Magnetic classification of stony meteorites: 2. Non‐ordinary chondrites

Abstract— A database of magnetic susceptibility (χ) measurements on different non‐ordinary chondrites (C, E, R, and ungrouped) populations is presented and compared to our previous similar work on ordinary chondrites. It provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and magnetite) in these meteorites. In contrast with all the other classes, CM and CV show a wide range of magnetic mineral content, with a two orders of magnitude variation of χ. Whether this is due to primary parent body differences, metamorphism or alteration, remains unclear. C3–4 and C2 yield similar χ values to the ones shown by CK and CM, respectively. By order of increasing χ, the classes with well‐grouped χ are: R << CO < CK ≈ CI < Kak < CR < E ≈ CH < CB. Based on magnetism, EH and EL classes have indistinguishable metal content. Outliers that we suggest may need to have their classifications reconsidered are Acfer 202 (CO), Elephant Moraine (EET) 96026 (C4–5), Meteorite Hills (MET) 01149, and Northwest Africa (NWA) 521 (CK), Asuka (A)‐88198, LaPaz Icefield (LAP) 031156, and Sahara 98248 (R). χ values can also be used to define affinities of ungrouped chondrites, and propose pairing, particularly in the case of CM and CV meteorites.     

Contrasting the termination of moderate and extreme El Niño events in coupled general circulation models

As in the observed record, the termination of El Niño in the coupled IPCC-AR4 climate models involves meridional processes tied to the seasonal cycle. These meridional processes both precondition the termination of El Niño events in general and lead to a peculiar termination of extreme El Niño events (such as those of 1982–83 and 1997–98), in which the eastern equatorial Pacific warm sea surface temperature anomalies (SSTA) persist well into boreal spring/early-summer. The mechanisms controlling the peculiar termination of extreme El Niño events, which involves to the development of an equatorially centred intertropical convergence zone, are consistent across the four models that exhibit extreme El Niños and observational record, suggesting that this peculiar termination represents a general feature of extreme El Niños. Further, due to their unusual termination, extreme El Niños exhibit an apparent eastward propagation of their SSTA, which can strongly influence estimates of the apparent propagation of ENSO over multi-decadal periods. Interpreting these propagation changes as evidence of changes in the underlying dynamical feedbacks behind El Niño could therefore be misleading, given the strong influence of a single extreme event.     

Prograde and retrograde fluid flow during contact metamorphism of siliceous carbonate rocks from the Ballachulish aureole,Scotland

 Siliceous dolomites and limestones contain abundant retrograde minerals produced by hydration-carbonation reactions as the aureole cooled. Marbles that contained periclase at the peak of metamorphism bear secondary brucite, dolomite, and serpentine; forsterite-dolomite marbles have retrograde tremolite and serpentine; wollastonite limestones contain secondary calcite and quartz; and wollastonite-free limestones have retrograde tremolite. Secondary tremolite never appears in marbles where brucite has replaced periclase or in wollastonite-bearing limestones. A model for infiltration of siliceous carbonates by CO₂-H₂O fluid that assumes (a) vertical upwardly-directed flow, (b) fluid flux proportional to cooling rate, and (c) flow and reaction under conditions of local equilibrium between peak temperatures and ≈400 °C, reproduces the modes of altered carbonate rocks, observed reaction textures, and the incompatibility between tremolite and brucite and between tremolite and wollastonite. Except for samples from a dolomite xenolith, retrograde time-integrated flux recorded by reaction progress is on the order of 1000 mol fluid/cm² rock. Local focusing of flow near the contact is indicated by samples from the xenolith that record values an order of magnitude greater. Formation of periclase, forsterite, and wollastonite at the peak of metamorphism also required infiltration with prograde time-integrated flux approximately 100–1000 mol/cm². The comparatively small values of prograde and retrograde time-integrated flux are consistent with lack of stable isotope alteration of the carbonates and with the success of conductive thermal models in reproducing peak metamorphic temperatures recorded by mineral equilibria. Although isobaric univariant assemblages are ubiquitous in the carbonates, most formed during retrograde metamorphism. Isobaric univariant assemblages observed in metacarbonates from contact aureoles may not record physical conditions at the peak of metamorphism as is commonly assumed. Received: 19 September 1995 / Accepted: 14 March 1996     

Experimental calibration of the partitioning of Fe and Mg between biotite and garnet

