From London to Liverpool: Evidence for a Limehouse–Reid porcelain connection based on the analysis of sherds from the Brownlow Hill (ca. 1755–1767) factory site

The diversity of Brownlow Hill porcelains of the W^m Reid & Co. era is due to the remarkably wide range in the composition of their pastes and glazes and inferred firing conditions relative to the initial vitrification temperature. Sixteen of 21 analyzed sherds from the factory site are bone‐ash wares that display large variations in their bulk chemical composition. The remaining samples have silicious‐aluminous (akin to “stone china” sensu Richard Pococke in 1750) and silicious‐aluminous‐calcic (“S‐A‐C”) compositions that resemble Limehouse (London) and Pomona (Staffordshire) porcelains produced during the 1740s. The mineralogy of the Brownlow Hill S‐A‐C sherds suggests firing at a relatively high temperature (T_max approaching 1400°C, based on relations on the SiO₂‐Al₂O₃‐CaO phase diagram), thereby obscuring the identity of some of the ingredients (e.g., the source of CaO) used in their manufacture. Limehouse and Brownlow Hill may have been linked through the activities of William Ball, who is mentioned in connection with both factories, or indirectly via former Limehouse staff later employed at the Pomona factory, located not far from a W^m Reid & Co. branch factory in Shelton, Stoke‐on‐Trent. In terms of a time line, knowledge of these pastes appears to have spread first from London to Staffordshire, and then to Liverpool. © 2003 Wiley Periodicals, Inc.     

Holocene rockfalls in the southern Negev Desert,Israel and their relation to Dead Sea fault earthquakes

Rockfall ages in tectonically active regions provide information regarding frequency and magnitude of earthquakes. In the hyper-arid environment of the Dead Sea fault (DSF), southern Israel, rockfalls are most probably triggered by earthquakes. We dated rockfalls along the western margin of the DSF using terrestrial cosmogenic nuclides (TCN). At each rockfall site, samples were collected from simultaneously exposed conjugate boulders and cliff surfaces. Such conjugate samples initially had identical pre-fall (“inherited”) TCN concentrations. After boulder detachment, these surfaces were dosed by different production rates due to differences in post-fall shielding and geometry. However, in our study area, pre-rockfall inheritance and post-rockfall production rates of TCN cannot be evaluated. Therefore, we developed a numerical approach and demonstrated a way to overcome the above-mentioned problems. This approach can be applied in other settings where rockfalls cannot be dated by simple exposure dating. Results suggest rockfall ages between 3.6 ± 0.8 and 4.7 ± 0.7 ka. OSL ages of sediment accumulated behind the boulders range between 0.6 ± 0.1 and 3.4 ± 1.4 ka and support the TCN results. Our ages agree with dated earthquakes determined in paleoseismic studies along the entire length of the DSF and support the observation of intensive earthquake activity around 4–5 ka.     

A 20 cm2 CCD mosaic camera for a dark matter search part I : Mechanics,optics and cryogeny

A 20cm ² CCD mosaic camera has been especially built to search for dark galactic halo objects by the gravitational microlensing effect. The sensitive area is made of 16 edge-buttable CCDs developped by Thomson-CTS, with 23×23 µm ² pixels. The 35 kg camera housing and mechanical equipment is presented. The associated electronics and data acquisition system are described in a separate paper. The camera resides at the focal plane of a 40 cm, f/10, Ferson reflector. The instrument has been in operation since December 1991 at the La Silla Observatory (ESO).     

Groundwater residence time and movement in the Maltese islands – A geochemical approach

