In situ Raman observation of the crystallization in NaNO3–Na2SO4–H2O solution droplets

Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO₃–Na₂SO₄ system including the formation of the double salt darapskite, Na₃NO₃SO₄·H₂O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na₂SO₄(III), Na₂SO₄(V) and darapskite. The experimental observations are discussed on the basis of the NaNO₃–Na₂SO₄–H₂O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures.     

Magnetic field measurements of CP stars from hydrogen line cores

We present the results of measurements of magnetic fields of chemically peculiar (CP) stars, performed from the shifts between the circularly polarized components of metal and hydrogen lines (the Babcock method). The observations are carried out with an analyzer of circular polarization at the 6‐m telescope of the SAO RAS. We found that for the absolute majority of the objects studied (in 22 CP stars out of 23), the magnetic fields, determined from the Zeeman shifts in the hydrogen line cores, are significantly lower than those obtained from metal lines in the same spectra. This disparity varies between the stars. We show that instrumental effects can not produce the above features, and discuss the possible causes of the observed effect. The discovered condition reveals a more complicated structure of magnetic fields of CP stars than a simple dipole, in particular, a reduction of the field strength in the upper atmosphere with the vertical gradient, significantly higher than the dipole (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Spread <Emphasis Type="Italic">F</Emphasis> in the Midlatitude Ionosphere According to DPS-4 Ionosonde Data

The results of studying spread F obtained from the DPS-4 ionosonde data at the observatory of the Pushkov Institute of Terrestrial Magnetism, Ionosphere, and Radio Wave Propagation (Moscow) are presented. The methodical questions that arise during the study of a spread F phenomenon in the ionosphere are considered; the current results of terrestrial observations are compared with previously published data and the results of sounding onboard an Earth-satellite vehicle. The automated algorithm for estimation of the intensity of frequency spread F, which was developed by the authors and was successfully verified via comparison of the data of the digisonde DPS-4 and the results of manual processing, is described. The algorithm makes it possible to quantify the intensity of spread F in megahertz (the dFs parameter) and in the number of points (0, 1, 2, 3). The strongest spread (3 points) is shown to be most likely around midnight, while the weakest spread (0 points) is highly likely to occur during the daytime. The diurnal distribution of a 1–2 point spread F in the winter indicates the presence of additional maxima at 0300–0600 UT and 1400–1700 UT, which may appear due to the terminator. Despite the large volume of processed data, we can not definitively state that the appearance of spread F depends on the magnetic activity indices Kp, Dst, and AL, although the values of the dFs frequency spread interval strongly increased both at day and night during the magnetic storm of March 17–22, 2015, especially in the phase of storm recovery on March 20–22.     

Sources and sinks for atmospheric H2: A current analysis with projections for the influence of anthropogenic activity

Oxidation of CH₄ provides the major source for atmospheric H₂ which is removed mainly by reaction with OH. Biological activity at the Earth's surface appears to represent at most a minor sink for H₂. Anthropogenic activity is a significant source for both H₂ and CO in the present atmosphere and may be expected to exert a growing influence in the future. Models are presented which suggest a rise in the mixing ratio of H₂ from its present value of 5.6 × 10^?7 to about 1.8 × 10^?6 by the year 2100. The mixing ratio of CO should grow from 9.7 × 10^?8 to 2.3 × 10^?7 over the same time period and there should be a rise in CH₄ by about a factor of 1.5 associated with anthropogenically induced reductions in tropospheric OH.     

New calculations of interstellar dust (ID) contraction in a non-isothermal regime

We have calculated the opacity as resulting from different interstellar grain models, molecules, atoms, and ions. The resulting opacities have been applied to a numerical code used to follow the thermal evolution of a contracting cloud in one dimension. An exact analytical and computational developments of both Mie theory for isolated grains and Güttler's formulae for composite grain models have been used to calculate the extinction coefficients. We have studied two models of composite grain and three models of isolated grain. The opacity of interstellar grains has been calculated in the temperature range 10–1500 K. The molecular opacity is splitted into continuous and line opacities. The different sources of continuous opacity have been studied. The line opacity has also been included. The atomic opacities are also considered. The hydrodynamical equations are solved explicitly but the energy and Poisson equations are solved implicitly.It has been found that the thermal evolution during contraction of protostellar clouds is sensitive to both: the assumed grain models and the considered chemical composition. A cloud of an initial temperature of 10 K collapsed to a stage in which the temperature increases to 91 000 K and the density reached to 0.16 g cm^–3.     

