Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania

On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.     

Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania

With a paroxysmal ash eruption on 4 September 2007 and the highly explosive activity continuing in 2008, Oldoinyo Lengai (OL) has dramatically changed its behavior, crater morphology, and magma composition after 25 years of quiet extrusion of fluid natrocarbonatite lava. This explosive activity resembles the explosive phases of 1917, 1940–1941, and 1966–1967, which were characterized by mixed ashes with dominantly nephelinitic and natrocarbonatitic components. Ash and lapilli from the 2007–2008 explosive phase were collected on the slopes of OL as well as on the active cinder cone, which now occupies the entire north crater having buried completely all earlier natrocarbonatite features. The lapilli and ash samples comprise nepheline, wollastonite, combeite, Na-åkermanite, Ti-andradite, resorbed pyroxene and Fe–Ti oxides, and a Na–Ca carbonate phase with high but varying phosphorus contents which is similar, but not identical, to the common gregoryite phenocrysts in natrocarbonatite. Lapilli from the active cone best characterize the erupted material as carbonated combeite–wollastonite–melilite nephelinite. The juvenile components represent a fundamentally new magma composition for OL, containing 25–30 wt.% SiO₂, with 7–11 wt.% CO₂, high alkalies (Na₂O 15–19%, K₂O 4–5%), and trace-element signatures reminiscent of natrocarbonatite enrichments. These data define an intermediate composition between natrocarbonatite and nephelinite, with about one third natrocarbonatite and two thirds nephelinite component. The data are consistent with a model in which the carbonated silicate magma has evolved from the common combeite–wollastonite nephelinite (CWN) of OL by enrichment of CO₂ and alkalies and is close to the liquid immiscible separation of natrocarbonatite from carbonated nephelinite. Material ejected in April/May 2008 indicates reversion to a more common CWN composition.     

Contact metamorphism/hydrothermal alteration of Tertiary basalts from the Isle of Skye,northwest Scotland

Alkali olivine basalts from Skye were simultaneously contact metamorphosed by Tertiary gabbro and granite intrusions and altered by the hydrothermal convection system that the plutons induced. Four metamorphic zones were mapped around the plutons. Furthest from the intrusions, in the primary olivine zone, metabasalts are composed of combinations of igneous olivine, augite, plagioclase, titaniferous magnetite, ilmenite, zeolites, gyrolite, sulfides, and chlorite-smectite intergrowths. Closer to the plutons, in the smectite zone, saponite and carbonate appear, primary olivine and gyrolite disappear, and zeolites decrease dramatically in abundance. Still closer to the plutons, in the amphibole zone, actinolite, edenite, chlorite, sphene, epidote, andradite, and quartz appear and saponite and chlorite-smectite intergrowths disappear. Along parts of the contact between gabbro and basalt, in the orthopyroxeneolivine zone, orthopyroxene, metamorphic olivine, and biotite appear and amphibole, chlorite, sphene, epidote, andradite, carbonate, and quartz disappear. Whole-rock chemical data indicate only minor change in the major-element chemical composition of the metabasalts during progressive metamorphism/hydrothermal alteration. Two-pyroxene eothermometry and various mineral-fluid equilibria suggest the range of peak temperatures attained in the metamorphic zones: orthopyroxene-olivine zone, 900°1, 030° C; amphibole zone, 400°–900° C; smectite and primary olivine zones, < 400° C. Mineralogical and oxygen isotopic alteration of the metabasalts were closely coupled: Basalts from the primary olivine zone with nearly unaltered igneous mineralogies have normal or near-normal wholerock ¹⁸O>+5 (SMOW); mineralogically more altered basalts from the smectite zone have whole-rock ¹⁸O=+2 to +5; still more mineralogically altered basalts from the amphibole zone (with one exception) have ¹⁸O<+ 2; completely recrystallized hornfelses from the orthopyroxene-olivine zone have ¹⁸O<0. The principal mechanism of isotope exchange between basalt and metamorphic/ hydrothermal fluid probably was heterogeneous mineralfluid reaction.Metabasalts from the orthopyroxene-olivine zone are mineralogically fresh pyroxene hornfelses that record crystallization temperatures > 1,000° C yet have highly altered whole-rock oxygen isotope compositions, ¹⁸O<0%. The hornfelses chemically interacted with metamorphic/hydrothermal fluids either at very high temperatures or while they were heated to > 1,000° C or both. Their mineralogy, however, rules out significant water-rock interaction after they cooled below 900° C. Hydrothermal convection on Skye was a two-stage process: (a) fluid flow through wall rocks initially was pervasive while they are heated; (b) fluid flow after the thermal peak in the wall rocks was sufficiently channelized that rocks such as those in the orthopyroxeneolivine zone were isolated from further fluid-rock interaction during all or almost all of the cooling history of the hydrothermal system.     