The Maltese islands are composed of two limestone aquifers, the Upper and Lower Coralline Limestone separated by an aquitard, the ‘Blue Clay’. The Lower Coralline Limestone is overlain in part by the poorly permeable Globigerina Limestone. The upper perched aquifers are discontinuous and have very limited saturated thickness and a short water level response time to rainfall. Frequent detections of coliforms suggest a rapid route to groundwater. However, the unsaturated zone has a considerable thickness in places and the primary porosity of the Upper Coralline Limestone is high, so there is likely to be older recharge by slow matrix flow as well as rapid recharge from fractures. Measurement of SF₆ from a pumping station in a deep part of one of the perched aquifers indicated a mean saturated zone age of about 15 a. The Main Sea Level aquifers (MSL) on both Malta and Gozo have a large unsaturated thickness as water levels are close to sea level. On Malta, parts of the aquifer are capped by the perched aquifers and more extensively by the Globigerina Limestone. The limited detection of coliform bacteria suggests only some rapid recharge from the surface via fractures or karst features. Transmissivity is low and ³H and CFC/SF₆ data indicate that saturated zone travel times are in the range 15–40 a. On Gozo the aquifer is similar but is more-extensively capped by impermeable Blue Clay. CFC data show the saturated zone travel time is from 25 a to possibly more than 60 a. Groundwater age is clearly related to the extent of low-permeability cover. The δ¹³C signature of groundwater is related to the geochemical processes which occur along the flowpath and is consistent with residence time ages in the sequence; perched aquifers < Malta MSL < Gozo MSL. The ¹⁸O and ²H enriched isotopic signature of post 1983 desalinated water can be seen in more-modern groundwater, particularly the urbanized areas of the perched and Malta MSL aquifers. In all aquifers, movement of solutes from the surface travelling slowly through the matrix provide a long-term source of groundwater contaminants such as NO₃.     

Neoproterozoic contaminated MORB of Wadi Ghadir ophiolite,NE Africa: Geochemical and Nd and Sr isotopic constraints

The ophiolitic metabasalts (pillowed and sheeted dikes) of Wadi Ghadir area, Eastern Desert, Egypt, were analyzed for their major, trace and rare earth elements, Nd and Sr isotopes and the chemistry of their plagioclase, amphibole and chlorite was also reported. Geochemically these rocks range from tholeiitic basalt to basaltic andesite. The generally low MgO, Cr and Ni and high Zr contents are consistent with derivation of these rocks from an evolved magma. The high TiO₂ contents (mostly between 1.76% and 2.23%) classify Wadi Ghadir ophiolitic metabasalts as MORB ophiolite. The chondrite-normalized REE patterns of most samples display small LREE-enrichment with (La/Yb)_n ranging from 1.44 to 2.56. The MORB-normalized spider diagram shows variable LILE abundances, which are either similar to or enriched relative to MORB, and most samples display small Nb depletion. The abundances of some LILE (Ba, Rb and K) as well as Na and Si were modified by post-magmatic seafloor hydrothermal alteration. Enrichment of the least mobile LILE (Th & U) indicates that Wadi Ghadir ophiolitic metabasalts are akin to C (contaminated)-MORB. These geochemical characteristics are similar to BABB modified by contamination.Wadi Ghadir metabasalts have low initial Sr ratios (0.7010–0.7034) which are similar to those of MORB, while their ε_Nd(t) values (+7.7–+4.5) are either more or less positive than the value of depleted mantle (DM). The more positive ε_Nd(t) values indicate DM source for these basalts, while the less positive ε_Nd(t) values reflect the involvement of slightly older component in Wadi Ghadir ophiolite. We suggest that the parent magma of metabasalts was contaminated by slightly older material, most probably oceanic-arc crustal rocks, which caused enrichment in LREE, and by analogy LILE, but did not significantly affect Nd isotopic systematics or modify Sr isotopes.Such contaminated MORB character also revealed by other ophiolitic metavolcanics in the Central Eastern Desert, contrasting the N-MORB character of the Gerf ophiolite in the South Eastern Desert. Moreover, the present work suggests the increase of the degree of contamination of the ophiolitic metabasalts from south to north in the Central Eastern Desert.     

Diversity and origin of abyssal tholeiite from the Mid-Atlantic Ridge near 24° and 30° North latitude

On cursory examination of hand specimens and thin sections, the abyssal tholeiite in a dredge haul may appear to be uniform in composition. Chemical analyses of a considerable number of fragments, however, have always revealed the existence of regular compositional variation in them. The MgO content decreases with increasing SiO₂. In abyssal tholeiites with relatively low Al₂O₃ contents, the SiO₂, total iron, Na₂O and P₂O₅ contents tend to increase and the MgO content tends to decrease with increasing iron/magnesia ratio, probably owing to crystallization differentiation.In a certain dredge haul, high-alumina abyssal tholeiites (with Al₂O₃ contents near or over 17%) occur in association with low-alumina abyssal tholeiites. The magma of high-alumina abyssal tholeiites would be generated from that of low-alumina abyssal tholeiites by differentiation at a depth around 30 km.In pillow lavas of abyssal tholeiite free from weathering and metamorphism, the chilled rim of the pillow usually has virtually the same chemical composition as the more crystalline core except for a decrease of K₂O content toward the rim. On the other hand, the weathered rim of pillow lavas shows marked compositional change. The Fe₂O₃/FeO ratio of unweathered abyssal tholeiite is in the range of 0.1 to 0.3. This ratio and the H₂O^– and H₂O⁺ contents increase with advancing weathering.Lamont-Doherty Geological Observatory Contribution No. 1339     

