Clastic sedimentary features of beachrocks and their palaeo-environmental significance:comparison of past and modern coastal regimes

Clastic sedimentary features of beachrocks and unconsolidated deposits of parent beaches were investigated along the northern Aegean coastline（Greece） to assess their suitability in palaeo-environmental reconstruction.Twelve paired datasets were collected in the Thermaikos,Toroneos,Siggitikos and lerissos gulfs of the Chalkidiki Peninsula,the adjoining Kavala Gulf and Thassos Island,comprising beachrock cores and companion beach subsurface sediments.Particle size analyses based on univariate and bivariate statistics suggest that,during the time period of beachrock formation,depositional conditions differed distinctly from those of the modern parent beaches.The results imply difference of maturity level of beach evolution from the time of cementation（coarser materials-early stage of beach formation） to modern situation（finer materials-reworked and ’mature’ beach sediments）.Furthermore,the findings indicate increasing coastal protection due to beachrock exposure in the modern swash zone.In conclusion,it is suggested that textural analysis of beachrocks in comparison with unconsolidated sediments of the parent beach might provide information regarding differences of coastal depositional regimes and future research could focus on specific-layer analysis and comparison.     

Photoabsorption in Ganymede’s atmosphere

In the framework of future space missions to Ganymede, a pre-study of this satellite is a necessary step to constrain instrument performances according to the mission objectives. This work aims at characterizing the impact of the solar UV flux on Ganymede’s atmosphere and especially at deriving some key physical parameters that are measurable by an orbiter. Another objective is to test several models for reconstructing the solar flux in the Extreme-UV (EUV) in order to give recommendations for future space missions.Using a Beer–Lambert approach, we compute the primary production of excited and ionized states due to photoabsorption, neglecting the secondary production that is due to photoelectron impacts as well as to precipitated suprathermal electrons. Ions sputtered from the surface are also neglected. Computations are performed at the equator and close to the pole, in the same conditions as during the Galileo flyby. From the excitations, we compute the radiative relaxation leading to the atmospheric emissions. We also propose a simple chemical model to retrieve the stationary electron density. There are two main results: (i) the modelled electron density and the one measured by Galileo are in good agreement. The main atmospheric visible emission is the atomic oxygen red line at 630 nm, both in equatorial and in polar conditions, in spite of the different atmospheric compositions. This emission is measurable from space, especially for limb viewing conditions. The OH emission (continuum between 260 and 410 nm) is also probably measurable from space. (ii) The input EUV solar flux may be directly measured or reconstructed from only two passbands solar observing diodes with no degradation of the modelled response of the Ganymede’s atmosphere. With respect to these results, there are two main conclusions: (i) future missions to Ganymede should include the measurement of the red line as well as the measurement of OH emissions in order to constrain the atmospheric model. (ii) None of the common solar proxies satisfactorily describes the level of variability of the solar EUV irradiance. For future atmospheric planetary space missions, it would be more appropriate to derive the EUV flux from a small radiometer rather than from a full-fledged spectrometer.     

The Paris CM chondrite: Secondary minerals and asteroidal processing

We report a petrographic and mineralogical survey of Paris, a new CM chondrite considered to be the least‐altered CM identified so far (Hewins et al. 2014 ). Compared to other CMs, Paris exhibits (1) a higher concentration of Fe‐Ni metal beads, with nickel contents in the range 4.1–8.1 wt%; (2) the systematic presence of thin lamellae and tiny blebs of pentlandite in pyrrhotite grains; and (3) ubiquitous tochilinite/cronstedtite associations with higher FeO/SiO₂ and S/SiO₂ ratios. In addition, Paris shows the highest concentration of trapped ³⁶Ar reported so far for a CM chondrite (Hewins et al. 2014 ). In combination with the findings of previous studies, our data confirm the reliability of (1) the alteration sequence based on the chemical composition of tochilinite/cronstedtite associations to quantify the fluid alteration processes and (2) the use of Cr content variability in type II ferroan chondrule olivine as a proxy of thermal metamorphism. In contrast, the scales based on (1) the Fe³⁺ content of serpentine in the matrix to estimate the degree of aqueous alteration and (2) the chemical composition of Fe‐Ni metal beads for quantifying the intensity of the thermal metamorphism are not supported by the characteristics of Paris. It also appears that the amount of trapped ³⁶Ar is a sensitive indicator of the secondary alteration modifications experienced by chondrites, for both aqueous alteration and thermal metamorphism. Considering Paris, our data suggest that this chondrite should be classified as type 2.7 as it suffered limited but significant fluid alteration and only mild thermal metamorphism. These results point out that two separated scales should be used to quantify the degree of the respective role of aqueous alteration and thermal metamorphism in establishing the characteristics of CM chondrites.     

Mineralogy and petrography of C asteroid regolith: The Sutter's Mill CM meteorite

Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data.     