Testing the genetic relationship between fluid alteration and brecciation in CM chondrites

Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration.     

Influence of the oceanic biology on the tropical Pacific climate in a coupled general circulation model

The influence of chlorophyll spatial patterns and variability on the tropical Pacific climate is investigated by using a fully coupled general circulation model (HadOPA) coupled to a state-of-the-art biogeochemical model (PISCES). The simulated chlorophyll concentrations can feedback onto the ocean by modifying the vertical distribution of radiant heating. This fully interactive biological-ocean-atmosphere experiment is compared to a reference experiment that uses a constant chlorophyll concentration (0.06 mg m⁻³). It is shown that introducing an interactive biology acts to warm the surface eastern equatorial Pacific by about 0.5°C. Two competing processes are involved in generating this warming: (a) a direct 1-D biological warming process in the top layers (0–30 m) resulting from strong chlorophyll concentrations in the upwelling region and enhanced by positive dynamical feedbacks (weaker trade winds, surface currents and upwelling) and (b) a 2-D meridional cooling process which brings cold off-equatorial anomalies from the subsurface into the equatorial mixed layer through the meridional cells. Sensitivity experiments show that the climatological horizontal structure of the chlorophyll field in the upper layers is crucial to maintain the eastern Pacific warming. Concerning the variability, introducing an interactive biology slightly reduces the strength of the seasonal cycle, with stronger SST warming and chlorophyll concentrations during the upwelling season. In addition, ENSO amplitude is slightly increased. Similar experiments performed with another coupled general circulation model (IPSL-CM4) exhibit the same behaviour as in HadOPA, hence showing the robustness of the results.     

The Paris CM chondrite: Secondary minerals and asteroidal processing

We report a petrographic and mineralogical survey of Paris, a new CM chondrite considered to be the least‐altered CM identified so far (Hewins et al. 2014 ). Compared to other CMs, Paris exhibits (1) a higher concentration of Fe‐Ni metal beads, with nickel contents in the range 4.1–8.1 wt%; (2) the systematic presence of thin lamellae and tiny blebs of pentlandite in pyrrhotite grains; and (3) ubiquitous tochilinite/cronstedtite associations with higher FeO/SiO₂ and S/SiO₂ ratios. In addition, Paris shows the highest concentration of trapped ³⁶Ar reported so far for a CM chondrite (Hewins et al. 2014 ). In combination with the findings of previous studies, our data confirm the reliability of (1) the alteration sequence based on the chemical composition of tochilinite/cronstedtite associations to quantify the fluid alteration processes and (2) the use of Cr content variability in type II ferroan chondrule olivine as a proxy of thermal metamorphism. In contrast, the scales based on (1) the Fe³⁺ content of serpentine in the matrix to estimate the degree of aqueous alteration and (2) the chemical composition of Fe‐Ni metal beads for quantifying the intensity of the thermal metamorphism are not supported by the characteristics of Paris. It also appears that the amount of trapped ³⁶Ar is a sensitive indicator of the secondary alteration modifications experienced by chondrites, for both aqueous alteration and thermal metamorphism. Considering Paris, our data suggest that this chondrite should be classified as type 2.7 as it suffered limited but significant fluid alteration and only mild thermal metamorphism. These results point out that two separated scales should be used to quantify the degree of the respective role of aqueous alteration and thermal metamorphism in establishing the characteristics of CM chondrites.     

