Microbial Quality in Coastal Waters of Dardanelles in Relation to the Pollution Sources and Transport Pathways

The coastal water quality of Çanakkale Dardanelles (Turkey) was assessed based on bacteriological data and physical–chemical parameters. Total coliform (TC), fecal coliform (FC), and enterococci (ENT) bacteria along with physicochemical parameters were measured monthly up to a year at 12 different sampling sites located through both coastal lines of the strait. The fecal bacteria were abounded at several sampling sites such as B1, B3, G3, and G4 due to direct wastewater discharges and septic leakages or overloading. Storm water runoff and sediment resuspension were important pathways for the transport of coliform and ENT bacteria to the Dardanelles, as the region receives high precipitation and strong winds for most part of the year. The values of pH, temperature, and salinity were in typical ranges for the studied area. The microbiological and physicochemical data were correlated individually and in combination. The best fit correlations for bacterial data were attained between TC and FC or TC and ENT (R = 0.67 or ?0.68), while those for the combined data were obtained for TC with temperature (R = 0.94) and TC with salinity (R = ? 0.70).     

Recovery of Phosphate Sludge as Concrete Supplementary Material

The automotive industry plays a major role in the worldwide economy and represents an opportunity to increase the performance of the Turkish economy. Phosphating units in the automotive manufacturing plants generate phosphate sludge as waste, which is classified as hazardous waste in the European Waste Catalogue. Phosphate sludge must be disposed of in licensed disposal plants according to the current environmental regulations. Solidification/stabilization (S/S) is a widely used treatment technology for the disposal of hazardous wastes. Portland cement is used for the solidification and stabilization processes to immobilize Ni and Zn in the phosphate sludge as well as to create construction material to be used as cobble stone for pavement. Examination of products obtained by S/S processes is performed for two points: to determine the quality and to assess the environmental impacts. The phosphate sludge samples are subjected to chemical characterization and a size distribution analysis leaching test. Concrete for cobble stone was produced by the S/S process with the addition of phosphate sludge to replace sand. Tests for the quality of the product were carried out to determine compressive strength, permeability, and elasticity. At the end of the leaching test, elution concentrations of Zn and Ni while using water with pH values of 4.0, 5.4, and 9.0 were determined to be under the limit of inert material properties. Use of phosphate sludge should be considered as a sand replacement in the proportion of 1% of phosphate sludge to cement in concrete production, such as for cobble stone for pavement, without any adverse environmental impacts.     

Exploration of S-wave velocity profiles at strong motion stations in Eskisehir,Turkey, using microtremor phase velocity and S-wave amplification

We have explored 1D S-wave velocity profiles of shallow and deep soil layers over a basement at strong motion stations in Eskisehir Province, Turkey. Microtremor array explorations were conducted at eight strong motion stations in the area to know shallow 1D S-wave velocity models. Rayleigh wave phase velocity at a frequency range from 3 to 30 Hz was estimated with the spatial autocorrelation analysis of array records of vertical microtremors at each station. Individual phase velocity was inverted to a shallow S-wave velocity profile. Low-velocity layers were identified at the stations in the basin. Site amplification factors from S-wave parts of earthquake records that had been estimated at the strong motion stations by Yamanaka et al. (2017) were inverted to the S-wave velocities and Q-values of the sedimentary layers. The depths to the basement with an S-wave velocity of 2.2 km/s are about 1 km in the central part of the basin, while the basement becomes shallow as 0.3 km in the marginal part of the basin. We finally discussed the effects of the shallow and deep sedimentary layers on the 1D S-wave amplification characteristics using the revealed profiles. It is found that the shallow soil layers have no significant effects in the amplification at a frequency range lower than 3 Hz in the area.     