Multiple precursors of secondary mineralogical assemblages in CM chondrites

We report a petrographic and mineralogical survey of tochilinite/cronstedtite intergrowths (TCIs) in Paris, a new CM chondrite considered to be the least altered CM identified to date. Our results indicate that type‐I TCIs consist of compact tochilinite/cronstedtite rims surrounding Fe‐Ni metal beads, thus confirming kamacite as the precursor of type‐I TCIs. In contrast, type‐II TCIs are characterized by complex compositional zoning composed of three different Fe‐bearing secondary minerals: from the outside inwards, tochilinite, cronstedtite, and amakinite. Type‐II TCIs present well‐developed faces that allow a detailed morphological analysis to be performed in order to identify the precursors. The results demonstrate that type‐II TCIs formed by pseudomorphism of the anhydrous silicates, olivine, and pyroxene. Hence, there is no apparent genetic relationship between type‐I and type‐II TCIs. In addition, the complex chemical zoning observed within type‐II TCIs suggests that the alteration conditions evolved dramatically over time. At least three stages of alteration can be proposed, characterized by alteration fluids with varying compositions (1) Fe‐ and S‐rich fluids; (2) S‐poor and Fe‐ and Si‐rich fluids; and (3) S‐ and Si‐poor, Fe‐rich fluids. The presence of unaltered silicates in close association with euhedral type‐II TCIs suggests the existence of microenvironments during the first alteration stages of CM chondrites. In addition, the absence of Mg‐bearing secondary minerals in Paris TCIs suggests that the Mg content increases during the course of alteration.     

Testing the genetic relationship between fluid alteration and brecciation in CM chondrites

Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration.     

A terrestrial origin for sulfate veins in CI1 chondrites

Abstract— White sulfate veins are a very well‐known petrological feature of the chemically primitive CI1 carbonaceous chondrites. Sulfate veins were first described in the Orgueil meteorite in 1961, almost one century after its fall. However, we have observed such veins to form easily during typical sample storage. We suggest that all CI1 sulfate veins formed during the terrestrial residence of these heavily brecciated, porous stones. Reacting with atmospheric water, sulfates originally present in the meteorites dissolved and remobilized, and/or sulfides oxidised, filling the many open spaces offered to them by the very porous rock. Sulfate veins in CI1 chondrites can no longer be used as evidence of a late‐stage oxidation event in the CI1 parent body, or of centimeter‐scale fluid transport on the parent asteroid.     

The Wuqbah peridotite, central Oman Ophiolite: Petrological characteristics of the mantle in a fossil overlapping ridge setting

The Wuqbah peridotites (Wuqbah massif, central Oman Ophiolite) constitute the mantle part of a complete ophiolitic sequence and their field deformation geometry is thought to reflect mantle dynamics in a fossil overlapping ridge settings (Girardeau et al., 2002). These peridotites comprise dominantly residual harzburgites and dunites. Nearly 70% of the harzburgites are clinopyroxene-free, and the rest contains less than 1%. The mineral chemistry of olivine, pyroxenes and spinel, and whole rock major and rare-earth element data, indicate that the Wuqbah peridotites are all strongly refractory and that they record a major percolation event, marked by strong enrichments in incompatible elements. At the massif scale, the Central Zone contains rocks with the most refractory features (20% melt extraction), as expected in an area of mantle upwelling. In the overlapping ridge senario, it corresponds to the overlap zone whose formation is discussed.     

Quantifying initial and wind forcing uncertainties in the Gulf of Mexico

This study aims at analyzing the combined impact of uncertainties in initial conditions and wind forcing fields in ocean general circulation models (OGCM) using polynomial chaos (PC) expansions. Empirical orthogonal functions (EOF) are used to formulate both spatial perturbations to initial conditions and space-time wind forcing perturbations, namely in the form of a superposition of modal components with uniformly distributed random amplitudes. The forward deterministic HYbrid Coordinate Ocean Model (HYCOM) is used to propagate input uncertainties in the Gulf of Mexico (GoM) in spring 2010, during the Deepwater Horizon oil spill, and to generate the ensemble of model realizations based on which PC surrogate models are constructed for both localized and field quantities of interest (QoIs), focusing specifically on sea surface height (SSH) and mixed layer depth (MLD). These PC surrogate models are constructed using basis pursuit denoising methodology, and their performance is assessed through various statistical measures. A global sensitivity analysis is then performed to quantify the impact of individual modes as well as their interactions. It shows that the local SSH at the edge of the GoM main current—the Loop Current—is mostly sensitive to perturbations of the initial conditions affecting the current front, whereas the local MLD in the area of the Deepwater Horizon oil spill is more sensitive to wind forcing perturbations. At the basin scale, the SSH in the deep GoM is mostly sensitive to initial condition perturbations, while over the shelf it is sensitive to wind forcing perturbations. On the other hand, the basin MLD is almost exclusively sensitive to wind perturbations. For both quantities, the two sources of uncertainty have limited interactions. Finally, the computations indicate that whereas local quantities can exhibit complex behavior that necessitates a large number of realizations, the modal analysis of field sensitivities can be suitably achieved with a moderate size ensemble.     

A conservative leapfrog time stepping method

This paper addresses the issue of the non conservation of tracer that occurs when a leapfrog time stepping scheme is used in association with a Robert-Asselin time filter within the framework of a time varying vertical coordinate system. A re-formulation of both the forcing and filtering terms that provides a globally conservative scheme is presented. Local conservation is then achieved when the model levels and subsequently the sea surface height satisfy a local compatibility condition. The properties of the resulting scheme are illustrated by a global coupled ocean–sea ice model based on the Nucleus for European Modelling of the Ocean (NEMO).