Constraining albedo,diameter and composition of near-Earth asteroids via near-infrared spectroscopy

We present a method to constrain the albedo and diameters of near-Earth asteroids (NEAs) based on thermal flux in their near-infrared spectra (0.7–2.5 μm) using the Standard Thermal Model. Near-infrared spectra obtained with the SpeX instrument on NASA Infrared Telescope Facility are used to estimate the albedo and diameters of 12 NEAs (1992 JE, 1992 UY4, 1999 JD6, 2004 XP14, 2005 YY93, 2007 DS84, 2005 AD13, 2005 WJ56, 1999 JM8, 2005 RC34, 2003 YE45, and 2008 QS11). Albedo estimates were compared with average albedo for various taxonomic classes outlined by Thomas et al. (Thomas, C.A. et al. [2011]. Astron. J. 142(3)) and are consistent with their results. Spectral band parameters, like band centers, are derived and compared to spectra of laboratory mineral mixtures and meteorites to constrain their composition and possible meteorite analogs. Based on our study we estimate the albedos and diameters of these NEAs and compare them with those obtained by other techniques such as ground-based mid-infrared, Spitzer thermal infrared and Arecibo radar. Our results are broadly consistent with the results from other direct methods like radar. Determining the compositions of low albedo asteroids is a challenge due to the lack of deep silicate absorption features. However, based on weak absorption features and albedo, we suggest possible meteorite analogs for these NEAs, which include black chondrites, CM2 carbonaceous chondrites and enstatite achondrites. We did not find any specific trends in albedo and composition among the asteroids we observed.     

Stratigraphic architecture of Solander Basin records Southern Ocean currents and subduction initiation beneath southwest New Zealand

Solander Basin is characterized by subduction initiation at the Pacific‐Australia plate boundary, where high biological productivity is found at the northern edge of the Antarctic Circumpolar Current. Sedimentary architecture results from tectonic influences on accommodation space, sediment supply and ocean currents (via physiography); and climate influence on ocean currents and biological productivity. We present the first seismic‐stratigraphic analysis of Solander Basin based on high‐fold seismic‐reflection data (voyage MGL1803, SISIE). Solander Trough physiography formed by Eocene rifting, but basinal strata are mostly younger than ca. 17 Ma, when we infer Puysegur Ridge formed and sheltered Solander Basin from bottom currents, and mountain growth onshore increased sediment supply. Initial inversion on the Tauru Fault started at ca. 15 Ma, but reverse faulting from 12 to ca. 8 Ma on both the Tauru and Parara Faults was likely associated with reorganization and formation of the subduction thrust. The new seabed topography forced sediment pathways to become channelized at low points or antecedent gorges. Since 5 Ma, southern Puysegur Ridge and Fiordland mountains spread out towards the east and Solander Anticline grew in response to ongoing subduction and growth of a slab. Solander Basin had high sedimentation rates because (1) it is sheltered from bottom currents by Puysegur Ridge; and (2) it has a mountainous land area that supplies sediment to its northern end. Sedimentary architecture is asymmetric due to the Subtropical Front, which moves pelagic and hemi‐pelagic sediment, including dilute parts of gravity flows, eastward and accretes contourites to the shelf south of Stewart Island. Levees, scours, drifts and ridges of folded sediment characterize western Solander Basin, whereas hemi‐pelagic drape and secondary gravity flows are found east of the meandering axial Solander Channel. The high‐resolution record of climate and tectonics that Solander Basin contains may yield excellent sites for future scientific ocean drilling.     

Doppler Images of ζ Andromedae

Doppler images are presented for the RS CVn-type binary ζ And. Our upgraded Doppler imaging code TempMap_ε takes into account the distorted geometry of the primary giant component. On the maps several low latitude spots are restored with a temperature contrast of about 1000 K. Some weak polar features are also found. Cross-correlation of the consecutive Doppler-maps suggests solar-like differential surface rotation.     

Magma at depth: a retrospective analysis of the 1975 unrest at Mount Baker,Washington, USA

Mount Baker volcano displayed a short interval of seismically-quiescent thermal unrest in 1975, with high emissions of magmatic gas that slowly waned during the following three decades. The area of snow-free ground in the active crater has not returned to pre-unrest levels, and fumarole gas geochemistry shows a decreasing magmatic signature over that same interval. A relative microgravity survey revealed a substantial gravity increase in the ~30 years since the unrest, while deformation measurements suggest slight deflation of the edifice between 1981–83 and 2006–07. The volcano remains seismically quiet with regard to impulsive volcano-tectonic events, but experiences shallow (<3 km) low-frequency events likely related to glacier activity, as well as deep (>10 km) long-period earthquakes. Reviewing the observations from the 1975 unrest in combination with geophysical and geochemical data collected in the decades that followed, we infer that elevated gas and thermal emissions at Mount Baker in 1975 resulted from magmatic activity beneath the volcano: either the emplacement of magma at mid-crustal levels, or opening of a conduit to a deep existing source of magmatic volatiles. Decadal-timescale, multi-parameter observations were essential to this assessment of magmatic activity.     