A statistical assessment on global drift ratio demands of mid-rise RC buildings using code-compatible real ground motion records

Over the past 20 years, significant socio-economic losses have been encountered in Turkey due to several moderate to large earthquakes. The studies published after the earthquakes concurringly emphasized that multistory reinforced concrete (RC) buildings, mostly 3–7 story ones, collapsed or were heavily damaged as a result of inadequate seismic performance. Global drift ratio demands are mostly used as a representative quantity for determining the behavior of structures when subjected to earthquakes. In this study, three representative mid-rise RC buildings are analyzed by nonlinear time history analysis using code-compatible real ground motion record sets and the calculated global drift ratio demands of these buildings are statistically evaluated. Ground motion record sets compatible with the design spectrum defined for local soil classes in the Turkish Earthquake Code (TEC-2007) are used for the analyses. In order to evaluate the effect of the number of ground motions on drift ratio demands, five different ground motion record sets with 7, 11 and 15 ground motion records are used separately for each local soil class. Results of this study indicate that (1) the dispersion of global drift ratio demands calculated for individual ground motion records in record sets is high, (2) local soil class has no significant effect on dispersion. However, dispersion increases in a direct proportion to the number of ground motion records in a record set, (3) the mean of global drift ratio demands calculated for different ground motion record sets may differ although they are compatible with the same design spectrum, (4) the mean of the drift demands obtained from different ground motion record sets compatible with a particular design spectrum can be accepted as simply random samples of the same population at 95% confidence level.     

Analysis of dam-induced cyclic patterns on river flow dynamics

This paper investigates the impact of the Hungry Horse Dam on streamflow dynamics in the South Fork of the Flathead River, Montana, USA. To this end, pre- and post-dam periods of raw and naturalized streamflow data were analysed. Pettitt’s change point analysis indicated a significant change point in streamflow dynamics due to dam construction. Complexities in the pre- and post-dam periods were evaluated by sample and multi-scale entropy analyses, and the entropies of the post-dam period were found to be higher than those of the pre-dam period. Possible reasons for this, unrelated to the natural hydrological cycle caused by the dam, were analysed using wavelet analyses. The wavelet analyses showed a clear change in the phase relationship between precipitation and streamflow. Finally, weak positive trends found in the hydrological variables indicated the effects of human activities (e.g. dam construction). The results also revealed distorted lead times, which can improve the streamflow forecasts for different lead times.     

Spectrophotometric Determination of Gold (III) after Liquid–Liquid Extraction and Selective Pre‐concentration with a Novel Dibenzo‐18‐Crown‐6 Derivative

A selective and sensitive method for the extraction and spectrophotometric determination of gold with N,N′‐6,7,9,10,17,18,20,21‐octahydrodibenzo[b,k][1,4,7,10,13,16] hexaoxacyclo‐octadecine‐2,13–diylbis(2‐chloroacetamide) (ODBOCA) is described. The ODBOCA–Au(III) complex was extracted from a slightly acidic aqueous solution (pH 5) into a chloroform layer and then the absorbance of the extract was measured using a UV–Vis spectrophotometer with 1.0 cm quartz cells at 540 nm. An enrichment factor of 200 was achieved. In the chloroform medium at 540 nm, the molar absorptivity and Sandell’s sensitivity were 4.12 × 10³ l mol^?1 cm^?1 and 0.048 μg cm^?2, respectively. Beer’s law was obeyed in the range of 0.5–15 μg ml^?1 in the measured solution. The relative standard deviation for ten replicate samples at the 1.0 μg ml^?1 level was 3.0%. The limit of detection, based on 3s, was 0.5 μg l^?1 in the original sample. The effects of pH, ligand concentration and shaking time were studied. The ratio of the metal ion to ligand molecules in the complex was found to be 1:2 according to the Job Method. The effects of interference by a number of metal ions were investigated. The method was verified with certified reference materials and spiked tests, and quantitative recovery values were obtained. The method was fast, accurate, selective and precise, and was applied to the determination of gold in water and ore with good results.     

