Monitoring the effects of disposal of fine sediments from maintenance dredging on suspended particulate matter concentration in the Belgian nearshore area (southern North Sea)

The impact of continuous disposal of fine-grained sediments from maintenance dredging works on the suspended particulate matter concentration in a shallow nearshore turbidity maximum was investigated during dredging experiment (port of Zeebrugge, southern North Sea). Before, during and after the experiment monitoring of SPM concentration using OBS and ADV altimetry was carried out at a location 5 km west of the disposal site. A statistical analysis, based on the concept of populations and sub-sampling, was applied to evaluate the effect. The data revealed that the SPM concentration near the bed was on average more than two times higher during the dredging experiment. The disposed material was mainly transported in the benthic layer and resulted in a long-term increase of SPM concentration and formation of fluid mud layers. The study shows that SPM concentration can be used as an indicator of environmental changes if representative time series are available.     

A steep-fronted Carboniferous carbonate platform: clinoformal geometry and lithofacies (Picos de Europa, NW Spain)

A steep‐margined carbonate platform is developed in the Carboniferous synorogenic foreland basin of northern Spain. Dips of 60–90° produced during Late Carboniferous thrusting enable cross‐sections of a 4‐km‐wide portion of the marginal area of this platform (Las Llacerias outcrop) to be studied in aerial photographs at a seismic scale. Three stratal domains are observed: (1) a horizontal‐bedded platform; (2) a clinoformal‐bedded margin with a relief of up to 500 m; and (3) a low‐angle toe‐of‐slope, where slope beds interfinger with basin sediments. The slope shows well‐bedded sigmoidal clinoforms with depositional dips ranging from 15° to 32°. Based on lithology and stratal patterns, four facies groups have been recognized: (1) a flat‐topped platform, in which thick algal boundstone, skeletal packstone–grainstone and peloidal micrite wackestone with a poorly rhythmic character prevail; (2) the platform margin and upper slope, characterized by microbial boundstone spanning a bathymetric range of ≈150 m measured from the break of slope; (3) a slope, predominantly composed of margin‐derived rudstones and breccias; and (4) a toe‐of‐slope to basin zone, where a cyclic alternation of spiculitic siltstones, packstone to grainstone calciturbidites and rudstone/breccia is visible. Five successive stages of platform development are deduced: (1) Bashkirian: flooding of the pre‐existing Serpukhovian platform giving rise to the nucleation of a low‐angle ramp to the south‐east of the study area with microbial mud‐mound accumulations, and breccias and calciturbidites on the margins; (2) Early Moscovian: an influx of siliciclastic sediment buried part of the platform and reduced the area of carbonate sedimentation; (3) Moscovian: aggradation and progradation of the carbonate system produced an extensive steep‐margined and flat‐topped shallow‐water platform (shelf system); (4) Latest Moscovian–earliest Kasimovian: drowning of the platform; and (5) Kasimovian: covering of the platform by marly calcareous ramp sediments.     

Effect of organic acids and fluoride on the dissolution kinetics of hydrous alumina. A model study using the rotating disc electrode

The dissolution of aluminium oxide was studied with an oxide film covered rotating disc aluminium electrode. This allows us to make measurements under conditions of well defined mass transport under conditions representative of those found in natural waters (conc. of Al, organic acids and fluoride), and permits us to distinguish between surface-controlled and transport-controlled rates.Under steady-state conditions, the dissolution current is a direct measure of the flux of dissolving Al ions at the aqueous interface of the amorphous hydrous oxide film.At pH 3–6 and in presence of organic ligands, dissolution is controlled by a surface process, i.e. the rate of detachment of surface complexes. Fluoride ions in concentrations ≥ 10^?6 M increase dramatically the dissolution rate: at pH = 4 the process is controlled by convertive diffusion of F^? from the solution to the surface (k_F- = (3.6 ± 0.5) × 10^?2cms^?1). Competitive and reversible adsorption of organic ligands (10^?6 ? 10^?2M) displacing fluoride slows down the rate of detachment of the surface complex which becomes the rate-limiting step. The affinity of ligands for the Al₂O₃ surface sites increases in the sequence: formate ~ chloride ~ carbonate < acetate < sulphate < salicylate < fumarate < maleate < malonate ? oxalate ? fluoride ≤ citrate.The results are compared with simulated weathering experiments and interpreted in terms of the surface complexation model.     

Intraseasonal variability in South America during the cold season

Intraseasonal (IS) variability in South America is analyzed during the cold season using 10–90 day bandpass filtered OLR anomalies (FOLR). IS variability explains a large percentage of variance with maximum values over Paraguay, northeastern Argentina, and southern Brazil. The leading pattern of FOLR, as isolated from an EOF analysis, (Cold Season IS pattern, CSIS), is characterized by a monopole centered over southeastern South America (SESA) with a northwest-southeast orientation. CSIS induces a large modulation on daily precipitation anomalies, especially on both wet spells and daily precipitation extremes, which are favored during positive (wet) CSIS phases. Large-Scale OLR anomalies over the tropical Indian and west Pacific Oceans associated with CSIS exhibit eastward propagation along tropical latitudes. In addition, circulation anomalies in the Southern Hemisphere reveal the presence of an anticyclonic anomaly over Antarctica with opposite-sign anomalies in middle latitudes 10 days before CSIS is maximum as well as evidence of Rossby wave-like patterns. Positive precipitation anomalies in SESA are favored during wet CSIS phases by the intensification of a cyclonic anomaly located further south, which is discernible over the southeastern Pacific for at least 14 days before CSIS peaks. The cyclonic anomaly evolution is accompanied by the intensification of an upstream anticyclonic anomaly, which remains quasi-stationary near the Antarctica Peninsula before the CSIS peak. We speculate that the stationary behavior of the anticyclonic center is favored by a hemispheric circulation anomaly pattern resembling that associated with a negative southern annular mode phase and a wavenumber 3–4 pattern at middle latitudes.     

Late pleistocene/early holocene environments and climates,fauna, and human occupation in the argentine altiplano

The Barro Negro site (23°S lat., 65°37′W long.) in the Altiplano (Puna) of northwestern Argentina contains a well stratified sequence of remains of Hippidion, the American extinct horse, camelids, and archaeological materials, which is the focus of this study. In addition to establishing a reliable chronology, paleoenvironmental information was obtained based on analyses of pollen and stable isotopes (oxygen and carbon) from bone and marl. The data indicate that Hippidion was present at the site between 12,000 and 10,000 yr B. P., at a time when Altoandean grasslands had expanded to lower elevations. By 10,000 yr B.P., when modern semi-arid sub-puna scrub had replaced the Altoandean grasslands, only camelids (Lama or Vicugna) were present, simultaneous with the first evidence of local human occupation. This suggests that a climatic shift from cool and moist (winter rain regime) to warm and dry (summer rain regime) conditions took place simultaneously with the disappearance of the American horse and the appearance of camelids and man.