Probing mid-mantle heterogeneity using PKP coda waves

We investigate the utility of PKP coda waves for studying weak scattering from small-scale heterogeneity in the mid-mantle. Coda waves are potentially a useful probe of heterogeneity in the mid-mantle because they are not preferentially scattered near the CMB, as PKP precursors are, but are sensitive to scattering at all depths. PKP coda waves have not been used for this purpose historically because of interference with other late-arriving energy due to near-surface resonance and scattering. Any study of deep mantle scattering using coda waves requires the removal of near-surface effects from the data. We have analyzed 3624 recordings of PKP precursors and coda made by stations in the Incorporated Research Institutions for Seismology (IRIS) Global Seismographic Network (GSN). To study the range and time dependence of the scattered waves, we binned and stacked envelopes of the recordings. We have considered precursors that arrive within a 20 s window before PKP and coda waves in a 60 s window after PKP. The PKP scattered waves increase in amplitude rapidly with range as predicted by scattering theory. At ranges below 125°, we predict and observe essentially no scattered energy preceding PKP. Coda amplitudes at these ranges are independent of range and provide an estimate of energy due to near-surface effects that we can expect at all ranges. We use the average coda amplitude at ranges from 120 to 125° to correct coda amplitudes at other ranges. PKP coda waves show a strong dependence on time and range and are clearly influenced by scattering in the lower mantle. PKP coda waves, however, do not provide a tighter constraint on the vertical distribution of mantle heterogeneity than is provided by precursors. This is due, in part, to relatively large scatter in coda amplitudes as revealed by a resampling analysis. Modeling using Rayleigh–Born scattering theory and an exponential autocorrelation function shows that PKP coda amplitudes are not highly sensitive to the vertical distribution of heterogeneity in the mantle. To illustrate this we consider single-scattering in two extreme models of mantle heterogeneity. One allows heterogeneity just at the CMB; the other includes heterogeneity throughout the mantle. The amplitudes of precursors are tightly constrained by our stack and support our earlier conclusion that small-scale heterogeneity is uniformly distributed throughout the lower mantle. The best-fit model includes 8 km scale length heterogeneity with an rms velocity contrast throughout the mantle of 1%.     

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.     

Evaluation of an empirical orthogonal function–based method to downscale soil moisture patterns based on topographical attributes

Soil moisture influences many hydrologic applications including agriculture, land management and flood prediction. Most remote‐sensing methods that estimate soil moisture produce coarse resolution patterns, so methods are required to downscale such patterns to the resolutions required by these applications (e.g. 10‐ to 30‐m grid cells). At such resolutions, topography is known to affect soil moisture patterns. Although methods have been proposed to downscale soil moisture based on topography, they usually require the availability of past high‐resolution soil moisture patterns from the application region. The objective of this article is to determine whether a single topographic‐based downscaling method can be used at multiple locations without relying on detailed local observations. The evaluated downscaling method is developed on the basis of empirical orthogonal function (EOF) analysis of space–time soil moisture data at a reference catchment. The most important EOFs are then estimated from topographic attributes, and the associated expansion coefficients are estimated on the basis of the spatial‐average soil moisture. To test the portability of this EOF‐based method, it is developed separately using four data sets (Tarrawarra, Tarrawarra 2, Cache la Poudre and Satellite Station), and the relationships that are derived from these data sets to estimate the EOFs and expansion coefficients are compared. In addition, each of these downscaling methods is applied not only for the catchment where it was developed but also to the other three catchments. The results suggest that the EOF downscaling method performs well for the location where it is developed, but its performance degrades when applied to other catchments. Copyright © 2011 John Wiley & Sons, Ltd.     

Low‐P and high‐T metamorphism of basalts: Insights from the Sudbury impact melt sheet aureole and thermodynamic modelling

Low‐pressure and high‐temperature (LP–HT) metamorphism of basaltic rocks, which occurs globally and throughout geological time, is rarely constrained by forward phase equilibrium modelling, yet such calculations provide valuable supplementary thermometric information and constraints on anatexis that are not possible to obtain from conventional thermometry. Metabasalts along the southern margin of the Sudbury Igneous Complex (SIC) record evidence of high‐grade contact metamorphism involving partial melting and melt segregation. Peak metamorphic temperatures reached at least ~925°C at ~1–3 kbar near the SIC contact. Preservation of the peak mineral assemblage indicates that most of the generated melt escaped from these rocks leaving a residuum characterized by a plagioclase–orthopyroxene–clinopyroxene–ilmenite‐magnetite±melt assemblage. Peak temperatures reached ~875°C up to 500 m from the SIC lower contact, which marks the transition to metabasalts that only experienced incipient partial melting without melt loss. Metabasalts ~500 to 750 m from the SIC contact are characterized by a similar two‐pyroxene mineral assemblage, but typically contain abundant hornblende that overgrew clino‐ and orthopyroxene along an isobaric cooling path. Metabasalts ~750 to 1,000 m from the SIC contact are characterized by a hornblende–plagioclase–quartz–ilmenite assemblage indicating temperatures up to ~680°C. Mass balance and phase equilibria calculations indicate that anatexis resulted in 10–20% melt generation in the inner ~500 m of the aureole, with even higher degrees of melting towards the contact. Comparison of multiple models, experiments, and natural samples indicates that modelling in the Na₂O–CaO–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCFMASHTO) system results in the most reliable predictions for the temperature of the solidus. Incorporation of K₂O in the most recent amphibole solution model now successfully predicts dehydration melting by the coexistence of high‐Ca amphibole and silicate melt at relatively low pressures (~1.5 kbar). However, inclusion of K₂O as a system component results in prediction of the solidus at too low a temperature. Although there are discrepancies between modelling predictions and experimental results, this study demonstrates that the pseudosection approach to mafic rocks is an invaluable tool to constrain metamorphic processes at LP–HT conditions.     

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.