Quaternary changes in delivery and accumulation of organic matter in sediments of Lake Biwa, Japan

A 911-m-long sediment core from Lake Biwa, Japan, provides a record of organic matter delivery and accumulation in this large lake during a succession of tectonic and climatic changes dating back to the latest Pliocene. Sediments deposited since 430 ky are profundal; older sediments vary in setting between shallow-water and fluviodeltaic conditions, with occasional deep-water intervals. C/N ratios identify algal production as the dominant source of organic matter throughout the core, although the proportion of land-derived contributions episodically increases in the fluviodeltaic and shallow-water sediments. Rates of organic matter delivery and burial in lake sediments change in response to glacial-interglacial climate changes over the past 430 ky. Sediments deposited during interglacial intervals have organic carbon mass accumulation rates up to 9 times greater than those from glacial intervals, reflecting interglacial climates that were wetter than glacial climates. Algal production of organic matter increased during interglacial times because of greater wash-in of soil nutrients, and organic matter preservation was enhanced because of faster sedimentation rates.     

Organic matter on clay minerals and marine sediments — effect on adsorption of dissolved copper,phosphate, and lipids from saline solutions

Adsorption of dissolved copper and phosphate by natural and peroxide-treated marine sediments was compared. A three-fold increase in copper adsorption and a six-fold increase in phosphate adsorption was caused by the peroxide treatment. Indigenous organic matter evidently interferes with adsorption.Clay minerals coated with heptadecanoic acid adsorbed somewhat less copper, phosphate, and hexadecane than uncoated clays, but slightly more nonadecanoic acid and anthracene.     

Insights into deposition of Lower Cretaceous black shales from meager accumulation of organic matter in Albian sediments from ODP site 763, Exmouth Plateau,Northwest Australia

The amount and type of organic matter present in an exceptionally complete upper Aptian to lower Cenomanian sequence of sediments from ODP site 763 on the Exmouth Plateau has been determined. Organic carbon concentrations average 0.2%. Organic matter is marine in origin, and its production and preservation was low over the ca. 20-million-year interval recorded by this sequence. Because this section was tectonically isolated from mainland Australia in the early Aptian, it better represents global oceanic conditions than the many basin-edge locations in which Albian-age black shales have been found. Formation of the basin-edge black shales evidently resulted from rapid, turbiditic burial of organic matter rather than from enhanced oceanic production or from basin-wide anoxia during the Albian.     

Early diagenesis in rapidly accumulating sediments on the Alboran slope, ODP site 976

 The oxidation and reduction that occur during early diagenesis of sediments has been studied in the interstitial waters of a rapidly accumulating sedimentary sequence from the Mediterranean margin of Spain. A series of reactions that are mediated by progressively lower free energy derived from oxidation of organic matter is evident in the sedimentary sequence. Iron and manganese are rapidly reduced. Phosphate and alkalinity maxima at a subbottom depth of 15 m indicate maximal organic matter degradation. Methane first appears at ∼20 m subbottom after sulfate is depleted, and its concentrations quickly climb. Received: 27 October 1997 / Revision received: 4 March 1998     

A more accurate scheme for calculating Earth’s skin temperature

The theoretical framework of the vertical discretization of a ground column for calculating Earth’s skin temperature is presented. The suggested discretization is derived from the evenly heat-content discretization with the optimal effective thickness for layer-temperature simulation. For the same level number, the suggested discretization is more accurate in skin temperature as well as surface ground heat flux simulations than those used in some state-of-the-art models. A proposed scheme (“op(3,2,0)”) can reduce the normalized root–mean–square error (or RMSE/STD ratio) of the calculated surface ground heat flux of a cropland site significantly to 2% (or 0.9 W m^?2), from 11% (or 5 W m^?2) by a 5-layer scheme used in ECMWF, from 19% (or 8 W m^?2) by a 5-layer scheme used in ECHAM, and from 74% (or 32 W m^?2) by a single-layer scheme used in the UCLA GCM. Better accuracy can be achieved by including more layers to the vertical discretization. Similar improvements are expected for other locations with different land types since the numerical error is inherited into the models for all the land types. The proposed scheme can be easily implemented into state-of-the-art climate models for the temperature simulation of snow, ice and soil.     

Bioaccumulation and histopathological effects of oil on a stony coral

Colonies of the shallow-water Caribbean coral Manicina areolata incorporated petroleum hydrocarbons into their tissues during exposure to water accommodated fractions of No. 2 fuel oil for three months. This contamination was not removed after depuration periods of up to two weeks. Although these corals remained alive, evidence of pathological responses was found which included impaired development of reproductive tissues, degeneration and loss of symbiotic zooxanthellae, and atrophy of mucous secretory cells and muscle bundles.     

Optimal annual operation of a water supply and distribution system

A model for determining the optimal operation of Israel's National Water System over 1 year, with monthly time increments, is described. The water system contains the Main National Carrier — some 250 km long from the Kinneret (Sea of Galillee) in the north to the Negev region in the south — and some 25 regional water systems connected to it. Water is taken from the Kinneret and from two aquifers. Water transfers may take place between the National Carrier and regional systems, and between interconnected regional systems.The mathematical model of the system represents its monthly production and transfer capacities. Given the monthly demands which have to be met and the hydraulic constraints the model determines the month-by-month operating plan which minimizes energy costs over the year.The optimization model is formulated as a linear program. This necessitates several types of approximations and linearizations, which are discussed in detail. The optimal operating plan for 1977–78 is compared with the actual operation of that year and conclusions are drawn from the comparison concerning the practicality and adequacy of the model's output and the potential for effective operation and for energy savings.     

Fatty acids and hydrocarbons in surficial sediments of Lake Huron

Fatty acid and hydrocarbon distributions in surficial sediments from ten locations in southern Lake Huron indicate both aquatic and terrigenous recent biological sources of these geolipid materials. Normal alkanoic acids appear to be derived primarily from aquatic sources whereas normal alkanes are from multiple origins. Geolipid distributions are determined by the nature of the biogenic source and are modified during transport and deposition. Sediments receiving urban runoff in Saginaw Bay contain large amounts of non-biogenic hydrocarbons of a petroleum or industrial nature.     

Characterization of sedimentary humic matter by alkaline hydrolysis

Humic matter fractions from modern sediments of Lake Huron and Lake Michigan have been compared. Large yields of saccharinic acids from alkaline hydrolysis suggest that these fractions contain large portions of carbohydrate materials. Evidence for contributions of aquatic lipid (C-16 fatty acids) and of liginin (phenolic acids) to these sediments is also present in the hydrolysis products. Qualitative differences among fulvic acid, humic acid and humin from the same lake are minor, suggesting common (or similar) organic sources for these fractions. The lability of sedimentary humic matter to alkaline hydrolysis is inversely related to its degree of exposure to oxidative weathering. Lability may also be related to diagenetic state as fulvic acids generally yield greater quantities of hydrolysis components than humic acids which in turn yield more than humin.