Novel Polymeric Resin for Solid Phase Extraction and Determination of Lead in Waters

Interest in preconcentration techniques for the determination of metals at ultratrace levels still continues increasingly because of some disadvantages of flameless atomic absorption spectrometry and the high costs of other sensitive methods in compared to flame atomic absorption spectrometry (FAAS). Among preconcentration techniques, solid‐phase extraction is the most popular because of a number of advantages. In this work, thiol‐containing sulfonamide resin was synthesized, characterized, and applied as a new sorption material for solid phase extraction and determination of lead in natural water samples. The optimization of experimental conditions was performed using the parameters including pH, contact time, and volumes of initial and elution solutions. After preconcentration procedure, FAAS was used for determinations. The synthesized resin exhibits the superiority in compared to the other adsorption reagents because of the fact that there is no necessity of any complexing reagent as well as high sorption capacity. Consequently, 280‐fold improvement in the sensitivity of analytical scheme was achieved by combining the slotted tube atom trap‐atomic absorption spectrometry (STAT‐FAAS) and the developed preconcentration method. The limit of detection was found to be 0.15 ng mL^?1. The Pb²⁺ concentrations in the studied water samples were found to be in the range of 0.9–6.7 ng mL^?1.     

Identification of pulse-like ground motions using artificial neural network

For more than 20 years, the concept of near-fault pulse-like ground motion has been a topic of great interest due to its distinct characteristics, particularly due to directivity or fling effects, which are hugely influenced by the rupture mechanism. These unexpected characteristics, along with their effective frequency, energy rate, and damage indices, create a near-fault, pulse-like ground motion capable of causing severe damage to structures. One of the most common approaches for identifying ...     

Prediction of Reservoir Temperatures Using Hydrogeochemical Data,Western Anatolia Geothermal Systems (Turkey): A Machine Learning Approach

Natural Resources Research - Geothermal fluids can be used for purposes such as power production, district heating/cooling, agriculture, and industrial and thermal tourism. Although using...     

Fission track dating obsidians in Central and Northern Anatolia

Twenty obsidian samples from Central and North Anatolia were dated by the fission track method. Split samples analyzed in two different laboratories give consistent results. Data presented refer to three volcanic fields and are summarized as follows: Orta-Sakaeli (Northern Anatolia) obsidians with ages from 21–23 Ma; Göllü Dagi dome complex near Çiftlik (Central anatolia) has given ages between 1.33–0.98 Ma; Acigöl caldera (Central Anatolia) shows three age groups: (1) Eruptions of precaldera (Bogazköy) obsidians with ages 0.18–0.15 Ma; (2) Formation of the large intracaldera dome Kocadag-Taskesiktepe at about 0.08 Ma (uncorrected apparent age of 0.075 Ma); and (3) Acigöl peripheral obsidian domes with plateau ages of 0.020 and 0.019 Ma, and an additional uncorrected age of 0.018 Ma form a distinct age group. This fission track parameters discriminate between the various obsidian sources of prehistoric obsidian artifacts.     

On the importance of boundary layer calculations instead of viscous correction in heavily loaded marine propellers while using a surface panel method

A surface panel method is employed for the thin boundary layer calculation of heavily loaded marine propellers in steady state conditions. Employing the surface panel method, known as the “Morino Method”, the flow field around the propeller is represented by an unknown potential. The majority of the flow field is governed by the potential theory while the viscosity is assumed to be largely confined to thin shear layer on the propeller surface. The boundary layer calculations are performed by using Cebeci-Smith two dimensional model and the local skin friction coefficients and blowing velocities are obtained along the pre-computed on-body streamlines. It is shown that the prediction of torque of the propeller is improved when the boundary layer calculations are used instead of the boundary layer corrections based on the formulae established for the flat plates.     

