The humin structure of mucilage aggregates in the Adriatic and Tyrrhenian seas: hypothesis about the reasonable causes of mucilage formation

Sixteen mucilages sampled in the Adriatic and Tyrrhenian seas during 1999–2001 were characterised using spectroscopic [Fourier transform infrared spectroscopy (FTIR); colorimetric], chromatographic [thin-layer chromatography (TLC)], and elemental analysis techniques. Most samples contained comparable fractions of organic and inorganic compounds, with the exception of a few samples where the inorganic fraction was greater than the organic fraction. Carbohydrates were important in the samples rich in organic matter, while carbonate and silica (quartz and biogenic silica) were the most important constituents of the inorganic fraction. Carbonate and silica were the only important constituents of the samples with a very low organic content.According to chemical analyses, mucilage aggregates show the typical structure of humin—the insoluble fraction of the humic substance. Classification of mucilage samples as humin-like compounds, together with a reexamination of the factors involved in the formation of organic aggregates in marine environment, has led to the formulation of a reasonable hypothesis for mucilage formation.     

Bacterial response to seasonal changes in labile organic matter composition on the continental shelf and bathyal sediments of the Cretan Sea

Bacterial abundance, biomass and cell size were studied in the oligotrophic sediments of the Cretan Sea (Eastern Mediterranean), in order to investigate their response to the seasonal varying organic matter (OM) inputs. Sediment samples were collected on a seasonal basis along a transect of seven stations (ranging from 40 to 1570 m depth) using a multiple-corer. Bacterial parameters were related to changes in chloroplastic pigment equivalents (CPE), the biochemical composition (proteins, lipids, carbohydrates) of the sedimentary organic matter and the OM flux measured at a fixed station over the deep basin (1570 m depth). The sediments of the Cretan Sea represent a nutrient depleted ecosystem characterised by a poor quality organic matter. All sedimentary organic compounds were found to vary seasonally, and changes were more evident on the continental shelf than in deeper sediments. Bacterial abundance and biomass in the sediments of the Cretan Sea (ranging from 1.02 to 4.59 × 10⁸ cells g⁻¹ equivalent to 8.7 and 38.7 μgC g⁻¹) were quite high and their distribution appeared to be closely related to the input of fresh organic material. Bacterial abundance and biomass were sensitive to changes in nutrient availability, which also controls the average cell size and the frequency of dividing cells. Bacterial abundance increased up to 3-fold between August '94 and February '95 in response to the increased amount of sedimentary proteins and CPE, indicating that benthic bacteria were constrained more by changes in quality rather than the quantity of the sedimentary organic material. Bacterial responses to the food inputs were clearly detectable down to 10 cm depth. The distribution of labile organic compounds in the sediments appeared to influence the vertical patterns of bacterial abundance and biomass. Cell size decreased significantly with water depth. Bacterial abundance and biomass were characterised by clear seasonal changes in response to seasonal OM pulses. The strong coupling between protein flux and bacterial biomass together with the strong bacterial dominance over the total biomass suggest that the major part of the carbon flow was channelled through the bacteria and the benthic microbial loop.     

Comparison of four meteorite penetration funnels in the Campo del Cielo crater field,Argentina

Abstract– More craters may be discovered in the future, but as it is currently known, the Campo del Cielo crater field is 18 km long by 4 km at its widest point. Such a distribution of craters suggests that the parent meteoroid entered and traversed the atmosphere at a very low angle relative to horizontal. The crater field contains at least 20 small craters produced by the larger fragments of the parent meteoroid. Four of these are explosion analog craters and the rest are penetration funnels. During four field seasons, we have constructed topographic and magnetic maps of four of the penetration funnels as found, and then dug trenches across them to learn their original structures and recover meteorites preserved within them. Structures of these penetration funnels indicate very low angles of impact, i.e., 9–16° relative to horizontal. This supports the idea that the parent meteoroid traversed the atmosphere at a low angle. Data given here for the four penetration funnels include projectile masses, lengths, widths, depths, and estimates of impact angles and azimuths. One of the penetration funnels described here (No. 6) can almost be classified as an explosion analog crater.     

A case of no-wind plinian fallout at Pululagua caldera (Ecuador): implications for models of clast dispersal

The caldera of Pululagua is an eruptive centre of the Northern Volcanic Zone of the South American volcanic arc, located about 15 km north of Quito, Ecuador. Activity leading to formation of the caldera occurred about 2450 b.p. as a series of volcanic episodes during which an estimated 5–6 km³ (DRE) of hornblende-bearing dacitic magma was erupted. A basal pumice-fall deposit covers more than 2.2x10⁴ km² with a volume of about 1.1 km³ and represents the principal and best-preserved plinian layer. Circular patterns of isopachs and pumice, lithic and Md isopleths of the Basal Fallout (BF) around the caldera indicate emplacement in wind-free conditions. Absence of wind is confirmed by an ubiquitous, normally graded, thin ash bed at the top of the lapilli layer which originated from slow settling of fines after cessation of the plinian column (co-plinian ash). The unusual atmospheric conditions during deposition make the BF deposit particularly suitable for the application and evaluation of pyroclast dispersal models. Application of the Carey and Sparks' (1986) model shows that whereas the 3.2-, 1.6-, and 0.8-cm lithic isopleths predict a model column height of about 36 km, the 6.4-cm isopleth yields and estimate of only 21 km. The 4.9- and 6.4-cm isopleths yield a column height of 28 km using the model of Wilson and Walker (1987). The two models give the same mass discharge rate of 2x10⁸ kg s^-1. A simple exponential decrease of thickness with distance, as proposed by Pyle (1989) for plinian falls, fits well with the BF. Exponential decrease of size with distance is followed by clasts less than about 3 cm, suggesting, in agreement with Wilson and Walker (1987), that only a small proportion of large clasts reach the top of the column. Variations with distance in clast distribution patterns imply that, in order to obtain column heights by clast dispersal models, the distribution should be known from both proximal and distal zones. Knowledge of only a few isopleths, irrespective of their distance from the vent, is not sufficient as seemed justified by the method of Pyle (1989).     

