Measurements of the elastic and anelastic properties of sandstone flooded with supercritical CO2

The aim of this study was to investigate the effects of supercritical CO₂ (scCO₂) injection on the elastic and anelastic properties of sandstone at seismic and ultrasonic frequencies. We present the results of the low‐frequency and ultrasonic experiments conducted on water‐saturated sandstone (Donnybrook, Western Australia) flooded with scCO₂. The sandstone was cut in the direction perpendicular to a formation bedding plane and tested in a Hoek triaxial pressure cell. During the experiments with scCO_2, the low‐frequency and ultrasonic systems and the pump dispensing scCO₂ were held at a temperature of 42°C. The elastic parameters obtained for the sandstone with scCO₂ at seismic (0.1 Hz–100 Hz) and ultrasonic (～0.5 MHz) frequencies are very close to those for the dry rock. The extensional attenuation was also measured at seismic frequencies for the dry, water‐saturated, and scCO₂‐injected sandstones. The applicability of Gassmann's fluid substitution theory to obtained results was also tested during the experiments.     

Mesoscale circulation along the Sakhalin Island eastern coast

The seasonal and interannual variability of mesoscale circulation along the eastern coast of the Sakhalin Island in the Okhotsk Sea is investigated using the AVISO velocity field and oceanographic data for the period from 1993 to 2016. It is found that mesoscale cyclones with the horizontal dimension of about 100 km occur there predominantly during summer, whereas anticyclones occur predominantly during fall and winter. The cyclones are generated due to a coastal upwelling forced by northward winds and the positive wind stress curl along the Sakhalin coast. The anticyclones are formed due to an inflow of low-salinity Amur River waters from the Sakhalin Gulf intensified by southward winds and the negative wind stress curl in the cold season. The mesoscale cyclones support the high biological productivity at the eastern Sakhalin shelf in July– August.     

Magnetocentrifugal launching of jets from discs around Kerr black holes

Strong magnetic fields modify particle motion in the curved space–time of spinning black holes and change the stability conditions of circular orbits. We study conditions for magnetocentrifugal jet launching from accretion discs around black holes, whereby large-scale black hole lines anchored in the disc may fling tenuous coronal gas outwards. For a Schwarzschild black hole, magnetocentrifugal launching requires that the poloidal component of magnetic fields makes an angle less than  60°  to the outward direction at the disc surface, similar to the Newtonian case. For prograde rotating discs around Kerr black holes, this angle increases and becomes  90°  for footpoints anchored to the disc near the horizon of a critically spinning   a = M   black hole. Thus, a disc around a critically spinning black hole may centrifugally launch a jet even along the rotation axis.     

Research note: Laboratory study of the influence of changing the injection rate on the geometry of the fluid front and on P‐wave ultrasonic velocities in sandstone

Forced imbibition was performed in reservoir sandstone by injecting water into a dry sample. The injection was monitored with X‐ray computed tomography and acoustic acquisition to simultaneously visualize the displacement of the fluid and quantify its presence by calculating saturation and P‐wave velocities. We observed a strong influence when changing the injection rates on the acoustic response. Upon decreasing the injection rate from 5 mL/h to 0.1 mL/h, P‐wave velocities decreased sharply: 100 m/s in 1 h. This behaviour is related to the partially saturated conditions of the sample (76% of saturation) before decreasing the injection rate. The air that is still trapped is free to move due to a decrease of pore pressure that is no longer forced by the higher injection rate. After 1 hour, P‐wave velocities started increasing with small changes in saturation. Stopping injection for 16 hrs decreased saturation by 8% and P‐wave velocities by 100 m/s. Restarting injection at 5 mL/h increased saturation to 76% while P‐wave velocities fluctuated considerably for 2 hrs until they stabilized at 2253 m/s. Through the computed tomography scans we observed a water front advancing through the sample and how its shape changed from a plane to a curve after decreasing the injection rate.     

