The Zn abundance and isotopic composition of diatom frustules,a proxy for Zn availability in ocean surface seawater

We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ⁶⁶Zn (reported relative to the JMC_Lyon standard) and Zn/Si ratios from the Southern Ocean diatom_opal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ⁶⁶Zn compositions of the diatom_opal core-top samples is, similarly, likely to reflect changes in the δ⁶⁶Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatom_opal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatom_opal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO₂ on glacial–interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.     

Asteroid 21 Lutetia at 3 μm: Observations with IRTF SpeX

We present observations of Asteroid 21 Lutetia collected 2003–2008 using the SpeX instrument on the NASA Infrared Telescope Facility (IRTF) covering 2–4 μm. We also reevaluate NSFCam observations obtained in 1996 (Rivkin, A.S., Lebofsky, L.A., Clark, B.E., Howell, E.S., Britt, D.T. [2000]. Icarus 145, 351–368). Taken together, these show deeper 3-μm band depths (of order 3–5%) in the southern hemisphere of Lutetia, and shallower band depths (of order 2% or less) in the north. Such variation is consistent with observations at shorter wavelength by previous workers (Nedelcu, D.A. et al. [2007]. Astron. Astrophys. 470, 1157–1164; Lazzarin, M. et al. [2010]. Mon. Not. R. Astron. Soc. 408, 1433–1437), who observed hemispheric-level variations from C-like spectra to X-like spectra.While the shallowness of absorption bands on Lutetia hinders identification of its surface composition, goethite appears plausible as a constituent in its southern hemisphere (Beck, P., Quirico, E., Sevestre, D., Montes-Hernandez, G., Pommerol, A., Schmitt, B. [2011]. Astron. Astrophys. 526, A85–A89). Mathematical models of space weathered goethite are most consistent with Lutetia’s southern hemisphere spectrum, but more work and further observations are necessary to confirm this suggestion.     

Tracking embodied carbon flows in the Belt and Road regions

In the past few decades, economic globalization has driven rapid growth of cross-border trade and a new international division of labor, leading to increasing inter- country embodied carbon flows. Multi-region input-output (MRIO) analysis is used to identify embodied carbon flows between major world regions, including seven regions along the Belt and Road (BR), and the spatial distribution of production- and consumption-based carbon intensities. The results show that current embodied carbon flows are virtually all from BR regions to developed countries, with more than 95% of world net embodied carbon exports coming from BR regions. Consumption in the United States and European Union countries induce about 30% of the carbon emissions in most BR regions, indicating that the former bear a high proportion of consumers’ responsibility for the carbon emitted in the latter. For this reason, measuring environmental responsibilities from consumption rather than a production- based perspective is more equitable, while developing countries should be given a louder voice in the construction through dialogue and cooperation, in part in the context of the Belt and Road Initiative, of an inclusive global climate governance system.     

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.     

Mineralogical characterization of potential targets for the ASTEX mission scenario

In-situ investigation of asteroids is the next logical step in understanding their exact surface mineralogy, petrology, elemental abundances, particle size distribution, internal structure, and collisional evolution. Near-Earth asteroids (NEAs) provide us with ample opportunities for in-situ scientific exploration with lower Δv requirements and subsequently lower costs than their main belt counterparts. The ASTEX mission concept aims at surface characterization of two compositionally diverse NEAs, one with primitive and the other with a strong thermally evolved surface mineralogy. Here we present the first results of our ground-based characterization of potential ASTEX mission targets using the SpeX instrument on the NASA IRTF. Of the four potential targets we characterized, two (1991 JW and 1998 PA) have compositions similar to ordinary chondrite mineralogy. The other two targets (1994 CC and 1999 TA10) are thermally evolved objects with igneous formation histories. While 1994 CC is a triplet system and thus very challenging to orbit the V-type NEA, 1999 TA10 is the most interesting scientific ASTEX target identified so far.     

Quasi-exospheric heat flux of solar-wind electrons

Density, bulk-velocity, and heat-flow moments are calculated for truncated maxwellian distributions representing the cool and hot populations of solar-wind electrons, as realized at the base of a hypothetical exosphere. The electrostatic potential is thus calculated by requiring charge quasineutrality and the absence of electrical current. Plasma-kinetic coupling of the cool-electron and proton bulk velocities leads to an increase in the electrostatic potential and a decrease in the heat-flow moment. If the velocities differ by the Alfvén speed along the magnetic field, for example, the potential rises to 72.6 V and the heat flux falls to 2.72×10^–2 erg cm^–2 s^–1. In each case the heat flux is carried mainly by the quasi-exospherichot electrons.     

Nickeliferous sulfides in xenoliths,olivine megacrysts and basaltic glass

The composition of olivine and nickeliferous sulfide inclusions from a selection of mafic and ultramafre rocks, xenoliths and megacrysts, including picritic basalts from Kilauea Volcano, Hawaii, kimberlite from Fayette County, Pennsylvania, and megacrysts from Mount Shasta, California are compared with the mean experimental value of the distribution coefficient for Ni/Fe exchange (K_D3=32). Only nine of the forty five olivipe/bulk-sulfide pairs investigated have compositions consistent with equilibration at high temperature, yielding calculated K_D3 values in the range 22 to 41. The remaining pairs have calculated K_D3 values which range from 0 to 19. Bulk-sulfides in disequilibrated assem-blages are consistently depleted in nickel and within both indivudual associations and individual petrographic sections they exhibit a wide variation in NiS content. The bulk copper contents of olivine-and groundmass-hosted sulfides from Kilauea Volcano range from 0.5 to 43 at%, and samples from the Kilauea Iki lava lake are more Fe-and Cu-rich and generally have lower K_D3 values than those from the eruption itself. As with magmatic Ni–Cu sulfide deposits, most nickeliferous sulfide inclusions in mantle-related rocks and xenoliths and in volcanic rocks do not have pristine early-magmatic bulk compositions, and it would seem to be premature to attribute these sulfides solely to either a mantle or an early-magnatic origin.     

奥地利Gosau群Bibereck组Campanian早期海水变深序列的地层学和地球化学

Schmidsippl剖面位于奥地利北钙质阿尔卑斯构造带内Gosau群典型地区。剖面出露的Bibereck组记录了一个海侵和沉积区海水变深过程。Bibereck 组之下是Santonian 晚期Hochmoos 组(Sandkalkbank段),主要为砂质、粉砂质灰色生物扰动构造发育的泥灰岩,含少量双壳类碎片。Hochmoos组之上为灰色泥灰岩和泥灰质灰岩。Bibereck组下部显示变深到近滨-远滨过渡带区域;向上,泥灰岩指示细粒泥质远滨沉积,水深大致50~150 m;之上出现浮游有孔虫含量超过90%的泥灰质灰岩,代表着半深海沉积环境。生物地层数据显示采样层位整体位于浮游有孔虫asymetrica elevata 带,由Globotruncanita elevata 和Dicarinellaasymetrica 的共同出现来界定。钙质超微化石Calculites obscurus、Lucianorhabdus cayeuxii、Arkhangelsk iella cymbiformis 的出现指示属于钙质超微化石带CC17b/UC12,相当于Campanian初期。地层深度剖面上,Ca/Al比值和Catot含量显示海水来源的Ca在0~5 m地层内几近于零,向上快速增加;(Fe/Al)/碳酸盐显示两个峰值,代表更还原条件,分别位于4 m和10 m位置;K/Al比值的下降被解释为更潮湿气候条件;剖面上部Ba含量的增加显示向更低原始生产条件的变化;陆源矿物在剖面7 m以下保持稳定,之上一直到剖面顶部不断下降。生物地层