The effect of pumice as aggregate on the mechanical and thermal properties of foam concrete

Pumice is a porous rock, which is formed as a result of volcanic activity and does not include any crystal water. Its porous structure makes it lightweight and provides advantage for heat and sound isolation. Foam concrete is a type of lightweight concrete. Foam concrete is obtained by adding the foam obtained from the agent to the mixture of cement, water, and aggregate. Foam concrete is an environmentally friendly structure and insulation material which provides light, heat, and impact sound insulation that can be used in place of the building elements used in the interior-exterior walls and floors of all buildings. Because of the lack of coarse aggregate in the foam concrete mix, it has some structural problems and this limits its usage area. In this study, four different types of pumice aggregates and stone powder were used to overcome the structural problems of foam. The cement dosages (250 kg/m³), aggregate amounts (250 kg/m³), fresh concrete densities and w/c ratio (0.45) were kept constant in all foamed concrete mixtures. Then, physical, mechanical, and thermal conductivity properties of the resulting foam concretes were investigated. When the findings were evaluated, the most suitable type of lightweight aggregates for use in foam concrete have been determined in terms of compressive strength and thermal conductivity properties. In all aggregate groups, Nevsehir Pumice has the highest compressive strength while Karaman Pumice has the lowest thermal conductivity. However, when both properties were evaluated together, it was determined that the most favorable lightweight aggregate was Nevsehir Pumice.     

Fractionation of Ni,Cr and Cu from Soil by Sequential Extraction Procedure and Determination by Inductively Coupled Plasma Optical Emission Spectrometry

Five‐step sequential extractions were employed to fractionation of Ni, Cr and Cu in soil polluted by anthropogenic activities and determine the mobility of the metals. Twelve samples were collected on an agricultural area that was located near an airport and intercity roads in Elazig‐Turkey. Exchangeable, organically bounded, carbonate bounded, adsorbed species on Fe and Mn oxides and residual species (except silicates) of Ni, Cr and Cu were extracted into solution by using CaCl₂, Na₄P₂O₇, Na₂EDTA, NH₂OH–HCl and HNO₃–H₂O₂, respectively. Mobile metal concentrations in fractions and total recoverable in soils were determined by using inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Total recoverable Ni, Cr and Cu concentrations were in the range of 40–119, 45–126 and 23–72 mg kg^?1, respectively. It was observed that total concentrations of metals in some of the samples were higher than the permitted values. The sum of the mobile percentages of metals was found to be lower than 50%. The Ni, Cr and Cu percentages for exchangeable species are in the ranges of 0.18–1.64, 0.03–0.59 and 0.42–2.53%, respectively.     

Regional gravimetric quasi-geoid model and transformation surface to national height system for Turkey (THG-09)

Turkish regional geoid models have been developed by employing a reference earth gravitational model, surface gravity observations and digital terrain models. The gravimetric geoid models provide a ready transformation from ellipsoidal heights to the orthometric heights through the use of GPS/leveling geoid heights determined through the national geodetic networks. The recent gravimetric models for Turkish territory were computed depending on OSU91 (TG-91) and EGM96 (TG-03) earth gravitational models. The release of the Earth Gravitational Model 2008 (EGM08), the collection of new surface gravity observations, the advanced satellite altimetry-derived gravity over the sea, and the availability of the high resolution digital terrain model have encouraged us to compute a new geoid model for Turkey. We used the Remove-Restore procedure based on EGM08 and applied Residual Terrain Model (RTM) reduction of the surface gravity data. Fast Fourier Transformation (FFT) was then used to obtain the residual quasigeoid from the reduced gravity. We restored the individual contributions of EGM08 and RTM to the whole quasi-geoid height (TQG-09). Since the Helmert orthometric height system is adopted in Turkey, the quasi-geoid model (TQG-09) was then converted to the geoid model (TG-09) by making use of Bouguer gravity anomalies and digital terrain model. After all we combined a gravimetric geoid model with GPS/leveling geoid heights in order to obtain a hybrid geoid model (THG-09) (or a transformation surface) to be used in GPS applications. The RMS of the post-fit residuals after the combination was found to be ± 0.95 cm, which represents the internal precision of the final combination. And finally, we tested the hybrid geoid model with GPS/leveling data, which were not used in the combination, to assess the external accuracy. Results show that the external accuracy of the THG-09 model is ± 8.4 cm, a precision previously not achieved in Turkey until this study.     

