Biodegradation effects over different types of coastal rocks

Modern coastal areas have natural and transported rocks (armourstone) on which various types of organisms live. Burrowing, boring and feeding by these organisms can destroy or modify the coastal rocks and hence change the coastal morphology. Two rock types and three dominant types of organisms have been studied in Mersin Bay, Eastern Mediterranean of southern Turkey. In this study area, Plio-Quaternary conglomerates and variously aged limestone armourplates have been affected by Phoronida worms, bivalve Brachidontes pharaonis (Fischer P. 1870) and the limpet Patella sp. Phoronida colonies were found covering the hard substratum as a mat and form tubular endolithes of 35.0 mm depth and 1.5 mm diameter, whilst Brachidontes pharaonis (Fischer P. 1870) form 44 mm deep vase-shaped gastrochaenolites. The bioerosive activity of Limpet Patella sp., found intertidal and within the spray zone, cannot be significantly observed on the rocks over short time periods. The soft sandy matrix of the conglomerates present were found to disintegrate by bioerosional processes, with the released gravels being transported and deposited onto the beach. Within the armourstone limestone blocks, a maximum of 44.0 mm deep holes developed after 50–60 years. However, these biological activities do not threaten the stability of the blocks due to their hard and homogeneous internal structure. Furthermore, the organism colonies that cover these rocks as a strong mat (maximum 29.0 mm) act to protect their surfaces from further biological attack and wave action.     

A New Mathematical Formulation for Underground Cut-off Grade Determination in the Presence of Pre-concentration Systems

Natural Resources Research - The mining industry is facing increasingly lower grades, which intensifies the need to reduce costs. The depletion of orebodies close to the surface has pushed the...     

Assessment of the impact of anthropogenic activities on the groundwater hydrology and chemistry in Tarsus coastal plain (Mersin,SE Turkey) using fuzzy clustering,multivariate statistics and GIS techniques

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Highlights? Four distinct groundwater classes resulted from the fuzzy c-means clustering method. ? Both geogenic and anthropogenic processes affect the groundwater quality in the area. ? Salinization in the area is due to seawater intrusion and dissolution of evaporites. ? Near the coastal zone, the groundwater level is lowered 2–5 m below the sea level. ? Ancient subsurface hydrological features act as conduits for groundwater flow.     

Chromatographic Separation and Analytic Procedure for Priority Organic Pollutants in Urban Air

A separation procedure was developed for analysis of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in urban air, while simultaneously eliminating the interfering compounds. This was carried out by optimization of a column chromatograph with regard to the eluent type (n‐hexane and n‐pentane), volume of eluent, type of sorbent material (silica gel and florisil) and activation level of the sorbent material. The determination of the level of PCBs and PAHs was carried out using gas chromatography (GC) equipped with a mass selective detector (MSD), while determination of the OCPs was carried out by GC equipped with an electron capture detector (μ‐ECD). The use of a silica gel column (10 g, 5% deactivated with H₂O) with 70 mL of n‐hexane gave satisfactory separation of PCBs from PAHs and OCPs. After collecting the PCBs with 70 mL of n‐hexane, 3·20 mL of n‐hexane:ethyl acetate, (1:1, v:v) was adequate for elution of the PAHs and OCPs from the column. The primary aim of this study was to develop a multimethod for analyses of PCBs, PAHs, and OCPs in urban air as well as reducing solvent and sorbent consumption and analysis time during the clean‐up procedure compared to the US EPA standard methods (EPA methods TO‐13A for PAHs and TO‐4A for both PCBs and OCPs).     