Wave sloshing in corrugated bottom tanks with two-dimensional flow

The boundary integral element method based on Green's formula is applied to the analysis of transient flow problem in corrugated bottom tanks. The problem is formulated as a two-dimensional linear, initial boundary value problem in terms of a velocity potential. The Laplace equation and the boundary conditions, except the dynamic boundary condition on the free surface, are transformed into an integral equation by the application of Green's formula. Finite Difference discretization is applied timewise. Initially a triangular wave on the free surface is assumed to be formed. The height of the triangular corrugated bottom is varied between 1/10 and 1/5 of the tank depth. The form of the free surface and the equipotential lines for the flow in the tank are presented at different time steps. An accuracy analysis is performed and distortion in time is considered. Proper coefficients for solutions are derived and presented. The results show that utilization of triangular corrugated bottoms may help to regulate the flow in tanks.     

Significant wave height forecasting using wavelet fuzzy logic approach

Wave heights and periods are the significant inputs for coastal and ocean engineering applications. These applications may require to obtain information about the sea conditions in advance. This study aims to propose a forecasting scheme that enables to make forecasts up to 48 h lead time. The combination of wavelet and fuzzy logic approaches was employed as a forecasting methodology. Wavelet technique was used to separate time series into its spectral bands. Subsequently, these spectral bands were estimated individually by fuzzy logic approach. This combination of techniques is called wavelet fuzzy logic (WFL) approach. In addition to WFL method, fuzzy logic (FL), artificial neural networks (ANN), and autoregressive moving average (ARMA) methods were employed to the same data set for comparison purposes. It is seen that WFL outperforms those methods in all cases. The superiority of the WFL in model performances becomes very clear especially in higher lead times such as 48 h. Significant wave height and average wave period series obtained from buoys located off west coast of US were used to train and test the proposed models.     

Responses of the stratified flows to their driving conditions—A field study

The Bosphorus is oceanographically very complicated two-layer stratified strait where denser water from the Marmara Sea flows towards North under the lighter water which is frequently flowing from the Black Sea towards South. The water level difference between both ends of the Bosphorus varies seasonally within the range of ?0.2 and 0.6 m. The seasonal variability depends mainly on the water level changes in the adjacent basins related to the hydrological cycle, short-term changes in the atmospheric pressure and the wind characteristics. These variations together with the depth and alignment of the cross section along the strait dominate the spatial and temporal variations and sometimes sharp changes in the flow pattern in three dimensions. Although these hydrodynamic conditions are critical for all marine and hydraulic works along the Bosphorus, there was not continuous long-term measurement for a sufficient time span in the strait for detailed evaluation of the current climate. An extensive site surveying work including current, wind, pressure and water level measurements was carried out between September 2004 and January 2006 in relation to the design and construction requirements of the Bosphorus Tube Crossing Project. In this study, the characteristics of stratified flow in the Bosphorus Strait and their relation to local and regional, short- and long-term changes in the meteorological parameters are studied by using the measurement data and the results are discussed comparatively.     

Local site effects evaluation by surface wave and H/V survey methods in Senirkent (Isparta) region,southwestern Turkey

This study aimed to investigate the site characterization of the Senirkent Basin(Isparta) by using the microtremor(H/V) and surface wave analysis(ReMi) methods. Senirkent district, which is located on the foothill of the Kap? Mountain, are prone to seismic and landslide hazards. After the last landslip disaster(1995), the city has continued to develop on the alluvial basin. The microtremor data collected at 41 stations were analyzed. The predominant frequency and the amplification of the soil were found to be in the range of 1.8–6.6 Hz and 0.8–6.8, respectively. These are 4.0-6.8 Hz and 1-2.5 around the slope of the Kap? Mountain and 0.8-3.6 Hz and 3.0-6.6 at alluvium deposits of the valley. The ReMi data collected along 41 profiles were analyzed to obtain a V_(s30) map. The soil classifications were done by using V_(s30) values according to NEHRP soil classification criteria. The results showed that the southern area of the study had better soil conditions with V_(s30) between 360-1160 m/s and soil class between C and B. The alluvium deposits on the north are relatively low with V_(s30) in the range of 260-360 m/s and soil class D.