Neoproterozoic nascent island arc volcanism from the Nubian Shield of Egypt: Magma genesis and generation of continental crust in intra-oceanic arcs

The Neoproterozoic Wadi Ranga metavolcanic rocks, South Eastern Desert of Egypt, constitute a slightly metamorphosed bimodal sequence of low-K submarine tholeiitic mafic and felsic volcanic rocks. The mafic volcanic rocks are represented by massive and pillow flows and agglomerates, composed of porphyritic and aphyric basalts and basaltic andesites that are mostly amygdaloidal. The felsic volcanic rocks embrace porphyritic dacites and rhyolites and tuffs, which overlie the mafic volcanic rocks. The geochemical characteristics of Wadi Ranga volcanic rocks, especially a strong Nb depletion, indicate that they were formed from subduction-related melts. The clinopyroxene phenocrysts of basalts are more akin to those crystallizing from island-arc tholeiitic magmas. The tholeiitic nature of the Wadi Ranga volcanics as well as their LREE-depleted or nearly flat REE patterns and their low K₂O contents suggest that they were developed in an immature island arc setting. The subchondritic Nb/Ta ratios (with the lowest ratio reported for any arc rocks) and low Nb/Yb ratios indicate that the mantle source of the Wadi Ranga mafic volcanic rocks was more depleted than N-MORB-source mantle. Subduction signature was dominated by aqueous fluids derived from slab dehydration, whereas the role of subducted sediments in mantle-wedge metasomatization was subordinate, implying that the subduction system was sediment-starved and far from continental clastic input. The amount of slab-derived fluids was enough to produce hydrous magmas that follow the tholeiitic but not the calc-alkaline differentiation trend. With Mg# > 64, few samples of Wadi Ranga mafic volcanic rocks are similar to primitive arc magmas, whereas the other samples have clearly experienced considerable fractional crystallization.The low abundances of trace elements, together with low K₂O contents of the felsic metavolcanic rocks indicate that they were erupted in a primitive island arc setting. The felsic volcanic rocks are characterized by lower K/Rb ratios compared to the mafic volcanic rocks, higher trace element abundances (~ 2 to ~ 9 times basalt) on primitive arc basalt-normalized pattern and nearly flat chondrite-normalized REE patterns, which display a negative Eu anomaly. These features are largely consistent with fractional crystallization model for the origin of the felsic volcanic rocks. Moreover, SiO₂-REE variations for the Wadi Ranga volcanic rocks display steadily increasing LREE over the entire mafic to felsic range and enriched La abundances in the felsic lavas relative to the most mafic lavas, features which are consistent with production of the felsic volcanic rocks through fractional crystallization of basaltic melts. The relatively large volume of Wadi Ranga silicic volcanic rocks implies that significant volume of silicic magmas can be generated in immature island arcs by fractional crystallization and indicates the significant role of intra-oceanic arcs in the production of Neoproterozoic continental crust. We emphasize that the geochemical characteristics of these rocks such as their low LILE and nearly flat REE patterns can successfully discriminate them from other Egyptian Neoproterozoic felsic volcanic rocks, which have higher LILE, Zr and Nb and fractionated REE patterns.     

Electric charge and magnetic flux on rotating black holes in a force-free magnetosphere

The electric charge on rotating black holes is calculated to be ∼ BJ in the force-free configuration of Ghosh, with a horizon flux of ∼ BM ². This charge is gravitationally weak for B ∼10¹⁵ G , so that the Kerr metric applies. Being similar to the electric charge of a magnetar, both electric charge and magnetic flux should be, in sign and order of magnitude, continuous during stellar collapse into a black hole. Extraction of the rotational energy from newly formed black holes may proceed by interaction with the magnetic field.