Sulfuric Acid Production on Europa: The Radiolysis of Sulfur in Water Ice

Europa's surface is chemically altered by radiolysis from energetic charged particle bombardment. It has been suggested that hydrated sulfuric acid (H₂SO₄·nH₂O) is a major surface species and is part of a radiolytic sulfur cycle, where a dynamic equilibrium exists between continuous production and destruction of sulfur polymers S_x, sulfur dioxide SO₂, hydrogen sulfide H₂S, and H₂SO₄·nH₂O. We measured the rate of sulfate anion production for cyclo-octal sulfur grains in frozen water at temperatures, energies, and dose rates appropriate for Europa using energetic electrons. The measured rate is G_Mixture(SO₄²⁻)=f_Sulfur (r₀/r)^βG₁ molecules (100 eV)⁻¹, where f_Sulfur is the sulfur weight fraction, r is the grain radius, r₀=50 μm, β≈1.9, and G₁=0.4±0.1. Equilibrium column densities N are derived for Europa's surface and follow the ordering N(H₂SO₄) » N(S)>N(SO₂)>N(H₂S). The lifetime of a sulfur atom on Europa's surface for radiolysis to H₂SO₄ is τ(−S)=120(r/r₀)^β years. Rapid radiolytic processing hides the identity of the original source of the sulfurous material, but Iogenic plasma ion implantation and an acidic or salty ocean are candidate sources. Sulfate salts, if present, would be decomposed in <3800 years and be rapidly assimilated into the sulfur cycle.     

Small hypervelocity particles captured in aerogel collectors: Location,extraction, handling and storage

Abstract— It has now been about a decade since the first demonstrations that hypervelocity particles could be captured, partially intact, in aerogel collectors. But the initial promise of a bonanza of partially‐intact extraterrestrial particles, collected in space, has yet to materialize. One of the difficulties that investigators have encountered is that the location, extraction, handling and analysis of very small (10 μm and less) grains, which constitute the vast majority of the captured particles, is challenging and burdensome. Furthermore, current extraction techniques tend to be destructive over large areas of the collectors. Here we describe our efforts to alleviate some of these difficulties. We have learned how to rapidly and efficiently locate captured particles in aerogel collectors, using an automated microscopic scanning system originally developed for experimental nuclear astrophysics. We have learned how to precisely excavate small access tunnels and trenches using an automated micromanipulator and glass microneedles as tools. These excavations are only destructive to the collector in a very small area—this feature may be particularly important for excavations in the precious Stardust collectors. Using actuatable silicon microtweezers, we have learned how to extract and store “naked” particles—essentially free of aerogel—as small as 3 μm in size. We have also developed a technique for extracting particles, along with their terminal tracks, still embedded in small cubical aerogel blocks. We have developed a novel method for storing very small particles in etched nuclear tracks. We have applied these techniques to the extraction and storage of grains captured in aerogel collectors (Particle Impact Experiment, Orbital Debris Collector Experiment, Comet‐99) in low Earth orbit.     

Spectral development of a solar X-ray burst observed on OSO-7

The UCSD solar X-ray instrument on the OSO-7 satellite observes X-ray bursts in the 2–300 keV range with 10.24 s time resolution. Spectra obtained from the proportional counter and scintillation counter are analyzed for the event of November 16, 1971, at 0519 UT in terms of thermal (exponential spectrum) and non-thermal (power law) components. The energy content of the approximately 20 × 10⁶K thermal plasma increased with the 60 s duration hard X-ray burst which entirely preceded the 5 keV soft X-ray maximum. If the hard X-rays arise by thick target bremsstrahlung, the nonthermal electrons above 10 keV have sufficient energy to heat the thermally emitting plasma. In the thin target case the collisional energy transfer from non-thermal electrons suffices if the power law electron spectrum is extrapolated below 10 keV, or if the ambient plasma density exceeds 4 × 10¹⁰ cm^–3.Formerly at UCSD.     

Reconstructing the 3D Morphology of the 17 May 2008 CME

We model the kinematics and three-dimensional distribution of mass in a coronal mass ejection (CME) observed on 17 May 2008, using a comprehensive analysis of STEREO images of the CME. The CME is a surprisingly fast one for solar minimum, reaching velocities of up to 1120 km?s^?1. It can be followed continuously from inception all the way out to 1 AU. We find that the appearance of the CME can be modeled reasonably well as a combination of two distinct fronts that expand outward in a self-similar fashion. The model implies that STEREO-B is struck by the weaker of these two fronts on 19 May, and the in situ instruments on STEREO-B do see a weak density and magnetic field enhancement at the expected time.     

Volcanogenic massive sulfide deposits of ophiolite associations

Volcanogenic massive sulfide deposits in ophiolite complexes are usually attributed to the Cyprus type. They associate with basaltic volcanics that are formed in mid-ocean or back-arc spreading centers and much less frequently in intra-plate settings. The deposits are characterized by copper or copper-zinc ores that are enriched in Ni, Co, and in places Mn and As, but are very poor in Pb and demonstrate a low to moderate content of Ag and Au. Typically, the deposits are low to very low in ore and metal reserves. Cyprus-type deposits were irregularly distributed during geological history. The most ancient of them were formed in the Neoproterozoic, while the bulk of the deposits are Ordovician or Cretaceous in age. Their possible Paleoproterozoic analogues can be found in the Svecofennian belt (Outokumpu ore district), while modern ones are confined to the Explorer and Endeavour Ridges and southern segment of the Juan de Fuca Ridge.     

The stellar content of a spiral arm of NGC 4321

The effects of the passage of a spiral arm through the disc of the giant Virgo Sc galaxy NGC 4321 are investigated with Hubble Space Telescope WFPC2 images in two colours. Concentrating on a portion of the southern spiral arm of NGC 4321, we have applied a new program to solve for the star formation histories in the arm and interarm regions separately. The observational uncertainties and the variable crowding across the spiral arm are taken into account using the results of artificial star tests. In the interarm regions the data are consistent with a constant star formation rate for the last 50 Myr while the stars in the arm region show a star formation rate four times larger than in the interarm regions in the last 5 Myr.     

Chironomids as indicators of climate change: a 100‐lake training set from a subarctic region of northern Sweden (Lapland)

Multivariate numerical analyses (DCA, CCA) were used to study the distribution of chironomids from surface sediments of 100 lakes spanning broad ecoclimatic conditions in northern Swedish Lapland. The study sites range from boreal forest to alpine tundra and are located in a region of relatively low human impact. Of the 19 environmental variables measured, ordination by CCA identified mean July air temperature as one of the most significant variables explaining the distribution and the abundance of chironomids. Lossonignition (LOI), maximum lake depth and mean January air temperature also accounted for significant variation in chironomid assemblages. A quantitative transfer function was created to estimate mean July air temperature from sedimentary chironomid assemblages using weightedaveraging partial least squares regression (WAPLS). The coefficient of determination was relatively high (r² = 0.65) with root mean squared error of prediction (RMSEP, based on jack-knifing) of 1.13 °C and maximum bias of 2.1 °C, indicating that chironomids can provide useful quantitative estimates of past changes in mean July air temperature. The paper focuses mainly on the relationship between chironomid composition and July air temperature, but the relationship to LOI and depth are also discussed.