Atmospheric scattering effects on ground-based measurements of thermospheric winds

Inherent in observations of thermospheric winds from the ground with the Fabry-Perot interferometer is the assumption that the measured Doppler shift is a property of the source medium viewed by the instrumental line of sight. However, ground based airglow observations in regions of weak airglow emission near large intensity gradients may be contaminated by scattered light. Light from areas where the emission is strong can be scattered by the lower atmosphere into the field of view of the observations. Thermospheric winds deduced from the observed Doppler shifts will then show apparent convergence or divergence with respect to the site of observation. Examples of this effect are found in observations by the Michigan Airglow Observatory station located near the auroral zone at Calgary, Alberta. Simulation calculations based upon an experimental model for a significant scattering atmosphere also showed results with either convergence or divergence in the apparent neutral wind field observed by the station.     

Origin and emplacement of the impact formations at Chicxulub,Mexico, as revealed by the ICDP deep drilling at Yaxcopoil‐1 and by numerical modeling

We present and interpret results of petrographic, mineralogical, and chemical analyses of the 1511 m deep ICDP Yaxcopoil‐1 (Yax‐1) drill core, with special emphasis on the impactite units. Using numerical model calculations of the formation, excavation, and dynamic modification of the Chicxulub crater, constrained by laboratory data, a model of the origin and emplacement of the impact formations of Yax‐1 and of the impact structure as a whole is derived. The lower part of Yax‐1 is formed by displaced Cretaceous target rocks (610 m thick), while the upper part comprises six suevite‐type allochthonous breccia units (100 m thick). From the texture and composition of these lithological units and from numerical model calculations, we were able to link the seven distinct impact‐induced units of Yax‐1 to the corresponding successive phases of the crater formation and modification, which are as follows: 1) transient cavity formation including displacement and deposition of Cretaceous “megablocks;” 2) ground surging and mixing of impact melt and lithic clasts at the base of the ejecta curtain and deposition of the lower suevite right after the formation of the transient cavity; 3) deposition of a thin veneer of melt on top of the lower suevite and lateral transport and brecciation of this melt toward the end of the collapse of the transient cavity (brecciated impact melt rock); 4) collapse of the ejecta plume and deposition of fall‐back material from the lower part of the ejecta plume to form the middle suevite near the end of the dynamic crater modification; 5) continued collapse of the ejecta plume and deposition of the upper suevite; 6) late phase of the collapse and deposition of the lower sorted suevite after interaction with the inward flowing atmosphere; 7) final phase of fall‐back from the highest part of the ejecta plume and settling of melt and solid particles through the reestablished atmosphere to form the upper sorted suevite; and 8) return of the ocean into the crater after some time and minor reworking of the uppermost suevite under aquatic conditions. Our results are compatible with: a) 180 km and 100 km for the diameters of the final crater and the transient cavity of Chicxulub, respectively, as previously proposed by several authors, and b) the interpretation of Chicxulub as a peak‐ring impact basin that is at the transition to a multi‐ring basin.     

Nondestructive spectroscopic and petrochemical investigations of Paleoarchean spherule layers from the ICDP drill core BARB5, Barberton Mountain Land,South Africa

A Paleoarchean impact spherule‐bearing interval of the 763 m long International Continental Scientific Drilling Program (ICDP) drill core BARB5 from the lower Mapepe Formation of the Fig Tree Group, Barberton Mountain Land (South Africa) was investigated using nondestructive analytical techniques. The results of visual observation, infrared (IR) spectroscopic imaging, and micro‐X‐ray fluorescence (μXRF) of drill cores are presented. Petrographic and sedimentary features, as well as major and trace element compositions of lithologies from the micrometer to kilometer‐scale, assisted in the localization and characterization of eight spherule‐bearing intervals between 512.6 and 510.5 m depth. The spherule layers occur in a strongly deformed section between 517 and 503 m, and the rocks in the core above and below are clearly less disturbed. The μXRF element maps show that spherule layers have similar petrographic and geochemical characteristics but differences in (1) sorting of two types of spherules and (2) occurrence of primary minerals (Ni‐Cr spinel and zircon). We favor a single impact scenario followed by postimpact reworking, and subsequent alteration. The spherule layers are Al₂O₃‐rich and can be distinguished from the Al₂O₃‐poor marine sediments by distinct Al‐OH absorption features in the short wave infrared (SWIR) region of the electromagnetic spectrum. Infrared images can cover tens to hundreds of square meters of lithologies and, thus, may be used to search for Al‐OH‐rich spherule layers in Al₂O₃‐poor sediments, such as Eoarchean metasediments, where the textural characteristics of the spherule layers are obscured by metamorphism.     