The cation exchange reaction Fe₃Al₂Si₃O₁₂ +KMg₃AlSi₃O₁₀(OH)₂ = Mg₃Al₂Si₃O₁₂+KFe₃-AlSi₃ O₁₀(OH)₂ has been investigated by determining the partitioning of Fe and Mg between synthetic garnet, (Fe, Mg)₃Al₂Si₃O₁₂, and synthetic biotite, K(Fe, Mg)₃AlSi₃O₁₀(OH)₂. Experimental results at 2.07 kbar and 550 °–800 ° C are consistent with In [(Mg/Fe) garnet/(Mg/Fe) biotite] = -2109/T(°K) +0.782. The preferred estimates for ¯H and ¯S of the exchange reaction are 12,454 cal and 4.662 e.u., respectively. Mixtures of garnet and biotite in which the ratio garnet/biotite=49/1 were used in the cation exchange experiments. Consequently the composition of garnet-biotite pairs could approach equilibrium values in the experiments with minimal change in garnet composition (few tenths of a mole percent). Equilibrium was demonstrated at each temperature by reversal of the exchange reaction. Numerical analysis of the experimental data yields a geothermometer for rocks containing biotite and garnet that are close to binary Fe-Mg compounds.     

Thermal radiative fluxes through inhomogeneous cloud fields: a sensitivity study using a new stochastic cloud generator

We analyze the effects of flat and bumpy top, fractional and internally inhomogeneous cloud layers on large area-averaged thermal radiative fluxes. Inhomogeneous clouds are generated by a new stochastic model: the tree-driven mass accumulation process (tdMAP). This model is able to provide stratocumulus and cumulus cloud fields with properties close to those observed in real clouds. A sensitivity study of cloud parameters is done by analyzing differences between 3D fluxes simulated by the spherical harmonic discrete ordinate method and three “standard” models likely to be used in general circulation models: plane-parallel homogeneous cloud model (PPH), PPH with fractional cloud coverage model (FCPPH) and independent pixel approximation model (IPA). We show that thermal fluxes are strong functions of fractional cloud coverage, mean optical depth, mean geometrical thickness and cloud base altitude. Fluctuations of “in-cloud” horizontal variability in optical depth and cloud-top bumps have negligible effects in the whole. We also showed that PPH, FCPPH and IPA models are not suitable to compute thermal fluxes of flat top fractional inhomogeneous cloud layer, except for completely overcast cloud. This implies that horizontal transport of photon at thermal wavelengths is important when cloudy cells are separated by optically thin regions.     

La plate-forme carbonatée oxfordienne de Lorraine : arguments pour une ouverture vers la mer Germanique

The study of sedimentary facies in the quarry of Dompcevrin (Middle Oxfordian) located northwestward of St-Mihiel (Meuse department) provides evidences of high-energy depositional conditions. The occurrence of beaches associated with hurricane coral breccias containing megaclasts is characteristic of platform edge environments. The open sea was located northeastward, in the direction of Germany, as it is indicated by the direction of progradation of beaches. It is concluded that the Oxfordian carbonate platform of Lorraine was opened to the northeast toward the Germanic Sea during the Middle Oxfordian. To cite this article: C. Carpentier et al., C. R. Geoscience 336 (2004).     

Formation and destruction of periclase by fluid flow in two contact aureoles

Periclase formed in steeply dipping marbles from the Beinn an Dubhaich aureole, Scotland, and the Silver Star aureole, Montana, by the reaction dolomite = periclase + calcite + CO₂. Equilibrium between rock and fluids with X _{CO 2} < 1 requires that reaction was infiltration-driven. Brucite pseudomorphs after periclase occur in the Beinn an Dubhaich aureole either as bed-by-bed replacement of dolomite or in a lens along the contact between dolomite and a pre-metamorphic dike. Transport theory predicts that infiltration drove both periclase reaction and ¹⁸O-depletion fronts which moved at significantly different velocities along the flow path. The distributions of brucite and ¹⁸O-depleted rocks are identical in surface exposures, thus indicating upward flow. Time-integrated flux (q) was <500 mol/cm² and the fluid source was magmatic. Because periclase and its hydrated equivalent brucite are unaltered to dolomite by retrograde reactions, the exposure of brucite marbles accurately images the flow paths of peak metamorphic fluids. In the Silver Star aureole brucite pseudomorphs after periclase exclusively occur in tabular bodies that are beds with elevated Mg/Ca. The spatial pattern of ¹⁸O-depletion requires upward vertical fluid flow. Estimated prograde q ≈ 10³–10⁴ mol/cm² and the fluid source was magmatic. Low Mg/Ca, ¹⁸O-depleted, brucite-free rocks pose a dilemma because the periclase reaction front should have traveled ≈18 times further through them than the isotope alteration front. The dilemma is resolved by reaction textures that indicate periclase and brucite were destroyed in low Mg/Ca rocks by infiltration-driven retrograde carbonation reactions. Values of retrograde q were ≈10³–10⁴ mol/cm². Brucite (after periclase) was preserved only in high Mg/Ca layers where periclase developed in greater abundance. The geometry of brucite marbles at Silver Star thus reflects the location of high Mg/Ca beds rather than the geometry of fluid flow. Retrograde reactions must be considered before the mineralogical record of prograde fluid flow can correctly be interpreted. In both aureoles fluid flow, mineral reaction, and isotope depletion were structurally controlled by bedding and lithologic contacts. Received: 30 July 1996 / Accepted: 21 March 1997     

