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91.
Stratigraphy of total metals in PIRLA sediment cores 总被引:1,自引:0,他引:1
Stephen A. Norton Ray W. Bienert Jr. Michael W. Binford Jeffrey S. Kahl 《Journal of Paleolimnology》1992,7(3):191-214
Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by 210Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO2, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm–2 yr–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO2 as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO2 from the atmosphere varies and is a significant fraction of the total flux of TiO2 to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series. 相似文献
92.
Autumn Oczkowski Scott Nixon Kelly Henry Peter DiMilla Michael Pilson Stephen Granger Betty Buckley Carol Thornber Richard McKinney Joaquin Chaves 《Estuaries and Coasts》2008,31(1):53-69
Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one
of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage
treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third
or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary
(macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ15N) and carbon (δ13C). The δ15N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source
loading. There is also evidence of a west to east gradient of heavy to light values of δ15N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett
Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ15N values in macroalgae there reflected preferential uptake of 14N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of
dissolved C species may control the observed δ13C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ15N (13.2 ± 0.54‰ SD) and δ13C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ15N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a
food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate
that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources. 相似文献
93.
Martin Rosner Michael Wiedenbeck Thomas Ludwig 《Geostandards and Geoanalytical Research》2008,32(1):27-38
An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated. 相似文献
94.
Jeremy M. Testa W. Michael Kemp Walter R. Boynton James D. Hagy III 《Estuaries and Coasts》2008,31(6):1021-1037
We conducted a quantitative assessment of estuarine ecosystem responses to reduced phosphorus and nitrogen loading from sewage
treatment facilities and to variability in freshwater flow and nonpoint nutrient inputs to the Patuxent River estuary. We
analyzed a 19-year dataset of water quality conditions, nutrient loading, and climatic forcing for three estuarine regions
and also computed monthly rates of net production of dissolved O2 and physical transport of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) using a salt- and water-balance model.
Point-source loading of DIN and DIP to the estuary declined by 40–60% following upgrades to sewage treatment plants and correlated
with parallel decreases in DIN and DIP concentrations throughout the Patuxent. Reduced point-source nutrient loading and concentration
resulted in declines in phytoplankton chlorophyll-a (chl-a) and light-saturated carbon fixation, as well as in bottom-layer O2 consumption for upper regions of the estuary. Despite significant reductions in seaward N transport from the middle to lower
estuary, chl-a, turbidity, and surface-layer net O2 production increased in the lower estuary, especially during summer. This degradation of water quality in the lower estuary
appears to be linked to a trend of increasing net inputs of DIN into the estuary from Chesapeake Bay and to above-average
river flow during the mid-1990s. In addition, increased abundance of Mnemiopsis leidyi significantly reduced copepod abundance during summer from 1990 to 2002, which favored increases in chl-a and allowed a shift in total N partitioning from DIN to particulate organic nitrogen. These analyses illustrate (1) the value
of long-term monitoring data, (2) the need for regional scale nutrient management that includes integrated estuarine systems,
and (3) the potential water quality impacts of altered coastal food webs. 相似文献
95.
There has been increasing concern about the lack of involvement by social scientists and humanists in a global change program,
although many social scientists are already directly involved in various aspects of research on environmental change, and
their research interests are clearly central to a global change research agenda. Based on a historical review, the role of
social science disciplines as well as social science institutes in an emerging multidecadal global change program is discussed.
Both “plan of action” and “plan of inaction” are suggested to avoid potential pitfalls due to the rush development of a social
science program into the existing global climate change problem. 相似文献
96.
97.
We present an updated model for the photochemistry of Io's atmosphere and ionosphere and use this model to investigate the sensitivity of the chemical structure to vertical transport rates. SO2is assumed to be the dominant atmospheric gas, with minor molecular sodium species such as Na2S or Na2O released by sputtering or venting from the surface. Photochemical products include SO, O2, S, O, Na, NaO, NaS, and Na2. We consider both “thick” and “thin” SO2atmospheres that encompass the range allowed by recent HST and millimeter-wave observations, and evaluate the possibility that O2and/or SO may be significant minor dayside constituents and therefore likely dominant nightside gases. The fast reaction between S and O2limits the column abundance of O2to ∼104less than that calculated by Kumar (J. Geophys. Res.87, 1677–1684, 1982; 89(A9), 7399–7406, 1984) for a pure sulfur/oxygen atmosphere. If a significant source of NaO2or Na2O were supplied by the surface and mixed rapidly upward, then oxygen liberated in the chemical reactions which also liberate free Na would provide an additional source of O2. Fast eddy mixing will enhance the transport of molecular sodium species to the exobase, in addition to increasing the vertical transport rate of ions. Ions produced in the atmosphere will be accelerated by the reduced corotation electric field penetrating the atmosphere. These ions experience collisions with the neutral gas, leading to enhanced vertical ion diffusion. The dominant ion, Na+, is lost primarily by charge exchange with Na2O and/or Na2S in the lower atmosphere and by diffusion through the ionopause in the upper atmosphere. The atmospheric column abundance of SO, O2, and the upper atmosphere escape rates of Na, S, O, and molecular sodium species are all strong functions of the eddy mixing rate. Most atmospheric escape, including that of molecular sodium species, probably occurs from the low density “background” SO2atmosphere, while a localized high density “volcanic” SO2atmosphere can yield an ionosphere consistent with that detected by the Pioneer 10 spacecraft. 相似文献
98.
