Extent of thermal ablation suffered by model organic microparticles during aerogel capture at hypervelocities

Abstract— New model organic microparticles are used to assess the thermal ablation that occurs during aerogel capture at speeds from 1 to 6 km s^?1. Commercial polystyrene particles (20 μm diameter) were coated with an ultrathin 20 nm overlayer of an organic conducting polymer, polypyrrole. This overlayer comprises only 0.8% by mass of the projectile but has a very strong Raman signature, hence its survival or destruction is a sensitive measure of the extent of chemical degradation suffered. After aerogel capture, microparticles were located via optical microscopy and their composition was analyzed in situ using Raman microscopy. The ultrathin polypyrrole overlayer survived essentially intact for impacts at ～1 km s^?1, but significant surface carbonization was found at 2 km s^?1, and major particle mass loss at ≥3 km s^?1. Particles impacting at ～6.1 km s^?1 (the speed at which cometary dust was collected in the NASA Stardust mission) were reduced to approximately half their original diameter during aerogel capture (i.e., a mass loss of 84%). Thus significant thermal ablation occurs at speeds above a few km s^?1. This suggests that during the Stardust mission the thermal history of the terminal dust grains during capture in aerogel may be sufficient to cause significant processing or loss of organic materials. Further, while Raman D and G bands of carbon can be obtained from captured grains, they may well reflect the thermal processing during capture rather than the pre‐impact particle's thermal history.     

Capture effects in carbonaceous material: A Stardust analogue study

Abstract— It is reasonable to expect that cometary samples returned to Earth by the Stardust space probe have been altered to some degree during capture in aerogel at 6.1 km/s. In order to help interpret the measured structure of these particles with respect to their original cometary nature, a series of coal samples of known structure and chemical composition was fired into aerogel at Stardust capture velocity. This portion of the study analyzed the surfaces of aerogel‐embedded particles using Raman spectroscopy. Results show that particle surfaces are largely homogenized during capture regardless of metamorphic grade or chemical composition, apparently to include a devolatilization step during capture processing. This provides a possible mechanism for alteration of some aliphatic compound‐rich phases through devolatilization of cometary carbonaceous material followed by re‐condensation within the particle. Results also show that the possibility of alteration must be considered for any particular Stardust grain, as examples of both graphitization and amorphization are found in the coal samples. It is evident that Raman G band (～1580 cm^?1) parameters provide a means of characterizing Stardust carbonaceous material to include identifying those grains which have been subjected to significant capture alteration.     

The dark matter environment of the Abell 901/902 supercluster: a weak lensing analysis of the HST STAGES survey

We present a high-resolution dark matter reconstruction of the   z = 0.165  Abell 901/902 supercluster from a weak lensing analysis of the Hubble Space Telescope STAGES survey. We detect the four main structures of the supercluster at high significance, resolving substructure within and between the clusters. We find that the distribution of dark matter is well traced by the cluster galaxies, with the brightest cluster galaxies marking out the strongest peaks in the dark matter distribution. We also find a significant extension of the dark matter distribution of Abell 901a in the direction of an infalling X-ray group Abell 901α. We present mass, mass-to-light and mass-to-stellar mass ratio measurements of the structures and substructures that we detect. We find no evidence for variation of the mass-to-light and mass-to-stellar mass ratio between the different clusters. We compare our space-based lensing analysis with an earlier ground-based lensing analysis of the supercluster to demonstrate the importance of space-based imaging for future weak lensing dark matter 'observations'.     

The fusion crust of the Winchcombe meteorite: A preserved record of atmospheric entry processes

Fusion crusts form during the atmospheric entry heating of meteorites and preserve a record of the conditions that occurred during deceleration in the atmosphere. The fusion crust of the Winchcombe meteorite closely resembles that of other stony meteorites, and in particular CM2 chondrites, since it is dominated by olivine phenocrysts set in a glassy mesostasis with magnetite, and is highly vesicular. Dehydration cracks are unusually abundant in Winchcombe. Failure of this weak layer is an additional ablation mechanism to produce large numbers of particles during deceleration, consistent with the observation of pulses of plasma in videos of the Winchcombe fireball. Calving events might provide an observable phenomenon related to meteorites that are particularly susceptible to dehydration. Oscillatory zoning is observed within olivine phenocrysts in the fusion crust, in contrast to other meteorites, perhaps owing to temperature fluctuations resulting from calving events. Magnetite monolayers are found in the crust, and have also not been previously reported, and form discontinuous strata. These features grade into magnetite rims formed on the external surface of the crust and suggest the trapping of surface magnetite by collapse of melt. Magnetite monolayers may be a feature of meteorites that undergo significant degassing. Silicate warts with dendritic textures were observed and are suggested to be droplets ablated from another stone in the shower. They, therefore, represent the first evidence for intershower transfer of ablation materials and are consistent with the other evidence in the Winchcombe meteorite for unusually intense gas loss and ablation, despite its low entry velocity.     

