On the relevance of iron adsorption to container materials in small-volume experiments on iron marine chemistry: Fe-aided assessment of capacity, affinity and kinetics

Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron ⁵⁵Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10^− 9 mol/m² or 1.7 × 10^− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log K_Fe'W = 11.0 ± 0.3 m²/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 ⁻⁴–10^− 5 L/s and rate constants for association in the order of 10⁸ L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry.     

Clustering of groundwater chemistry data with implications for reservoir appraisal in West Siberia

Division of sedimentary strata according to groundwater chemistry is discussed with implications for petroleum reservoir potential. It is suggested to process multiparametric water chemistry data from West Siberia using formalized clustering techniques. The efficiency of this approach has been tested for Neocomian clinoform reservoirs with reference to regional-scale appraisal and subregional petroleum division.     

Solar x-ray control of the ionospheric absorption measured by the sweep frequency method

The ionospheric absorption data measured by the sweep frequency method have been compared with the solar x-ray data in the band of 1–8 Å during quiet- and disturbed-sun conditions. The degree of solar x-ray control of the ionospheric absorption and the corresponding limit of solar x-ray flux have been discussed.     

Parametric cubic splines and geologic shape descriptions

Parametric cubic splines provide a versatile means of describing and sampling shapes and curves commonly found in geology. These splines allow the researcher to treat easily curves which are not single-valued in Cartesian or polar coordinates. In addition, they simultaneously provide approximations to positions, slopes, and curvatures of the curve being considered. In conjunction with simple digitizing equipment and a small computer, the method of parametric cubic spline approximation allows the researcher to analyze curves or outlines in cases where the more rapid technique involving video imaging equipment is either not applicable or not available.     

Planet Four: Craters—Optimizing task workflow to improve volunteer engagement and crater counting performance

Virtual citizen science platforms allow nonscientists to take part in scientific research across a range of disciplines, including planetary science. What is required of the volunteer can vary considerably in terms of task type, variety, judgment required, and autonomy—even when the overall goal is unchanged. Through analysis of our live Zooniverse Planet Four: Craters citizen science platform, the effects of task workflow design factors including volunteer autonomy, task variety, task type, and judgment required on volunteer engagement and crater marking performance were investigated. Website analytics showed volunteers using the Full interface (most autonomy and variety) were more likely to return to the platform, although the amount of time spent per visit was unaffected by the interface used. However, analysis of performance suggested that how this time was used did differ. The interface involving the least complex task resulted in the greatest amount of data and rate of collection, although this also coincided with a greater number of false positives when compared with the expert. Performance in terms of agreement, both between participants and with the expert judgment, was significantly improved when using the Stepped interface for crater position and the Ramped (Mark) when measuring diameter—interfaces that both directly measured the metric with a specific, delineated task. The implications for planetary scientists considering the citizen science route is that there is a balancing act to perform, weighing the importance of volunteer engagement with scientists' data needs and the resources that can be committed to data validation.     

Monitoring of fire incidences in vegetation types and Protected Areas of India: Implications on carbon emissions

Carbon emissions released from forest fires have been identified as an environmental issue in the context of global warming. This study provides data on spatial and temporal patterns of fire incidences, burnt area and carbon emissions covering natural vegetation types (forest, scrub and grassland) and Protected Areas of India. The total area affected by fire in the forest, scrub and grasslands have been estimated as 48765.45, 6540.97 and 1821.33 km ², respectively, in 2014 using Resourcesat-2 AWiFS data. The total CO ₂ emissions from fires of these vegetation types in India were estimated to be 98.11 Tg during 2014. The highest emissions were caused by dry deciduous forests, followed by moist deciduous forests. The fire season typically occurs in February, March, April and May in different parts of India. Monthly CO ₂ emissions from fires for different vegetation types have been calculated for February, March, April and May and estimated as 2.26, 33.53, 32.15 and 30.17 Tg, respectively. Protected Areas represent 11.46% of the total natural vegetation cover of India. Analysis of fire occurrences over a 10-year period with two types of sensor data, i.e., AWiFS and MODIS, have found fires in 281 (out of 614) Protected Areas of India. About 16.78 Tg of CO ₂ emissions were estimated in Protected Areas in 2014. The natural vegetation types of Protected Areas have contributed for burnt area of 17.3% and CO ₂ emissions of 17.1% as compared to total natural vegetation burnt area and emissions in India in 2014. 9.4% of the total vegetation in the Protected Areas was burnt in 2014. Our results suggest that Protected Areas have to be considered for strict fire management as an effective strategy for mitigating climate change and biodiversity conservation.     

Parametric integral model of the wind disturbance concerted with the All-Union wave constructional standards and regulations (CSR)

In a modern statement, the concept of a parametric integral model consists of integration of the energy balance equation (or wind forcing) over the frequency. The angular distribution of the energy and the frequency spectrum are prescribed. The equation is solved by the numerical method taking into consideration the energy advection and its local pumping with the assigned wind field varying in time and space. To calculate the swell waves one can employ the well-known Longuet-Higgins theorem on the invariance of a two-dimensional spectrum. or the ray discrete technique.UDK 551.466.315Translated by Mikhail M. Trufanov.     

Observations on the asexual reproductive activities of the sessile stages of the sea nettleChrysaora quinquecirrha (Scyphozoa)

Twenty-seven colonies of wild scyphistomae ofChrysaora quinquecirrha were observed for a period of ten weeks during the summer. Asexual activities of individual organisms were recorded several times each week. Polyps most often proceeded to strobilate in mid-June and then strobilate a second time 18 days later. They then detached and changed position by means of stolons and then produced podocysts. Initial cysts first excysted and the resulting polyps then strobilated. A second strobilation was not generally observed. The developmental implications of these activities are discussed.     

Evaporation data from a Piche evaporimeter

Measurements with Piche evaporimeters have been conducted within a thermometer screen over a grass surface at several heights. The results show a good correlation with model calculations but differ somewhat in absolute value. Comparisons with the Penman potential evaporation results show a considerable overestimation. With a simple factor, or with a lower measuring position, the results can be brought in a better agreement. The idea of G. Stanhill was verified and proved to be useful only for long periods.