The sensitivity of the development of the convective planetary boundary layer (PBL) and the surface layer are examined using a coupled surface parameterization and detailed PBL model. First, the coupling is verified against observations from the First ISLSCP (International Satellite Land Surface Climatology Project) Field Experiment (FIFE). Results of the sensitivity experiments indicate that the PBL is most sensitive to the amount of soil water content, and the proximity of the soil water content to critical soil texture values (field capacity and wilting point). While vegetation cover is not the most sensitive parameter at the surface, its influence on the surface energy and hydrologic balance is crucial. Model sensitivity to minimum stomatal resistance, type of soil parameterization and canopy height (surface roughness and displacement depth) is also discussed. 相似文献
99.
The Bureau of Economic Analysis (BEA), U.S. Department of Commerce, in keeping with broad international efforts to green national gross domestic product (GDP) accounts, has attempted to create satellite accounts for mineral depletion. The present paper criticizes the BEA's unit rent measure of resource depletion, which is based upon Hotelling's pure theory of exhaustion. Following a thorough criticism of Hotelling's theory as a real-world model of mineral prices, practical issues related to the treatment of recycling, exploration, definition of reserves/resources, and their valuation/exploitation are introduced. For crude oil and natural gas and the nonfuel minerals, specific application problems of joint products and residuals complicate BEA's assumptions and efforts. 相似文献
100.
Biswajit Mukhopadhyay Michael J. Holdaway 《Contributions to Mineralogy and Petrology》1994,116(4):462-472
The equilibrium in which hydrous Fe-cordierite breaks down to almandine, sillimanite, quartz, and water was previously experimentally determined by Richardson (1968) and Holdaway and Lee (1977) using QMF buffer and by Weisbrod (1973) using QIF buffer. All these studies yielded similar results — a negative dP/dT slope for the equilibrium curve. However, based on theoretical arguments, Martignole and Sisi (1981), and based on Fe-Mg partitioning experiments on coexisting cordierite and garnet in equilibrium with sillimanite and quartz, Aranovich and Podlesskii (1983) suggested that this equilibrium curve has a positive dP/dT slope and its position depends on the water content of the equilibrium cordierite. We have redetermined this equilibrium using a much improved tecnique of detecting reaction direction, and cordierite starting material that contained virtually no hercynite. Hercynite was present as a contaminant in the cordierites of previous experimental studies and possibly reacted with quartz during the experimental runs to expand the apparent stability field of Fe-cordierite. We synthesized Fe-cordierite from reagent grade oxides at 710°C and 2 kbar (using QMF buffer) with two intermediate stages of grinding and mixing. The cordierite has a unit cell volume of 1574.60 Å3 (molar volume=23.706 J/bar) and no Fe3+ as indicated by X-ray diffraction and room temperature Mössbauer studies respectively. Reaction direction was concluded by noting20% change of the ratios of intensities of two key X-ray diffraction peaks of cordierite and almandine. Our results show that the four-phase equilibrium curve passes through the points 2.1 kbar, 650°C and 2.5 kbar, 750°C. This disagrees with all previous experimental studies. H2O in the Fe-cordierite, equilibrated at 2.2 kbar and 700°C and determined by H-extraction line in the stable isotope laboratory, is 1.13 wt% (n=0.41 moles). H2O content of pure Mg-cordierite equilibrated under identical conditions and determined by thermogravimentric conditions and determined by thermogravimetric analysis is 1.22 wt% (n=0.40). Similar determinations on Fe-cordierite and Mg-cordierite equilibrated at 2.0 kbar and 650°C show 1.27 wt% (n=0.46) and 1.47 wt% (n=0.48) of H2O respectively. Thus, H2O content appears to be independent of Fe/Mg ratio in cordierite, a conclusion which supports previous experimental determinations. The experimentally determined equilibrium curve represents conditions of PH2O=Ptotal. From this we calculated the anhydrous curve representing equilibrium under conditions of X
H2O
V
=0.0. A family of calculated equilibrium curves of constant n
H2O
Cord
cut the experimentally determined curve at a very small angle indicating a slight variation in n
H2O
Cord
in cordierite in equilibrium with almandine, sillimanite, and quartz under the conditions of constant X
H2O
V
. Ancther set of calculated equilibrium curves, each representing constant a
H2O
V
demonstrate that the slopes of the curves vary with X
H2O
V
, and are all positive in the full range of 0.0X
H2O
V
1.0. 相似文献