Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.     

Transformation of Tobacco with ScMTII Gene‐Enhanced Cadmium and Zinc Accumulation

Genetic transformation is gaining importance for developing plant types suitable to metal accumulate and/or hyperaccumulate. In this study, the transgenic tobacco plant which transferred the ScMTII gene from Saccharomyces cerevisiae to wild type tobacco cultivar Petite Havana (SR1) was grown on soils with low and high cadmium (Cd) and zinc (Zn) concentrations in a growth chamber for 6 weeks and compared to wild type tobacco for Cd and Zn accumulation. Cadmium and Zn accumulations in the transgenic and wild type tobacco plants were increased with the increasing Cd and Zn concentrations. Unlike Zn, the transgenic plant accumulated significantly higher amount of Cd compared to the wild type control plants. Shoot Cd concentrations of transgenic tobacco in higher Cd dosages reached the above the hyperaccumulation threshold value of 100 mg Cd kg^?1 in the dry weight (DW). Transgenic tobacco accumulated 354, 400, 372, and 457 mg Cd kg^?1 DW, for 10, 20, 40, and 80 mg Cd kg^?1 soil treatments, respectively. These values are 3.5–4.5‐fold higher than that of Cd hyperaccumulation threshold value. With 10 mg kg^?1 Cd treatment, the bioconcentration factor (BCF) of transgenic tobacco plants for Cd reached up to 35 in which the threshold value for BCF should be at least 10. Our results showed that the transgenic tobacco may be used as a good Cd hyperaccumulator plant and for phytoextraction of Cd contaminated soils, but not for Zn.     

Adsorption Kinetics of Chloroform from Aqueous Solutions onto Activated Lignite

The lignite coal researched by this study was subjected to a two‐stage activation process performed in the scope of obtaining active carbon from domestic resources. “Activation” and “carbonization” stages were used in the experiments. The modified lignite was produced by impregnating lignite with KOH and washing the activation product with 15% HCl solution after thermal treatment. Increasing KOH dosage also increased the removal efficiency. The variables investigated in adsorption experiments were contact time, initial concentration, pH, and sorbent dosage. Adsorption kinetics was fitted by using the pseudo‐first‐order equation, pseudo‐second‐order equation, and intra‐particle diffusion. Isotherm modeling was carried out using Langmuir, Freundlich, and Dubinin–Radushkevich equations. Selected target compound in this work is common environmental pollutant in waters. A commonly known effect of chloroform is its carcinogenic effect. Therefore, removal of these compounds from water is considerably important. Chloroform removal of 97% for was achieved by the use of Konya region activated lignite.     

Observations on the building damages after 19 May 2011 Simav (Turkey) earthquake

An earthquake with a magnitude of 5.7 $(\text{ M}_{\mathrm{L}})$ has struck Simav, Kutahya located in the western part of Turkey on May 19, 2011. The ground motion caused observable damage within 25 km radius from the epicenter. Although the earthquake is moderate, its effects on the structures are serious. This paper presents the observations on seismic damages of reinforced concrete (RC) and masonry structures. Common reasons of damage in RC buildings are: low quality of concrete, detailing mistakes of reinforcement, short column, pounding, overhangs and misconstructed gable and outer infill wall parts. Interesting cases related to these deficiencies are reported. Damages in the masonry buildings are due to lack of connection between orthogonal walls and unsuitable location and dimension of openings. The damages at structures are more noticeable at regions with unfavorable soil conditions like plain regions or foothills. However, on stiffer soils at hilly sides, the damages seem to be more limited and masonry structures are observed to be less affected compared to the RC ones. The damages in RC buildings found to be increasing with story number for light damage states. However, for heavier damage states, 4–5 story buildings are observed to be the most damaged.     

Removal of Organochlorine Pesticides from Aqueous Solution by Using Neutralized Red Mud

This work describes the potential usability of neutralized red mud for the removal of organochlorine pesticides (OCPs) from aqueous solutions. After examination on the adsorption capability of neutralized red mud for all studied OCPs, the experiments were performed by employing aldrin as a model compound. The effect of several parameters, such as contact time, pH of the solution, initial aldrin concentration, and dosage of the adsorbent was evaluated by batch experiments. The determination of OCPs was carried out using traditional liquid–liquid extraction followed by a GC coupled with µ‐electron capture detector (GC‐µECD). The results showed that adsorption equilibrium time depended upon the initial aldrin concentration and adsorption followed the second‐order kinetic model. Kinetic study also indicated that the film diffusion mechanism was a main rate control mechanism. The removal was explained by considering the electrostatic interactions between metal oxides surface of the neutralized red mud and inductively charged centers (negative charge (d?) of chlorine atoms and positive charge (d+) of π‐cloud aromatic ring) of the aldrin molecules. In comparison to the Langmuir isotherm model, the Freundlich model better represented the adsorption data. The neutralized red mud was also succesfully employed for the removal of OCPs from real water samples, including tap water and surface (lake) water, fortified with studied OCPs.     

Investigation of liquefaction and pore water pressure development in layered sands

This paper presents the results of shaking table model tests which were carried out to investigate the pore water pressure generation and related liquefaction mechanism in layered sand deposits. The experiments were performed on uniform sand columns, silt interlayered sand columns and two layered sand columns deposited at various relative densities and subjected to different input excitations. During the experiments excess pore water pressures were measured by pore pressure transducers installed at three different depths and, surface settlements and thickness of water film developed under less permeable inclusions were measured by a digital camera. The experimental results are discussed and compared to demonstrate the effects of relative density, input acceleration and presence of a silt seam on the generation of excess pore water pressure in sand deposits subjected to dynamic loading. The results showed that the presence of a less permeable silt interlayer within the sand deposit and existence of a loose sand layer underlying dense sand deposits can have significant effect on the pore water pressure generation mechanism.     

强震观测建筑结构的地震反应分析

选择取得强震观测资料的建筑结构为研究对象，采用有限元法建立结构的动力反应分析模型，利用SAP2000程序分析了结构的地震反应，并同实际记录到的结构地震反应进行了对比分析，讨论了结构模型参数估计和一些不确定因素对模型精度的影响。     

Comparative analysis of fuzzy inference systems for water consumption time series prediction

Two types of fuzzy inference systems (FIS) are used for predicting municipal water consumption time series. The FISs used include an adaptive neuro-fuzzy inference system (ANFIS) and a Mamdani fuzzy inference systems (MFIS). The prediction models are constructed based on the combination of the antecedent values of water consumptions. The performance of ANFIS and MFIS models in training and testing phases are compared with the observations and the best fit model is identified according to the selected performance criteria. The results demonstrated that the ANFIS model is superior to MFIS models and can be successfully applied for prediction of water consumption time series.