An experimental study on steel‐encased buckling‐restrained brace hysteretic dampers

This paper describes a seismic test program performed on 12 steel‐encased buckling‐restrained braces (BRBs). The use of rolled or built‐up buckling‐restraining mechanisms with welded or bolted attachments was examined. In addition, the effects of bolt pretension, core‐to‐encasing attachment details, aspect ratio of core segment and imperfections due to manufacturing on the brace response were investigated. All specimens were subjected to a stepwise incremental quasi‐static testing protocol with a maximum axial strain amplitude of 2%. All specimens except one showed satisfactory performance with stable hysteretic response and sustained cumulative inelastic deformations in excess of 200 times the yield deformation. Based on the experimental results, the compression strength adjustment factor, and the strain hardening adjustment factor for each excursion were quantified. Test results revealed that these two factors are significantly influenced by the parameters investigated in the experimental program. BRB details were also found to influence the buckling and the yielding patterns of the core segment. Copyright © 2009 John Wiley & Sons, Ltd.     

Correlation between Cerchar abrasivity index,rock properties,and drill bit lifetime

The Cerchar abrasivity index (CAI) is one of the most widely known index method for identification of rock abrasivity. It is a simple and fast testing method providing reliable information on rock abrasiveness. In this study, the relationships between the CAI and some rock properties such as uniaxial compressive strength (UCS), point load strength, Brazilian tensile strength and Schmidt rebound hardness, and equivalent quartz content (EQC) are examined. The relationships between the CAI and drill bit lifetime is also investigated and the type of drill bit wear observed is mentioned. Additionally, the CAI is modeled using simple and multiple linear regression analysis based on the rock properties. Drill bit lifetime is also modeled based on the CAI. The results show that the CAI increases with the increase of the UCS, point load strength, Brazilian tensile strength, L-type and N-type Schmidt rebound hardness, and the EQC. It is concluded that the higher and the lower bit lifetime are obtained for marl and andesitic-basaltic formation, respectively. Moreover, flushing holes, inserted button, button removal, and failures of button on the bits are determined as the type of drill bit wear. The modeling results show that the models based on the UCS and the EQC give the better forecasting performances for the CAI.     

SHRIMP U–Pb zircon ages and whole-rock geochemistry for the Şapçı volcanic rocks,Biga Peninsula,Northwest Turkey: implications for pre-eruption crystallization conditions and source characteristics

Palaeogene and Neogene volcanic rocks are widespread on the Biga Peninsula of Northwest Turkey. These rocks were formed during the Eocene, Oligocene–Miocene, and late Miocene, and the early Miocene ?apç? volcanic rocks in the Bal?kesir area consist of andesitic lava flows and associated pyroclastics. Temperatures, pressures, and oxygen fugacities calculated for the hornblendes in these andesitic rocks are 903–930°C, 3.3–4.8 kbar, and –9.91 to –11.88, respectively, and for the biotites they are 755–788°C, 1.30–1.74 kbar, and –14.88 to –13.98, respectively. SHRIMP U–Pb dating of zircons from three andesite samples gave ages of 22.72 ± 0.19, 22.97 ± 0.23, and 18.72 ± 0.17 Ma (early Miocene), and these are regarded as crystallization ages. Geochemical analyses show that the volcanic rocks are mainly high-K and calc-alkaline, and have high contents of large-ion lithophile elements and low contents of high-field strength elements, revealing that they evolved from parental magmas that were derived from an enriched subcontinental lithospheric mantle source. The chondrite-normalized rare earth element patterns of the rocks are concave upwards with La_CN/Lu_CN = 11.9–21.2 and Eu_CN/Eu* = 0.84–0.92, implying significant fractional crystallization of hornblende during their evolution. According to the petrological data with regional geology, Neogene magmatic activity on the Biga Peninsula has a post-collisional feature, and was closely related to slab break-off geodynamic model after collision of Tauride–Anatolide Block and Sakarya continent.     