The role and conditions of second-stage mantle melting in the generation of low-Ti tholeiites and boninites: the case of the Manihiki Plateau and the Troodos ophiolite

High-Mg, low-Ti volcanic rocks from the Manihiki Plateau in the Western Pacific share many geochemical characteristics with subduction-related boninites such as high-Ca boninites from the Troodos ophiolite on Cyprus, which are believed to originate by hydrous re-melting of previously depleted mantle. In this paper we compare the Manihiki rocks and Troodos boninites using a new dataset on the major and trace element composition of whole rocks and glasses from these locations, and new high-precision, electron microprobe analyses of olivine and Cr-spinel in these rocks. Our results show that both low-Ti Manihiki rocks and Troodos boninites could originate by re-melting of a previously depleted lherzolite mantle source (20–25% of total melting with 8–10% melting during the first stage), as indicated by strong depletion of magmas in more to less incompatible elements (Sm/Yb < 0.8, Zr/Y < 2, Ti/V < 12) and high-Cr-spinel compositions (Cr# > 0.5). In comparison with Troodos boninites, the low-Ti Manihiki magmas had distinctively lower H₂O contents (< 0.2 vs. > 2 wt% in boninites), ~ 100 °C higher liquidus temperatures at a given olivine Fo-number, lower fO₂ (ΔQFM < + 0.2 vs. ΔQFM > + 0.2) and originated from deeper and hotter mantle (1.4–1.7 GPa, ~ 1440 °C vs. 0.8–1.0 GPa, ~ 1300 °C for Troodos boninites). The data provide new evidence that re-melting of residual upper mantle is not only restricted to subduction zones, where it occurs under hydrous conditions, but can also take place due to interaction of previously depleted upper mantle with mantle plumes from the deep and hotter Earth interior.     

Abiotic reduction of uranium by Fe(II) in soil

Structural Fe(II) has been shown to reduce several oxidized environmental contaminants, including NO₃, chlorinated solvents, Cr(VI), and U(VI). Studies investigating reduction of U(VI) by soils and sediments, however, suggest that abiotic reduction of U(VI) by Fe(II) is not significant, and that direct enzymatic reduction of U(VI) by metal-reducing bacteria is required for U(VI) immobilization as U(IV). Here evidence is presented for abiotic reduction and immobilization of U(VI) by structural Fe(II) in a redoximorphic soil collected from a hillside spring in Iowa. Oxidation of Fe(II) in the soil after reaction with U(VI) was demonstrated by Mössbauer spectroscopy and reduction of U(VI) by the pasteurized soil using U L_III-edge X-ray absorption spectroscopy (XAS). XAS indicates that both reduced U(IV) and oxidized U(VI) or U(V) are present after U(VI) interaction with the Fe(II) containing soil. The EXAFS data show the presence of a non-uraninite U(IV) phase and evidence of the oxidized U(V) or U(VI) fraction being present as a non-uranyl species. Little U(VI) reduction is observed by soil that has been exposed to air and oxidation of Fe(II) to goethite has occurred. Soil characterization based on chemical extractions, Mössbauer spectroscopy, and Fe K-edge XAS indicate that the majority of Fe(II) in the soil is structural in nature, existing in clay minerals and possibly a green rust-like phase. These data provide compelling evidence for abiotic reduction of U(VI) by structural Fe(II) from soil near Fe-rich oxic–anoxic boundaries in natural environments. The work highlights the potential for abiotic reduction of U(VI) by Fe(II) in reduced, Fe-rich environments.     

Turning off low and high currents in a transmitter loop used in the transient electromagnetic method

In near-surface transient electromagnetic studies, it is desirable to measure the transient response starting from the earliest possible time. This requires the current in the transmitter loop to be switched off quickly, which necessitates working with a low transmitter current. As for deep-target transient electromagnetic studies, the transmitter current is as high as possible. The transmitter current's turn-off waveform and total duration affect the transient voltage response, especially at early times, which is to be accounted for when interpreting transient electromagnetic data. This article discusses the difference in switching off low and high current in a horizontal loop used as the source of the primary magnetic field in the transient electromagnetic method. Low and high currents are turned off in fundamentally different ways. When the current to be switched off is low, the loop can be represented as a symmetric combination of two transmission lines grounded at the middle of the loop perimeter. Such a representation of a loop allows calculating the current turn-off waveform at any point of the loop. The waveform and total duration of switching off a low current does not depend on its magnitude, but is determined by the period of natural oscillations of the current in the loop and the resistance of a shunting resistor. Switching off a low current in a loop can be represented as the sum of stepped current waves travelling along the loop wire. As a consequence, the current at different points of the loop perimeter is turned off at different times. In contrast to a low current, a high current is switched off linearly in time and synchronously at all points of the loop perimeter. The wave phenomena appear only at the very beginning of the current shutdown for a time interval that is much less than the total current turn-off duration. Presentation of the loop using a simple lumped-circuit model predicts the waveform and duration of the high current turn-off that coincide with the measured ones. There are two reasons why the article may be of interest to those engaged in the theory and/or practice of electromagnetic geophysical methods. First, it contributes to a general understanding of how the current in the transmitter loop is turned off. Second, the article shows how the parameters of a transmitter loop determine the current turn-off duration and thus the minimum depth of the transient electromagnetic sounding method.     