The Orgueil meteorite: 150 years of history

The goal of this paper is to summarize 150 yr of history of a very special meteorite. The Orgueil meteorite fell near Montauban in southwestern France on May 14, 1864. The bolide, which was the size of the full Moon, was seen across Western France, and almost immediately made the news in local and Parisian newspapers. Within a few weeks of the fall, a great diversity of analyses were performed under the authority of Gabriel Auguste Daubrée, geology professor at the Paris Museum, and published in the Comptes Rendus de l'Académie des Sciences. The skilled scientists reported the presence of iron sulfides, hydrated silicates, and carbonates in Orgueil. They also characterized ammonium salts which are now gone, and observed sulfates being remobilized at the surface of the stone. They identified the high water and carbon contents, and noted similarities with the Alais meteorite, which had fallen in 1806, 300 km away. While Daubrée and his colleagues noted the similarity of the Orgueil organic matter with some terrestrial humus, they were cautious not to make a direct link with living organisms. One century later, Nagy and Claus were less prudent and announced the discovery of “organized” elements in some samples of Orgueil. Their observations were quickly discredited by Edward Anders and others who also discovered that some pollen grains were intentionally placed into the rock back in the 1860s. Orgueil is now one of the most studied meteorites, indeed one of the most studied rocks of any kind. Not only does it contain a large diversity of carbon‐rich compounds, which help address the question of organo‐synthesis in the early solar system but its chemical composition is also close to that of the Sun's photosphere and serves as a cosmic reference. Secondary minerals, which make up 99% of the volume of Orgueil, were probably formed during hydrothermal alteration on the parent‐body within the first few million years of the solar system; their study is essential to our understanding of fluid–rock interaction in asteroids and comets. Finally, the Orgueil meteorite probably originated from a volatile‐rich “cometary” outer solar system body as indicated by its orbit. Because it bears strong similarities to other carbonaceous chondrites that originated on dark asteroids, this cometary connection supports the idea of a continuum between dark asteroids and comets.     

Description of a very dense meteorite collection area in western Atacama: Insight into the long‐term composition of the meteorite flux to Earth

We describe the geological, morphological, and climatic settings of two new meteorite collections from Atacama (Chile). The “El Médano collection” was recovered by systematic on‐foot search in El Médano and Caleta el Cobre dense collection areas and is composed of 213 meteorites before pairing, 142 after pairing. The “private collection” has been recovered by car by three private hunters and consists of 213 meteorites. Similar to other hot desert finds, and contrary to the falls and Antarctica finds, both collections show an overabundance of H chondrites. A recovery density can be calculated only for the El Médano collection and gives 251 and 168 meteorites larger than 10 g km^?2, before and after pairing, respectively. It is by far the densest collection area described in hot deserts. The Atacama Desert is known to have been hyperarid for a long period of time and, based on cosmic‐ray exposure ages on the order of 1–10 Ma, to have been stable over a period of time of several million years. Such a high meteorite concentration might be explained invoking either a yet unclear concentration mechanism (possibly related to downslope creeping) or a previously underestimated meteorite flux in previous studies or an average terrestrial age over 2 Myr. This last hypothesis is supported by the high weathering grade of meteorites and by the common terrestrial fragmentation (with fragments scattered over a few meters) of recovered meteorites.     

Reduced-order modeling for thermal recovery processes

Thermal recovery can entail considerably higher costs than conventional oil recovery, so the use of computational optimization techniques in designing and operating these processes may be beneficial. Optimization, however, requires many simulations, which results in substantial computational cost. Here, we implement a model-order reduction technique that aims at large reductions in computational requirements. The technique considered, trajectory piecewise linearization (TPWL), entails the representation of new solutions in terms of linearizations around previously simulated (and saved) training solutions. The linearized representation is projected into a low-dimensional space, with the projection matrix constructed through proper orthogonal decomposition of solution “snapshots” generated in the training step. Two idealized problems are considered here: primary production of oil driven by downhole heaters and a simplified model for steam-assisted gravity drainage, where water and steam are treated as a single “effective” phase. The strong temperature dependence of oil viscosity is included in both cases. TPWL results for these systems demonstrate that the method can provide accurate predictions relative to full-order reference solutions. Observed runtime speedups are very substantial, over 2 orders of magnitude for the cases considered. The overhead associated with TPWL model construction is equivalent to the computation time for several full-order simulations (the precise overhead depends on the number of training runs), so the method is only applicable if many simulations are to be performed.