Evolution of Pleistocene travertine depositional system from terraced slope to fissure-ridge in a mixed travertine-alluvial succession (Jebel El Mida,Gafsa, southern Tunisia)

The Quaternary stratigraphic record of Jebel El Mida, composed of continental deposits, is a useful example of concomitant travertines and alluvial deposition in an extensional setting. Travertine deposition occurred in a faulted Pleistocene alluvial fan giving rise to seven (recognised) facies interfingering with five other alluvial ones. The travertine depositional events indicate a tectonically driven evolution from terraced slope (facies group FC1–FC6) to a travertine fissure ridge-type depositing phase (facies group of FC1–FC7). Interfingering between travertine and alluvial facies indicates the co-existence of adjacent and time-equivalent depositional environments. The travertine deposition resulted from deep origin hydrothermal fluids channelled along damaged rocks volumes associated to a regional fault system, named as the Gafsa Fault (GF). The travertine–terrigenous succession in Jebel El Mida highlights the major role played by the GF in controlling: (i) the hydrothermal fluid flow, still active as also indicated by the numerous thermal springs aligned along the fault zone; (ii) paleoflow directions, discharge locations, volume, rate and fluctuations of the water supply. The paleoclimatic correlation with adjacent localities reveals that, at that time, humid episodes could have contributed to the recharge of the hydrothermal system and to the deposition of alluvial sediments.     

The genesis of the carbonatized and silicified ultramafics known as listvenites: a case study from the Mihalıççık region (Eskişehir), NW Turkey

The Mihalıççık region (Eskişehir) in NW Turkey includes an ophiolitic assemblage with a serpentinite‐matrix mélange. The serpentinites of this mélange host silica‐carbonate metasomatites which were previously named as listvenites. Our mineralogical and geochemical studies revealed that these alteration assemblages represent members of the listvenitic series, mainly the carbonate rocks, silica‐carbonate rocks and birbirites, rather than true listvenites (sensu stricto). Tectonic activity and lithology are principal factors that control the formation of these assemblages. Carbonatization and silicification of the serpentinite host‐rock is generated by CO₂, SiO₂‐rich H₂O hydrothermal fluid which includes As, Ba, Sb and Sr. Low precious metal (Au, Ag) contents of the alteration assemblages indicate lack of these metals in the fluid. Primary assemblages of the alteration are carbonate rocks that are followed by silica‐carbonate rocks and birbirites, respectively. Petrographic studies and chemical analyses suggested an alkaline and moderate to high temperature (350–400°C) fluid with low oxygen and sulphur fugacity for the carbonatization of the serpentinites. The low temperature phases observed in the subsequent silicification indicated that the fluid cooled during progressive alteration. The increasing Fe‐oxide content and sulphur phases also suggested increasing oxygen and sulphur fugacity during this secondary process and silica‐carbonate rock formation. The occurrence of birbirites is considered as a result of reactivation of tectonic features. These rocks are classified in two sub‐groups; the Group 1 birbirites show analogous rare earth element (REE) trends with the serpentinite host‐rock, and the Group 2 birbirites simulate the REE trends of the nearby tectonic granitoid slices. The unorthodox REE trend of Group 2 birbirites is interpreted to have resulted from a mobilization process triggered by the weathering solutions rather than being products of enrichment by the higher temperature hydrothermal activity. Copyright © 2006 John Wiley & Sons, Ltd.     

On the Use of Venturi Tubes in Aeration

The ecological quality of water depends largely on the amount of oxygen that the water can hold. The higher the level of dissolved oxygen, the better the quality of a water system. By measuring dissolved oxygen, scientists determine the quality of water and health of an ecosystem. Oxygen enters water by entrainment of air bubbles. Many industrial and environmental processes involve the aeration of a liquid by such entrainment of air bubbles. Venturi aeration is a method of aeration that has become popular in recent years. When a minimal amount of differential pressure exists between the inlet and outlet sides of a venturi tube, a vacuum (air suction) occurs at the suction holes of the venturi tube. The present paper describes the effect of Reynolds Number, air inlet hole diameter, inlet diameter, pipe length, and angle of pipe downstream of the venturi tube, on the air injection rate. It is observed from the results that venturi tubes have high air injection efficiencies. Therefore, venturi tubes can be used as highly effective aerators in ponds, lakes, fish hatcheries, water treatment plants, etc.