Delta formation at the southern entrance of Istanbul Strait (Marmara sea, Turkey): a new interpretation based on high-resolution seismic stratigraphy

A detailed stratigraphic investigation based on high-resolution seismic profiles revealed that the delta at the southern entrance of the Istanbul Strait consists of three parasequence sets. The lowermost parasequence shows a sea-level stillstand at the beginning of the lowstand systems tract, possibly at 11,000±1,100 a b.p., whereas the upper two parasequences reflect deposition at lowstand and during the subsequent transgression. A maximum flooding surface may be developing on the delta at present. The delta is located on the eastern side of the Istanbul Strait canyon, with east–west prograding parasequences. The development of the delta is clearly associated with the Kurbağalı Stream on the east coast, and not with the Black Sea outflow through the strait. The geometry of the delta indicates a radial architecture arranged from northeast to southwest.     

Evidence and implications of massive erosion along the Strait of İstanbul (Bosphorus)

The Strait of İstanbul (SoI) (Bosphorus) is a narrow valley, which has evolved tectonically from a stream, and in which thick sediment deposits have accumulated in the course of its evolution. Detailed seismic and multi-beam bathymetric data have revealed that the upper parts of the deeper channel deposits consist of parallel strata, which have mostly been eroded subsequently to their deposition. The resulting erosion surface is represented by the present channel floor in the strait, the estimated volume of the eroded material being approximately 2×10⁸ m³ . Erosion rate and seafloor morphology indicate that the flow direction was from the south to the north. This inner channel may have been formed by an abrupt flooding of the Black Sea by Mediterranean waters at the beginning of the latest connection between the Marmara and the Black seas. Subsequently, the Mediterranean bottom current of the modern two-way flow system, which was established at about 5–4 ka b.p., has given the latest shape to the strait floor.     

A Detached Binary System V505 Persei

The UBV photometry of a detached F-type eclipsing binary V505 Persei is presented. The light curve solution by a simple spherical model combined with the radial velocity data from two high resolution spectra by Marschall et al. (1990) reveals that the system is formed with two identical component stars of M 1.2 M in the main sequence close to ZAMS in evolution. They should have about solar metallicity (z 0.017). The isochrones with solar metallicity by Van denBerg (1985) yield an age of about (2.2± 0.5) × 10⁹ yr for the system. The distance of the system should be about 60 pc.     

Zinc contamination in river water and sediments at Taisyu Zn–Pb mine area,Tsushima Island,Japan

Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml^− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g^− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange.     

Assessment of water quality and pollution of the Lake Seyfe basin, Kırşehir, Turkey

Lake Seyfe is located in a closed basin near K?r?ehir in the central Anatolian region, Turkey. The aim of this study is to evaluate the groundwater quality and effects of lithogenic contamination carried out in the Lake Seyfe basin, which is represented by various lithologies and groundwater types. Seyfe, Horla and Akp?nar springs are recharged through marbles at the western and southwestern of the basin are ultimately and discharged into the K?z?l?rmak Formation and Lake Seyfe. The waters of deep wells drilled into the marbles are of bicarbonate type (type I) in the Ca²⁺–Mg²⁺–HCO₃ ^? and Ca²⁺–HCO₃ ^? facies. Özlühüyük spring and waters from most of trenches and shallow wells, which are fed by the K?z?l?rmak Formation, have a mixed (type II) composition in the Ca²⁺–Mg²⁺–HCO₃ ^?–Cl^? facies. Groundwater in the alluvium and K?z?l?rmak Formation along Lake Seyfe has a salty (type III) character in the Na⁺–Cl^? facies. The main reasons of formation and change of the groundwater salinity and hydrochemical facies in the Seyfe basin are causing the various (a) lithogenic pollution and heterogeneity of the K?z?l?rmak Formation, (b) salinity of the upper soil zones, and (c) evaporation of the trench and channel waters open to the atmosphere. Considering parameters such as sodium hazard, specific conductivity, bicarbonate and carbonate hazards, waters in the study area are generally suitable for agricultural usage.