Klyuchevskoy volcano, in Kamchatka’s subduction zone, is one of the most active arc volcanoes in the world and contains some
of the highest δ
18O values for olivines and basalts. We present an oxygen isotope and melt inclusion study of olivine phenocrysts in conjunction
with major and trace element analyses of
14C- and tephrochronologically-dated tephra layers and lavas spanning the eruptive history of Klyuchevskoy. Whole-rock and groundmass
analyses of tephra layers and lava samples demonstrate that both high-Mg (7–12.5 wt% MgO) and high-Al (17–19 wt% Al
2O
3, 3–6.5 wt% MgO) basalt and basaltic andesite erupted coevally from the central vent and flank cones. Individual and bulk
olivine δ
18O range from normal MORB values of 5.1‰ to values as high as 7.6‰. Likewise, tephra and lava matrix glass have high-δ
18O values of 5.8–8.1‰. High-Al basalts dominate volumetrically in Klyuchevskoy’s volcanic record and are mostly high in δ
18O. High-δ
18O olivines and more normal-δ
18O olivines occur in both high-Mg and high-Al samples. Most olivines in either high-Al or high-Mg basalts are not in oxygen
isotopic equilibrium with their host glasses, and Δ
18O
olivine–glass values are out of equilibrium by up to 1.5‰. Olivines are also out of Fe–Mg equilibrium with the host glasses, but to a lesser
extent. Water concentrations in olivine-hosted melt inclusions from five tephra samples range from 0.4 to 7.1 wt%. Melt inclusion
CO
2 concentrations vary from below detection (<50 ppm) to 1,900 ppm. These values indicate depths of crystallization up to ~17
km (5 kbar). The variable H
2O and CO
2 concentrations likely reflect crystallization of olivine and entrapment of inclusions in ascending and degassing magma. Oxygen
isotope and Fe–Mg disequilibria together with melt inclusion data indicate that olivine was mixed and recycled between high-Al
and high-Mg basaltic melts and cumulates, and Fe–Mg and δ
18O re-equilibration processes were incomplete. Major and trace elements in the variably high-δ
18O olivines suggest a peridotite source for the parental magmas. Voluminous, highest in the world with respect to δ
18O, and hydrous basic volcanism in Klyuchevskoy and other Central Kamchatka depression volcanoes is explained by a model in
which the ascending primitive melts that resulted from the hydrous melt fluxing of mantle wedge peridotite, interacted with
the shallow high-δ
18O lithospheric mantle that had been extensively hydrated during earlier times when it was part of the Kamchatka forearc. Following
accretion of the Eastern Peninsula terrains several million years ago, a trench jump eastward caused the old forearc mantle
to be beneath the presently active arc. Variable interaction of ascending flux-melting-derived melts with this older, high-δ
18O lithospheric mantle has produced mafic parental magmas with a spectrum of δ
18O values. Differentiation of the higher δ
18O parental magmas has created the volumetrically dominant high-Al basalt series. Both basalt types incessantly rise and mix
between themselves and with variable in δ
18O cumulates within dynamic Klyuchevskoy magma plumbing system, causing biannual eruptions and heterogeneous magma products.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
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