Geological model for Boulder 1 at Station 2, South Massif,Valley of Taurus-Littrow

It appears possible to establish a preliminary geological model for the origin and evolution of the breccias of Boulder 1 at Station 2 in the Valley of Taurus-Littrow based on firm and probable geological constraints. The crystallization of plagioclase and other ANT-suite phases now present as clasts appears to have occurred in the lunar crust about 4.5 b.y. ago during the ‘melted shell stage’ of lunar history as that history is presently modeled. The original rocks containing these phases, which now make up the gray competent breccias of Boulder 1, were greatly modified by impact processes during the ‘cratered highland stage’ and the early part of the ‘large basin stage’, up to about 4.0 b.y. ago. About 4.0 b.y. ago, pigeonite basalts with KREEP affinities appear to have been intruded into the pre-Serenitatis crust from which the light friable breccias of Boulder 1 were later derived. During the large basin stage, three major dynamic events profoundly influenced the present character of the Boulder 1 materials. These events probably occurred as follows: (1) formation of gray competent breccia containing ANT-suite clasts in the hot ejecta blanket of an old large basin event, such as Tranquillitatis, that took place about 4.0 b.y. ago; (2) rebrecciation and redeposition of the gray competent breccia, mixed with light friable breccia and pigeonite basalt, in a relatively cool ejecta deposit, possibly produced by the northern Serenitatis event; (3) uplift and exposure of the Boulder 1 materials in the South Massif by the southern Serenitatis event about 3.90 b.y. ago.     

Threshold of erosion of submarine bedrock landscapes by tidal currents

Since sea level stabilized 7000 yr bp , shelf seas experiencing semi‐diurnal tides will have been affected by streaming four times per day. If tidal erosion of bedrock were even only marginally efficient, the ~10 million streamings since then should have left geomorphological imprints. We examine high‐resolution multibeam sonar data from three areas with extreme tidal currents. The Minas Passage (Bay of Fundy) experiencing 8‐knot surface tidal currents was surveyed in 2007 with a multibeam sonar. In an area near to transverse dunes, which are evidence for bedload transport, the data show local overhanging surfaces near to the sediment‐rock contact, potentially created by abrasion by saltating particles. However, they are uncommon. In the Straits of Messina, where surface currents reach 10 knots, surveying revealed ridges lying oblique to the flow that are not obviously broken into separate outcrops by erosion. In the Bristol Channel, UK, sonar data collected where currents reach 3·4 knots at 1·5 m above the bed reveal outcrops of limestone with superimposed sand dunes, but only minor rounding of blocks. Holocene tidal currents have apparently been generally ineffective at eroding bedrock. We examine this issue further by compiling extreme tidal streams around the UK and from them estimate shear stresses, representing a macro‐tidal environment where peak surface currents reach 9·7 knots. Those data are compared with shear stresses in mountainous rivers where long‐term rates of erosion are comparable with tectonic uplift rates and are thus geomorphologically significant. Whereas river stresses reach 10²–10³ Pa, the largest tidal stresses are generally 10¹ and only rarely approach 10² Pa, too small for quarrying to operate generally. However, the vertical faces in the Minas Passage may represent the onset of abrasion. Given this limited evidence for abrasion, we explore conditions in the geological past for tides that may have locally eroded bedrock. Copyright © 2012 John Wiley & Sons, Ltd.     

Cytotoxic and genotoxic evaluation and chemical characterization of sewage treated using activated sludge and a floating emergent-macrophyte filter in a municipal wastewater treatment plant: a case study in Southern Brazil

This study was conducted to evaluate the chemical parameters and the cytotoxic and genotoxic potential of raw domestic sewage and effluents from treatment with activated sludge and a floating emergent-macrophyte filter from a domestic wastewater treatment plant in the city of Novo Hamburgo, Rio Grande do Sul, Brazil. The physicochemical analysis revealed that both treatment systems achieved the legal emission pattern for biochemical oxygen demand, chemical oxygen demand, and suspended solids, but ammoniacal nitrogen and E. coli values were above the limits in the macrophyte treatment effluent. Phosphorous values were above the maximum permitted for both treatments. The results obtained from the Allium cepa test and the micronuclei test in fish did not demonstrate any significant differences in both cytotoxicity (mitotic index) and genotoxicity (chromosome aberration and micronucleus) endpoints between the negative control group and the exposed groups. However, the comet assay in fish revealed a DNA damage increase in animals exposed to the 30 % concentration of the macrophyte effluent and two concentrations of the activated sludge treatment effluent (10 and 75 %), which suggests that these two treatment systems may increase wastewater genotoxicity.     