EURONEAR—Recovery, follow-up and discovery of NEAs and MBAs using large field 1–2 m telescopes

We report on the follow-up and recovery of 100 program NEAs, PHAs and VIs using the ESO/MPG 2.2 m, Swope 1 m and INT 2.5 m telescopes equipped with large field cameras. The 127 fields observed during 11 nights covered 29 square degrees. Using these data, we present the incidental survey work which includes 558 known MBAs and 628 unknown moving objects mostly consistent with MBAs from which 58 objects became official discoveries. We planned the runs using six criteria and four servers which focus mostly on faint and poorly observed objects in need of confirmation, follow-up and recovery. We followed 62 faint NEAs within one month after discovery and we recovered 10 faint NEAs having big uncertainties at their second or later opposition. Using the INT we eliminated four PHA candidates and VIs. We observed in total 1286 moving objects and we reported more than 10,000 positions. All data were reduced by the members of our network in a team effort, and reported promptly to the MPC. The positions of the program NEAs were published in 27 MPC and MPEC references and used to improve their orbits. The O−C residuals for known MBAs and program NEAs are smallest for the ESO/MPG and Swope and about four times larger for the INT whose field is more distorted. For the astrometric reduction, the UCAC-2 catalog is recommended instead of USNO-B1. The incidental survey allowed us to study statistics of the MBA and NEA populations observable today with 1–2 m facilities. We calculate preliminary orbits for all unknown objects, classifying them as official discoveries, later identifications and unknown outstanding objects. The orbital elements a, e, i calculated by FIND_ORB software for the official discoveries and later identified objects are very similar with the published elements which take into account longer observational arcs; thus preliminary orbits were used in statistics for the whole unknown dataset. We present a basic model which can be used to distinguish between MBAs and potential NEAs in any sky survey. Based on three evaluation methods, most of our unknown objects are consistent with MBAs, while up to 16 unknown objects could represent NEO candidates and four represent our best NEO candidates. We assessed the observability of the unknown MBA and NEA populations using 1 and 2 m surveys. Employing a 1 m facility, one can observe today fewer unknown objects than known MBAs and very few new NEOs. Using a 2 m facility, a slightly larger number of unknown than known asteroids could be detected in the main belt. Between 0.1 and 0.8 new NEO candidates per square degree could be discovered using a 2 m telescope.     

The Dar al Gani meteorite field (Libyan Sahara): Geological setting,pairing of meteorites,and recovery density

Abstract— As of July 2001, 1238 Libyan meteorites have been reported. Most were found in two areas called Dar al Gani and Hamadah al Hamra. Dar al Gani is located on a plateau of marine carbonate rocks with marly components. Eight‐hundred and sixty‐nine meteorites between 6 g and 95 kg totalling 687 kg have been found here but the calculated mean recovery density is comparatively low with one meteorite on 6.5 km². Dar al Gani is a perfect site for the recognition and preservation of meteorites. The existence of meteorites is the result of a combination of specific geological and geomorphological conditions: there is a bright‐colored, old limestone plateau (<2 Ma), under arid weather conditions over long periods of time, with rapid elimination of surface water if present and low erosion rates. The preservation of meteorites is guaranteed through the absence of quartz sand on the plateau, strongly reducing wind erosion and a basic environment emerging from the carbonate ground retards rusting of metallic meteorite components. A supposed soil cover during pluvial times has probably protected older meteorites and led to a concentration of meteorites of different periods. An evaluation of Dar al Gani meteorites suggests the existence of at least 26 strewnfields and 26 meteorite pairs reducing the number of falls to, at most, 534. Shock and weathering grades as a tool for the recognition of pairings turned out to be problematic, as several strewnfields showed paired meteorites which had been classified to different shock and weathering grades.     

Novae in M31 in 1999–2005

We present the results of our study of 19 novae in the galaxy M31 on photographs taken with wide-field telescopes in 1999–2005. Two of the six novae discovered in our program (ShA 65 and ShA 67) have been identified with supersoft X-ray sources, the discovery of one nova (ShA 69) was reported in IAU Circulars, and the other three novae (ShA 66, ShA 68, and ShA 70) are reported for the first time.     

Stars with Discrepant <Emphasis Type="Italic">v</Emphasis> sin <Emphasis Type="Italic">i</Emphasis> as Derived from the Ca II 3933 and Mg II 4481 Å Lines. VII. HD9531 (SB), HD31592 (SB2), HD129174 (SB?)

In this paper of the series we analyze three stars listed among stars with discrepant v sin i: HD9531 and HD31592, which also show radial velocity variations inherent to spectroscopic binaries, and HD129174 which is an Mn-type star with a possible magnetic field. In HD9531 we confirm the radial velocity derived fromthe hydrogen lines as well as fromthe Ca II line at 3933 Å as variable. The profile of the calcium line also appears variable, and with the estimated magnetic induction B_e = ?630 ± 1340 G, this suggests that the abundance of calcium possibly varies over the surface of the star. We identified the lines of the secondary component in the spectrum of HD31592 revealing thus it is an SB2 binary with B9.5V and A0V components. While the primary star rotates with v sin i = 50 km s^?1, the secondary star is faster with v sin i = 170 km s^?1. We find that only 60% of the Mn lines identified in the spectrum of HD129174 can be fitted with a unique abundance value, whereas the remaining lines are stronger or fainter. We also identified two Xe II lines at 5339.33 Å and 5419.15 Å and estimated their log g f.