Water retention effects on elastic properties of Opalinus shale

Shales play an important role in many engineering applications such as nuclear waste, CO₂ storage and oil or gas production. Shales are often utilized as an impermeable seal or an unconventional reservoir. For both situations, shales are often studied using seismic waves. Elastic properties of shales strongly depend on their hydration, which can lead to substantial structural changes. Thus, in order to explore shaly formations with seismic methods, it is necessary to understand the dependency of shale elastic properties on variations in hydration. In this work, we investigate structural changes in Opalinus shale at different hydration states using laboratory measurements and X-ray micro-computed tomography. We show that the shale swells with hydration and shrinks with drying with no visible damage. The pore space of the shale deforms, exhibiting a reduction in the total porosity with drying and an increase in the total porosity with hydration. We study the elastic properties of the shale at different hydration states using ultrasonic velocities measurements. The elastic moduli of the shale show substantial changes with variations in hydration, which cannot be explained with a single driving mechanism. We suggest that changes of the elastic moduli with variations in hydration are driven by multiple competing factors: (1) variations in total porosity, (2) substitution of pore-filling fluid, (3) change in stiffness of contacts between clay particles and (4) chemical hardening/softening of clay particles. We qualitatively and quantitatively analyse and discuss the influence of each of these factors on the elastic moduli. We conclude that depending on the microstructure and composition of a particular shale, some of the factors dominate over the others, resulting in different dependencies of the elastic moduli on hydration.     

Reconnaissance paleomagnetism of Late Triassic blocks, Kuyul region, Northern Kamchatka Peninsula, Russia

The northernmost Kamchatka Peninsula is located along the northwestern margin of the Bering Sea and consists of complexly deformed accreted terranes. Progressing inland from the northwestern Bering Sea, the Olyutorskiy, Ukelayat and Koryak superterranes (OLY, UKL and KOR) are crossed. These terranes were accreted to the backstop Okhotsk-Chukotsk volcanic-plutonic belt (OChVB) in northernmost Kamchatka. A sedimentary sequence of Albian to Maastrichtian age overlaps the terranes and units of the Koryak superterrane, and constrains their accretion time. A paleomagnetic study of blocks within the Kuyul (KUY) terrane of the Koryak superterrane was completed at two localities (Camp 2: λ=61.83°N, φ=165.83°E and Camp 3: λ=61.67°N, φ=164.75°E). At both localities, paleomagnetic samples were collected from Late Triassic (225–208 Ma) limestone blocks (2–10 m in outcrop height) within a melange zone. Although weak in remanent magnetization, two components of remanent magnetization were observed during stepwise thermal demagnetization at 32 sites. The A component of magnetization was observed between room temperature and approximately 250 °C. This magnetic component is always of downward directed inclination and shows the best grouping at relatively low degrees of unfolding. Using McFadden–Reid inclination-only statistics and averaging all site means, the resulting A component mean is I_opt=60.3°, I₉₅=5.0° and n=36 (sites). The B magnetic component is observed up to 565 °C, at which temperature, most samples have no measurable remanent magnetization, or growth of magnetic minerals has disrupted the thermal demagnetization process. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, where bedding orientation differs within a block, most of these sites show the best grouping of B component directions at 100% unfolding, and two of the blocks display remanent magnetizations of both upward and downward directed magnetic inclination. Combining sites with Fisher estimates of kappa (k-value)≥13 and n (sites)≥3, the resulting overall B component paleolatitude and associated uncertainty are λ_obs=30.4°N or S, λ₉₅=8.9° and n=19 (sites). When compared with the expected North America paleolatitude of λ_{APWP expected}=57.9°N, our data support a model in which blocks within the Koryak superterrane are allochthonous and far travelled.