Pétrographie et Datations K-Ar des Transformations Minérales Affectant le Gîte Uranifère de Bertholène (Aveyron — France)

Résumé La minéralisation uranifère de Bertholène est encaissée dans un orthogneiss, à proximité de sa couverture permo-carbonifère. Les variations de faciès observées dans la zone du gisement trahissent d'importantes transformations minéralogiques des roches. L'étude pétrographique révèle deux stades majeurs: 1. Important phénomène d'albitisation oblitérant localement la texture et la minéralogie initiale de l'orthogneiss. 2. Phénomènes plus tardifs d'hydrolyse de l'albite et d'argilisation. La minéralisation uranifère est mise en place lors de ce dernier stade. Les datations K-Ar de fraction fines et de phases minérales séparées permettent de préciser l'âge des transformations: 1. Les phénomènes d'albitisation sont datés à 200–210 Ma. 2. L'âge des phénomènes d'argilisation et de la mise en place des minéralisation est fixé à 170–175 Ma. Ces deux âges, déjà connus en plusieurs autres points du Sud du Massif Central comme épisodes de métamorphisme, de diagenèse, ou de mise en place de minéralisations diverses apparaissent d'une grande importance régionale.

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The Bertholène uranium deposit is located within an orthogneiss not far away from its Permo-Carboniferous sedimentary cover. Variations in texture and coloration in the deposit and its vicinity result from a radical alteration of the country rock mineralogy. Two major stages of transformation are revealed by petrographic study: 1. An important albitization process, locally obliterating the orthogneiss initial texture and mineralogy — 2. A later stage of argillization and albite hydrolysis during which the uranium deposit was formed. K-Ar datings of fine fractions and hand-picked mineral phases enabled the following ages to be established: 1. The age of the albitization process is 200–210 M.Y. 2. The uranium deposit formation and the process of argillization are 170–175 M.Y. old. These two ages, already reported from several other locations in the South of the Massif Central, as epochs of metamorphism, diagenesis or ore bodies formation seem of great regional importance.

     

The CM carbonaceous chondrite regolith Diepenveen

A carbonaceous chondrite was recovered immediately after the fall near the village of Diepenveen in the Netherlands on October 27, 1873, but came to light only in 2012. Analysis of sodium and poly‐aromatic hydrocarbon content suggests little contamination from handling. Diepenveen is a regolith breccia with an overall petrology consistent with a CM classification. Unlike most other CM chondrites, the bulk oxygen isotopes are extremely ¹⁶O rich, apparently dominated by the signature of anhydrous minerals, distributed on a steep slope pointing to the domain of intrinsic CM water. A small subset plots closer to the normal CM regime, on a parallel line 2 ‰ lower in δ¹⁷O. Different lithologies in Diepenveen experienced varying levels of aqueous alteration processing, being less aqueously altered at places rather than more heated. The presence of an agglutinate grain and the properties of methanol‐soluble organic compounds point to active impact processing of some of the clasts. Diepenveen belongs to a CM clan with ~5 Ma CRE age, longer than most other CM chondrites, and has a relatively young K‐Ar resetting age of ~1.5 Ga. As a CM chondrite, Diepenveen may be representative of samples soon to be returned from the surface of asteroid (162173) Ryugu by the Hayabusa2 spacecraft.     

Eddy covariance measurements of carbon dioxide,latent and sensible energy fluxes above a meadow on a mountain slope

Carbon dioxide, latent and sensible heat fluxes were measured by means of the eddy covariance method above a mountain meadow situated on a steep slope in the Stubai Valley in Austria, based on the hypothesis that, due to the low canopy height, measurements can be made in the shallow equilibrium layer where the wind field exhibits characteristics akin to level terrain. In order to test the validity of this hypothesis and to identify effects of complex terrain in the turbulence measurements, data were subjected to a rigorous testing procedure using a series of quality control measures established for surface-layer flows. The resulting high quality dataset comprised 36% of the original observations, the substantial reduction being mainly due to a change in surface roughness and associated fetch limitations in the wind sector dominating during nighttime and transition periods. The validity of the high quality dataset was further assessed by two independent tests: (i) a comparison with the net ecosystem carbon dioxide exchange measured by means of ecosystem chambers, and (ii) the ability of the eddy covariance measurements to close the energy balance. The net ecosystem CO₂ exchange measured by the eddy covariance method agreed reasonably well with ecosystem chamber measurements. The assessment of the energy balance closure showed that there was no significant difference in the correspondence between the meadow on the slope and another one situated on flat ground at the bottom of the Stubai Valley, available energy being underestimated by 28% and 29%, respectively. We thus conclude that, appropriate quality control provided, the eddy covariance measurements made above a mountain meadow on a steep slope are of similar quality as compared to flat terrain.     