Seasonal and spatial variations in the scaling and correlation structure of streamflow data

Seasonal and spatial variability in scaling, correlation and wavelet variance parameter of daily streamflow data were investigated using 56 gauging stations from five basins located in two different climate zones. Multifractal temporal scaling properties were detected using a multiplicative cascade model. The wavelet variance parameter yielded persistence properties of the streamflow time series. Seasonal variations were found to be significant in that winter and spring seasons where large‐scale frontal events are dominant showed higher long‐term correlations and less multifractality than did summer and fall seasons. Coherent spatial variations were apparent. The Neches River basin located in a subtropic humid climate zone exhibited high persistence and long‐term correlation as well as less multifractality as compared with other basins. It is found that larger drainage areas tend to have smaller multifractality and higher persistence structure, and this tendency becomes apparent in regions that receive large amounts of precipitation and decreases towards arid regions. Copyright © 2012 John Wiley & Sons, Ltd.     

Geochemistry,provenance and tectonic setting of the Late Cambrian–Early Ordovician Seydişehir Formation in the Çaltepe and Fele areas,SE Turkey

The major, trace and rare earth element (REE) contents of metapelite (MPL), metapsammite (MPS) and metamarl (MM) samples from the Cambro-Ordovician Seydi?ehir Formation were analyzed to investigate their provenance and tectonic setting. The MPS, MPL, and MM samples have variable SiO₂ concentrations, with average values of 72.36, 55.54, and 20.95 wt%, moderate SiO₂/Al₂O₃ ratios (means of 6.88, 3.23, and 3.80), moderate to high Fe₂O₃ + MgO contents (means of 5.14, 9.55, 3.56 wt%), and high K₂O/Na₂O ratios (means of 3.26, 3.64, 2.90), respectively. On average, the chemical index of alteration (CIA) values of the MPS and the MPL are 65.87 and 71.96, respectively, while the chemical index of weathering (CIW) values are 74.54 and 85.09, respectively. These data record an intermediate to high degree of alteration (weathering) of plagioclase to illite/kaolinite in the samples’ provenance. The chondrite-normalized REE patterns of all the sample groups are similar and are characterized by subparallel light rare earth elements (LREE)-enriched, relatively flat heavy rare earth elements (HREE) patterns with pronounced Eu anomalies (mean of 0.69) and moderate fractionation [average (La/Yb)_N = 8.7]. Plots of sediments in ternary diagrams of La, Th, Sc and elemental ratios (La/Sc, Th/Sc, Cr/Th, Eu/Eu*, La/Lu, Co/Th, La/Sc and Sc/Th), which are critical for determining provenance, and REE patterns indicate that the metaclastic units of the Seydi?ehir Formation were derived dominantly from felsic to intermediate magmatic rocks and not from a mafic source. The La–Sc–Th and Th–Sc–Zr/10 ternary diagrams of the Seydi?ehir Formation are typical of continental island arc/active continental margin tectonic settings. The geologic location and geochemistry of the Seydi?ehir Formation suggest that it was deposited in an Andean-type retroarc foreland basin during the Late Cambrian–Early Ordovician period. The Neoproterozoic intermediate to felsic magmatic rocks and metaclastic sediments with felsic origins of the Sand?kl?–Afyon Basement Complex (SBC) and their equivalent units, which are thought to be overlain by the younger units in the study area, may be the dominant source rocks for the Seydi?ehir Formation.     

Textural and mineralogical evidence for a Cadomian tectonothermal event in the eastern Mediterranean (Sandıklı-Afyon area, western Taurides, Turkey)

In the Sandıklı-Afyon area, the very low-grade metamorphic Sandıklı Basement Complex with clastic sediments and Late Neoproterozoic felsic igneous rocks are unconformably overlain by a cover succession with red continental clastic rocks, tholeiitic basalts and siliciclastic rocks with Early Cambrian trace fossils. Illite crystallinity studies reveal that both the basement and cover units were metamorphosed at high anchizonal to epizonal conditions ( 300 °C). Textural data together with the detailed evaluation of the P–T–b₀ grid, however, indicate that this thermal event has multiple phases. The first tectonothermal event was realized at pressures of  4.2 kb on the basis of b₀-data and resulted in development of blastomylonites. This is supported by the presence of dynamo-metamorphosed pebbles within the basal conglomerates of the Lower Paleozoic cover series. The second event is post-Ordovician–pre-Jurassic in age, occurred at lower pressures  3.2 kb and produced a weakly developed cleavage in the siliciclastic rocks of the cover. The mineralogical/textural data across the basement-cover boundary therefore indicate the removal of an entire metamorphic zone and thus a metamorphic hiatus.