Tsunami risk reduction for densely populated Southeast Asian cities: analysis of vehicular and pedestrian evacuation for the city of Padang, Indonesia, and assessment of interventions

A major tsunamigenic earthquake is expected in the near future along the coast of West Sumatra Province of Indonesia. In the city of Padang, the arrival time of the tsunami is expected to be ~30 min. Currently, there are approximately 400,000 people in the city living within the potential inundation zone. This study aimed to complement the existing research in appraising possible risk reduction interventions, specifically looking at enabling the timely evacuation of the area. This research, developed in consultation with national and local authorities, emergency planners and NGOs, analysed interventions for tsunami risk reduction in Padang through the development of a pedestrian and vehicular evacuation model and the appraisal of possible solutions to enhance the evacuation rates. Some of the conclusions from this research can be applied to other areas in Southeast Asia where the traffic patterns are similar to those in Padang and where the distance to safety is greater than 4–5 km. For the case of Padang, the results show that pedestrian evacuation is strongly preferable to vehicular evacuation due to the limited road capacity and the high population density. In the present situation, however, 70–80 % of the population in Padang could not evacuate within 30 min, even by foot. Common interventions such as widening roads and building bridges prove to be relatively ineffective in this case due to the large distance that has to be covered in a short time. These interventions would only have a decisive impact if a longer evacuation time was available (more than 60 min). In the case of Padang, the evacuation rate in the first 30 min is strongly dependent on the presence/absence of evacuation shelters, whose effectiveness is limited by the capacity of the structures. Building a few high-capacity and high-resilience structures such as evacuation hills is a more effective and robust evacuation strategy than constructing many small high-raised buildings. Even with evacuation structures, wider roads and bridges, about 20 % of the population would still be unable to reach safety by the time the tsunami arrives. This means about 70,000 people of Padang’s current population, which is rapidly increasing. The building of evacuation shelters may be a viable option for saving lives in the short term, but it is not a sustainable option in the medium to long term. It is therefore also necessary to set up and enforce regulations for land use planning that take into account the tsunami risk and prevent further urban development for the areas that may be affected by a tsunami.     

Dynamics of magma mixing and degassing recorded in plagioclase at Stromboli (Aeolian Archipelago,Italy)

Crystal-rich materials (scoriae and lava flows) emitted during the 1985–2000 activity of Stromboli were taken into consideration for systematic study of bulk rock/matrix glass chemistry and in particular for the study of chemical and textural zoning of plagioclase, the most abundant mineral phase. Over the considered time period, bulk rock composition remained fairly constant in both major (SiO₂ 49.2–50.9 wt% and K₂O 1.96–2.18 wt%) and trace elements. The quite constant chemistry of matrix glasses also indicates that the degree of crystallization of magma was maintained at around 50 vol%. Plagioclase ranges in composition between An₆₂ and An₈₈ and is characterized by alternating, <10–100 m thick, bytownitic and labradoritic concentric layers, although the dominant and representative plagioclase of scoriae is An_68. The labradoritic layers (An_62–70) show small-scale (1–5 µm), oscillatory zoning, are free of inclusions, and appear to record episodes of slow crystal growth in equilibrium with a degassed liquid having the composition of the matrix glass. In contrast the bytownitic layers (An₇₀-An₈₈) are patchy zoned, show sieve structure with abundant micrometric glass inclusions and voids, and are attributed to rapid crystal growth.A key to understanding the origin of bytownitic layers can be retrieved from the texture and composition of the coronas of plagioclase xenocrysts, inherited from crystal-rich magma, in nearly aphyric pumice which are erupted during more energetic events and represent a deep, volatile-rich, HK-basaltic magma. They show a continuum from fine-sieve to evident skeletal texture from the inner to the outer part of the corona associated with normal compositional zoning from An₉₀ to An₇₅. In the light of these observations, we propose that input of H₂O-rich melt blobs, and their mixing with the residing magma, causes partial dissolution of the labradoritic layers followed by the growth of bytownitic composition whose sieve texture attests of rapid crystallization occurring under undercooling conditions mainly induced by degassing. As a whole, the zoning of plagioclase in the scoriae records successive and discrete intrusions of volatile-rich magma blobs, its degassing and mixing with the resident degassed magma at shallow level.Editorial responsibility: T.L. GroveAn erratum to this article can be found at     

Impact of single inclined faults on the fluid flow and heat transport: results from 3-D finite element simulations

The impact of inclined faults on the hydrothermal field is assessed by adding simplified structural settings to synthetic models. This study is innovative in carrying out numerical simulations because it integrates the real 3-D nature of flow influenced by a fault in a porous medium, thereby providing a useful tool for complex geothermal modelling. The 3-D simulations for the coupled fluid flow and heat transport processes are based on the finite element method. In the model, one geological layer is dissected by a dipping fault. Sensitivity analyses are conducted to quantify the effects of the fault’s transmissivity on the fluid flow and thermal field. Different fault models are compared with a model where no fault is present to evaluate the effect of varying fault transmissivity. The results show that faults have a significant impact on the hydrothermal field. Varying either the fault zone width or the fault permeability will result in relevant differences in the pressure, velocity and temperature field. A linear relationship between fault zone width and fluid velocity is found, indicating that velocities increase with decreasing widths. The faults act as preferential pathways for advective heat transport in case of highly transmissive faults, whereas almost no fluid may be transported through poorly transmissive faults.