A survey of the selenochemistry of major,minor and trace elements

Average data for igneous and/or metaigneous rocks and soils from seven lunar sites are presented. There are compositional similarities between Apollo 11 and Luna 16 eastern maria, Ap 12 and 15 western maria and between Ap 16 and L 20 highlands. Subtle differences do exist between the paired mare sites and the two highland sites and striking differences between the eastern and western maria. Chondritic normalized REE (rare earth element) patterns for igneous rocks and soils from all sites range from 7-350 generally with negative Eu anomalies. Anorthositic gabbroes to anorthosites, presumably highland material, exhibit a positive Eu anomaly. The REE patterns or Sr isotopic ratios suggest two lava flows each for the L 16 and Ap 14 sites, at least four lava flows for the Ap 11 and 12 site and about six for the Ap 15 site. Paucity of lunar andesites suggests rather limited lunar chemical differentiation. Norite-KREEP is a prominent component at Ap 12, 14 and 15, less at Ap 11 and 16 and L 16 and apparently very low at the L 20 highland site. Derivation of lunar soils can be best explained using multi-component mixing systems. Characterization of meteoritic impacting bodies is also observed in addition to a steady state veil of 1.9% carbonaceous Cl like material in soils. Interelement correlations impose constraints on the primitive composition of the Moon and on magmatic processes like selective volatilization.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.     

On the Measurement of PANs by Gas Chromatography and Electron Capture Detection

A fast, automated, gas chromatographic system for the airborne measurement of PAN and a series of its homologues is described and its performance is evaluated. Response factors for PAN, PPN, APAN, PiBN, and MPAN have been determined and are discussed with regard to ECD response and to potential losses in the analytical system. Calibration methods used for these tasks are described and compared. The results from this work should help investigators who are employing the widely used GC/ECD method for the measurement of peroxyacyl nitrates to evaluate peaks of PAN homologues that cannot be calibrated for by using the reported response factors.     

Population synthesis of H ii galaxies

We study the stellar population of galaxies with active star formation, determining ages of the stellar components by means of spectral population synthesis of their absorption spectra. The data consist of optical spectra of 185 nearby ( z 0.075) emission-line galaxies . They are mostly H  ii galaxies, but we also include some starbursts and Seyfert 2s, for comparison purposes. They were grouped into 19 high signal-to-noise ratio template spectra, according to their continuum distribution, absorption- and emission-line characteristics. The templates were then synthesized with a star cluster spectral base.
The synthesis results indicate that H  ii galaxies are typically age-composite stellar systems, presenting important contributions from generations up to as old as 500 Myr. We detect a significant contribution of populations with ages older than 1 Gyr in two groups of H  ii galaxies. The age distributions of stellar populations among starbursts can vary considerably despite similarities in the emission-line spectra. In the case of Seyfert 2 groups we obtain important contributions from the old population, consistent with a bulge.
From the diversity of star formation histories, we conclude that typical H  ii galaxies in the local Universe are not systems presently forming their first stellar generation.     

Zircon-scale insights into the history of a Supervolcano,Bishop Tuff,Long Valley,California, with implications for the Ti-in-zircon geothermometer

Zircon has the outstanding capacity to record chronological, thermal, and chemical information, including the storage history of zoned silicic magma reservoirs like the one responsible for the Bishop Tuff of eastern California, USA. Our novel ion microprobe approach reveals that Bishop zircon rims with diverse chemical characteristics surround intermediate domains with broadly similar compositions. The highest Y, REE, U, and Th concentrations tend to accompany the largest excesses in Y + REE³⁺:P beyond what can be explained by xenotime substitution in zircon. Apparent Ti-in-zircon temperatures of <720°C for zircon rims are distinctly lower than most of the range in eruption temperatures, as estimated from FeTi-oxide equilibria and zircon solubility at quench. While permissive of crystallization of zircon at near-solidus conditions, the low Ti-in-zircon temperatures are probably better explained by sources of inaccuracy in the temperature estimates. After apparently nucleating from different melts, zircons from across the Bishop Tuff compositional spectrum may have evolved to broadly similar chemical and thermal conditions and therefore it is possible that there was no significant thermal gradient in the magma reservoir at some stage in its evolution. There is also no compelling evidence for punctuated heat ± chemical influxes during the intermediate stages of zircon growth. Judging by the zircon record, the main volume of the erupted magma evolved normally by secular cooling but the latest erupted portion is characterized by a reversal in chemistry that appears to indicate perfusion of the magma reservoir by—or zircon entrainment in—a less evolved melt from the one in which the zircons had previously resided.     

Line shape of the non-thermal 6300 Å O(1D) emission

The line shape of the non-thermal O(¹D) 6300 Å emission is calculated using the two population model of Schmitt, Abreu and Hays (Planet. Space Sci.29, 1095, 1981). The calculated line shapes simulate observations made from a space platform at different zenith angles and altitudes. The non-thermal line shapes observed at zenith angles other than the local vertical have been obtained by using the Addition theorem for spherical harmonics of a Legendre polynomial expansion of the non-thermal population distribution function.