Algal δ15N values detect a wastewater effluent plume in nearshore and offshore surface waters and three-dimensionally model the plume across a coral reef on Maui, Hawai'i, USA

The coral reef at Kahekili, Maui is located ~300 m south of the Lahaina Wastewater Reclamation Facility which uses four Class V injection wells to dispose of 3-5 million gallons of wastewater effluent daily. Prior research documented that the wastewater effluent percolates into the nearshore region of Kahekili. To determine if the wastewater effluent was detectable in the surface waters offshore, we used algal bioassays from the nearshore region to 100 m offshore and throughout the water column from the surface to the benthos. These algal bioassays documented that significantly more wastewater effluent was detected in the surface rather than the benthic waters and allowed us to generate a three-dimensional model of the wastewater plume in the Kahekili coastal region. Samples located over freshwater seeps had the highest δ(15)N values (~30-35‰) and the effluent was detected in surface samples 500 m south and 100 m offshore of the freshwater seeps (~8-11‰).     

International Collaborations In Geodesy Advance Geoscience Research

UNAVCO supports geoscience research at 113 US academic Member institutions,and another 104 Associate Member institutions include international universities,laboratories,observatories,academies of science,and a museum.This diverse membership shares UNAVCO’s purpose at home and abroad,giving UNAVCO global reach in advancing geodesy.Since the mid-1980s,modern geodesy has evolved into a cutting-edge,multi-faceted toolbox with remarkably diverse research and real-world applications,including studies and observation or forecasting of solid-Earth hazards,the dynamics of the atmosphere,climate,near-Earth space environment,and of key environmental parameters such as water storage,soil moisture,and seaand lake-level changes.UNAVCO operates facilities on behalf of the U.S.National Science Foundation to support investigators who use geodetic tools across all of these Earth and atmospheric domains.UNAVCO has built a number of large dense regional networks of GPS stations,including the Earth Scope Plate Boundary Observatory in North America,the COCONetCaribbean network,TLALOCNet in Mexico,GNET in Greenland,and ANET in Antarctica.Going forward,UNAVCO plans to federate the Plate Boundary Observatory(USA),TLALOCNet(Mexico),and COCONet(Caribbean)GPS networks as the Network of the Americas,with upgrades to state-of-the-art,multi-sensor,multi-GNSS observations.While UNAVCO community scientists actively engage in using space and terrestrial geodetic techniques to study geodynamics at all scales,this proliferation of continuous networks is the basis for a suite of recent contributions that focus on improved daily positioning to sense Earth’s elastic response and other perturbations to loading by atmospheric and surface water,oceans,and ice.Day-to-day and sub-daily variations in the GPS vertical and horizontal correlate to increasingly well-understood short-term mass variability,such as monsoonal flooding in Bangladesh,sub-daily changes in tidal loading at continent scales,day-to-day surface water and ice storage in the western U.S.,variations in the rate of GIA in Greenland across a variety of scales,and improved understanding of the inter-annual variation in sea level rise due to changes in terrestrial water storage.     

Using δN values in algal tissue to map locations and potential sources of anthropogenic nutrient inputs on the island of Maui, Hawai‘i, USA

Macroalgal blooms of Hypnea musciformis and Ulvafasciata in coastal waters of Maui only occur in areas of substantial anthropogenic nutrient input, sources of which include wastewater effluent via injection wells, leaking cesspools and agricultural fertilizers. Algal δ¹⁵N signatures were used to map anthropogenic nitrogen through coastal surveys (island-wide and fine-scale) and algal deployments along nearshore and offshore gradients. Algal δ¹⁵N values of 9.8‰ and 2.0-3.5‰ in Waiehu and across the north-central coast, respectively, suggest that cesspool and agricultural nitrogen reached the respective adjacent coastlines. Effluent was detected in areas proximal to the Wastewater Reclamation Facilities (WWRF) operating Class V injection wells in Lahaina, Kihei and Kahului through elevated algal δ¹⁵N values (17.8-50.1‰). From 1997 to 2008, the three WWRFs injected an estimated total volume of 193 million cubic meters (51 billion gallons) of effluent with a nitrogen mass of 1.74 million kilograms (3.84 million pounds).     

Azimuthal impact directions from oblique impact crater morphology

Planetary impact craters have a high degree of radial symmetry. This hampers efforts to identify the azimuthal impact direction for most craters – the radially symmetric component of an impact crater swamps any asymmetries that may be present. We demonstrate how the asymmetric component can be isolated and the direction of the asymmetries quantified using a two-dimensional eigenfunction expansion over a circular domain. The complex coefficients of expansion describe the magnitude and phase (angular alignment) of each term. From the analysis of hypervelocity impact craters formed in the laboratory, with impact angles ranging from 0° to 50° from the surface normal, we show that asymmetries which reveal the impact direction are still present at just 10° from the surface normal, and that the phase of one complex coefficient of expansion, c ₁₁, indicates the impact direction. Analysis of the lunar crater Hadley shows bilateral symmetry in the radially asymmetric component, which may be due to oblique impact. The 31-km lunar ray crater Kepler has morphological features that indicate the azimuthal impact direction. Coefficient c ₁₁ gives an azimuthal impact direction similar to that expected from the morphology, although post-impact gravitational collapse and slumping obscure the result to some degree. Ray craters may provide a means of testing the method for smaller 'simple' craters when data are available.