These data suggest that the Taurides were affected by a Late Neoproterozoic event as part of the peri-Gondwana during the Cadomian orogeny.     

Hydrogeochemistry and Water Quality Evaluation along the Flow Path in the Unconfined Aquifer of the Düzce Plain,North-western Turkey

The Düzce Plain has a multi-aquifer system, which consists of a near surface unconfined aquifer, along with first and second deeper confined aquifers. Hydrochemical evolution and water quality are related to infiltration of the precipitation, recharge from the formations surrounding the plain, flow path of groundwater and the relationship between surface and groundwater. The groundwater in the unconfined aquifer flows towards the Efteni Lake and the Büyük Melen River. Surface waters are divided into two main hydrochemical facies in the study area: (a) Ca2+–HCO3?; and (b) Ca2+, Mg2+–HCO3-, SO42-. The groundwater has generally three main hydrochemical facies: (a) Ca2+–HCO3-; (b) Ca2+, Mg2+–HCO3-; and (c) Ca2+, Mg2+–HCO3-, Cl-. The hydrochemical facies a and b dominate within shallow depths in recharge areas under rapid flow conditions, while hydrochemical facies c characterizes shallow and mixed groundwater, which dominate intermediate or discharge areas (near Efteni Lake and Büyük Melen River) during low flow conditions and agricultural contamination. Calcium and bicarbonate ions, total hardness and electrical conductivity of total dissolved solids (EC–TDS) values increase along the groundwater flow path; but these parameters remain within the limits specified by the standards set for industrial and agricultural usages.     

Gold abundance and an aluminosilicate-rich alteration zone in the Val D'Or mining district, abitibi, Quebec: Examples of the fossil geothermal fields

Investigation of gold abundance in a gold-rich mining district by accurate analytical techniques (e.g., Instrumental Neutron Activation and/or Radiochemical Neutron Activation) shows that gold is anomalously distributed in some parts of the Val d'Or mining district of Quebec. It is possible to distinguish: (1) background values (1.4–3.5 ppb Au); (2) zones of primarily anomalous gold values around the Lamaque-Sigma mines (median: 15 ppb Au); (3) enrichment halos around gold orebodies (median: 70 ppb Au); (4) secondary gold enrichment in shear zones; and (5) high background values for the East Sullivan Monzonitic Stock. The Bourlamaque batholith is considered to be a gold-enriched intrusion because of areas (shear zones) that are anomalously enriched in gold (median: 10 ppb Au). It is concluded that there are auriferous geological units in the Val d'Or mining district, such as the Bourlamaque batholith and Val d'Or Formation. The latter contains the Lamaque-Sigma gold mines, representing 49.6% of the total gold production in the district. It is interpreted that the Val d'Or Formation is part of a central volcanic complex within an island arc system, that the centre of this complex is located in the main Lamaque plug, and that this environment may be compared to high-temperature active geothermal systems which are commonly responsible for the formation of epithermal gold deposits. The Lamaque-Sigma area is considered to be a fossil geothermal field, potentially explaining the anomalous gold values. In addition, a dumortierite-bearing, aluminosilicate-rich zone of hydrothermal alteration in the Val d'Or mining district is considered, as for other similar occurrences, to be the result of hydrothermal alteration within a geothermal field producing an Al- and Si-rich leached protholith which has subsequently been metamorphosed and deformed. A model is proposed for the formation of the gold deposits within the primary gold-rich environment, by mobilisation of gold in the volcanic rocks due to metamorphism and deformation. Therefore, two distinct and successive events are postulated: (1) gold-rich synvolcanic geothermal activity; and (2) late remobilisation from the host rocks, followed by deposition of gold ore within favourable structures.