, show that the phase is almost extinguished by passing through this structure. For models of the graben structure, based on seismic refraction experiments, with crustal thinning beneath a zone of thickened sediments, numerical modelling of Lg propagation shows very poor transmission. The inclusion of attenuation simulating the effects of scattering from faults and other complex structures further diminishes the transmittivity. The theoretical effect of a crustal pinch is to redistribute S energy over a wide range of groups velocities, a pattern that fits well with the observations.
Three components recordings at NORSAR of explosive charges fired in water covering a wide range of azimuths, show significant transverse components to the seismograms. The transverse energy builds up with travel time and for Lg is of the same order as the vertical component. These results are consistent with the theoretical prediction of progressive net transfer of energy from Rayleigh to Love modes as the wavetrain propagates through a three-dimensionally heterogeneous medium.     

MELTWATER FLUXES AT AN ARCTIC FOREST-TUNDRA SITE

Models of surface energy balance and snow metamorphism are utilized to predict the energy and meltwater fluxes at an Arctic site in the forest–tundra transition zone of north-western Canada. The surface energy balance during the melt period is modelled using an hourly bulk aerodynamic approach. Once a snowcover becomes patchy, advection from the bare patches to the snow-covered areas results in a large spatial variation in basin snowmelt. In order to illustrate the importance of small-scale, horizontal advection, a simple parameterization scheme using sensible heat fluxes from snow free areas was tested. This scheme estimates the maximum horizontal advection of sensible heat from the bare patches to the snow-covered areas. Calculated melt was routed through the measured snowcover in each landscape type using a variable flow path, meltwater percolation model. This allowed the determination of the spatial variability in the timing and magnitude of meltwater release for runoff. Model results indicate that the initial release of meltwater first occurred on the shallow upland tundra sites, but meltwater release did not occur until nearly two weeks later on the deep drift snowcovers. During these early periods of melt, not all meltwater is available for runoff. Instead, there is a period when some snowpacks are only partially contributing to runoff, and the spatial variation of runoff contribution corresponds to landscape type. Comparisons of melt with and without advection suggests that advection is an important process controlling the timing of basin snowmelt.     

On molecules in sunspots

Spectra of umbrae of several sunspots in the wavelength region 4000–8000 Å scanned photoelectrically at the Göttingen Locarno Observatory were used in order to search for absorption lines of molecules. Several thousands of lines of known molecules were reidentifled (see Table II and Table III). Newly identified molecules are CoH, NiH and H₂O (see Table IV and Wöhl (1969a)). The Zeemann effect on molecular lines (of MgH and CaH; see Table V and Wöhl (1969b)) in spectra of umbrae was detected.     

VELOCITY DISPERSION OF SEISMIC WAVES*

In well velocity surveys made to calibrate Sonic (CV) Logs the calibration survey uses frequencies around 50 Hz whereas the Sonic Logging tool uses frequencies around 20 kHz. There thus exists the possibility of making a direct measure of velocity dispersion. In any one survey the disturbing factors, both instrumental and operational, will often mask any dispersive effect that might exist. Consequently this paper reports on a statistical analysis of the velocity differences resulting from calibration surveys and Sonic logs. Only Borehole Compensated Sonic Logs were used. Four areas were investigated: the North Sea, Abu Dhabi, Libya and Alaska. After rejecting logs and calibration records which were obviously in error there remained 424000 feet (about 130 km) of usable log distributed throughout 66 wells. The four areas were analysed separately and in no case was the estimated dispersion significantly different from zero. However, the mean values did correlate with lithology from (? 0.17 ± 0.18)% for the essentially carbonate section in Abu Dhabi to (+ 0.45 ± 0.25)% for the sand-shale section in Alaska, a positive sign meaning that the higher frequencies travelled faster. Except for Alaska the calibration surveys were made with a wall-clamp geophone, and for these areas amplitude measurements were made. After suitable corrections estimates of the absorption parameter Q were obtained. These varied from 20 to 200 with mean values of 63 for Libya, 70 for Abu Dhabi and 88 for the North Sea (excluding the Tertiary). If, as is usually assumed, the absorption mechanism is linear and is described by a Q which is independent of frequency, then these values would necessarily imply dispersion of several percent. As instanced above no such dispersion was observed. It is possible that the expected dispersion was compensated for by invasion of the mud filtrate into the borehole walls, but it is more likely that the absorption mechanism was substantially non-linear.     

Volcanogenic massive sulfide deposits of ophiolite associations

Volcanogenic massive sulfide deposits in ophiolite complexes are usually attributed to the Cyprus type. They associate with basaltic volcanics that are formed in mid-ocean or back-arc spreading centers and much less frequently in intra-plate settings. The deposits are characterized by copper or copper-zinc ores that are enriched in Ni, Co, and in places Mn and As, but are very poor in Pb and demonstrate a low to moderate content of Ag and Au. Typically, the deposits are low to very low in ore and metal reserves. Cyprus-type deposits were irregularly distributed during geological history. The most ancient of them were formed in the Neoproterozoic, while the bulk of the deposits are Ordovician or Cretaceous in age. Their possible Paleoproterozoic analogues can be found in the Svecofennian belt (Outokumpu ore district), while modern ones are confined to the Explorer and Endeavour Ridges and southern segment of the Juan de Fuca Ridge.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.