Proposal for applying a component-based mixture approach for ecotoxicological assessment of fracturing fluids

Hydraulic fracturing is increasingly being used to produce gas from unconventional resource sites for energy supply. Therefore, concerns about risks of this technology related to human health and the environment have to be addressed. Among the major issues is the potential contamination of surrounding water systems by chemical additives used in fracturing fluids. In this study, the ecotoxicological hazards of fracturing fluids, both, their individual components (chemicals) as well as their mixtures (product) were assessed using a component-based mixture approach. For five exemplary fracturing fluids, 40–90 wt% of the contained substances could unambiguously be defined in their chemical identity. The concentrations used in the applied fluid mixture were considered as (maximum) exposure concentrations. For components with mass fractions between 10 and 74 wt%, the effect concentrations for acute and chronic toxicity of fish, daphnia and algae were retrieved from experimental databases and through predictive modeling. The hazard indices calculated from the ratio of exposure to effect concentration were >1 for all fracturing fluids, using different scenarios. This indicated a hazard from the undiluted fracturing fluids. The assessment framework presented in this study allows for dealing with data gaps and uncertainties in a tiered fashion and in particular accommodates for combined effects resulting from chemical mixtures. It might be employed for ecotoxicological risk assessment of products containing chemical mixtures and optimization of their environmental performance.     

A magnetic cycle of τ Bootis? The coronal and chromospheric view

τ Bootis is a late F‐type main sequence star orbited by a Hot Jupiter. During the last years spectropolarimetric observations led to the hypothesis that this star may host a global magnetic field that switches its polarity once per year, indicating a very short activity cycle of only one year duration. In our ongoing observational campaign, we have collected several X‐ray observations with XMM‐Newton and optical spectra with TRES/FLWO in Arizona to characterize τ Boo's corona and chromosphere over the course of the supposed one‐year cycle. Contrary to the spectropolarimetric reconstructions, our observations do not show indications for a short activity cycle (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Decoupled crystallization and eruption histories of the rhyolite magmatic system at Tarawera volcano revealed by zircon ages and growth rates

We obtained U–Th disequilibrium age data on zircons from each of the four rhyolite eruptions that built Tarawera volcano in the last 22 ka within the Okataina Volcanic Center (OVC), caldera, New Zealand. Secondary ion mass spectrometry analyses on unpolished euhedral crystal faces that lack resorption features show that crystal growth variously terminated from near-eruption age to ~100 ka prior to eruption. Age-depth profiling of crystals reveals long periods of continuous (~34 ka) and discontinuous growth (~90 ka). Growth hiatuses of up to ~40 ka duration occur, but do not all relate to obvious resorption surfaces. Age differences up to similar magnitude are found on opposing faces of some crystals suggesting episodes of partial exposure to melts. These features are best explained by periodic, complete, or partial, sub-solidus storage and/or inclusion in larger crystal phases, followed by rapid liberation prior to eruption. This is supported by high abundances of U and Th (~500 − >2,000 ppm) in some zircons consistent with periods of high crystallinity (>70%) in the magmatic system, based on crystal/melt partitioning. Contemporaneous but contrasting rim-ward trends of these elements within crystals, even in the same lava hand sample, require synchronous growth in separate melt bodies and little connectivity within the system, but also significant crystal transport and mixing prior to eruption. Many crystals record continuity of growth through the preceding ~60 ka OVC caldera-collapse and subsequent eruptions from Tarawera. This demonstrates a decoupling between eruption triggers, such as shallow crustal extension and mafic intrusion, and the crystallization state of the OVC silicic magmatic system. The data highlights the need to distinguish between the time for accumulation of eruptible magma and the long-term magma residence time based on the age of crystals with high closure temperatures, when assessing the potential for catastrophic eruptions.