Constraints on the thermodynamic mixing properties of plagioclase feldspars

Taking account of the Cˉ1/Iˉ1 (Al/Si order/disorder) transformation at high temperatures in the albite-anorthite solid solution leads to a simple model for the mixing properties of the high structural state plagioclase feldspars. The disordered (Cˉ1) solid solution can be treated as ideal (constant activity coefficient) and, for anorthite-rich compositions, deviations from ideality can be ascribed to cation ordering. Values of the activity coefficient for anorthite in the Cˉ1 solid solution (γ _An ^Cˉ1 ) are then controlled by the free energy difference between Cˉ1 and Iˉ1 anorthite at the temperature (T) of interest according to the relation: ΔˉG _ord ^Iˉ1 ⇌Cˉ1 =RT ln γ _An ^Cˉ1 . If the Iˉ1⇌Cˉ1 transformation in pure anorthite is treated, to a first approximation, as first order and the enthalpy and entropy of ordering are taken as 3.7±0.6 kcal/mole (extrapolated from calorimetric data) and 1.4–2.2 cal/mole (using an equilibrium order/disorder temperature for An₁₀₀ of 2,000–2,250 K), a crude estimate of γ _An ^Cˉ1 for all temperatures can be made. The activity coefficient of albite in the Cˉ1 solid solution (γ _Ab ^Cˉ1 ) can be taken as 1.0. The possible importance of this model lies in its identification of the principal constraints on the mixing properties rather than in the actual values of γ _An ^Cˉ1 and γ _Ab ^Cˉ1 obtained. In particular it is recognised that γ _An ^Cˉ1 depends critically on ordering in anorthite as well as, at lower temperatures, any ordering in the Cˉ1 solid solution. A brief review of activity-composition data, from published experiments involving ranges of plagioclase compositions and from the combined heats of mixing plus Al-avoidance entropy model (Newton et al. 1980), reveals some inconsistencies. The values of γ _An ^Cˉ1 calculated using the approach of Newton et al. (1980), although consistent with Orville's (1972) ion exchange data, are slightly lower than values derived from experiments by Windom and Boettcher (1976) and Goldsmith (1982) or from ion-exchange experiments of Kotel'nikov et al. (1981). Based on the Cˉ1/Iˉ1 transformation model, values of γ _An ^Cˉ1 <1.0 are unlikely. Discrepancies between the experimental data sets are attributed to incomplete (non-equilibrium) Al/Si order attained during the experiments. It is suggested that the choice of activity coefficients remains somewhat subjective. The development of accurate mixing models would be greatly assisted by better thermodynamic data for ordering in pure anorthite and by more thorough characterisation of the state of order in plagioclase crystals used for phase equilibrium experiments.     

Modelling the Mixing Function to Constrain Coseismic Hydrochemical Effects: An Example from the French Pyrénées

Groundwater coseismic transient anomalies are evidenced and characterized by modelling the mixing function F characteristic of the groundwater dynamics in the Ogeu (western French Pyrénées) seismic context. Investigations of water-rock interactions at Ogeu indicate that these mineral waters from sedimentary environments result from the mixing of deep waters with evaporitic signature with surficial karstic waters. A 3-year hydrochemical monitoring of Ogeu springwater evidences that using arbitrary thresholds constituted by the mean ± 1 or 2σ, as often performed in such studies, is not a suitable approach to characterize transient anomalies. Instead, we have used a mixing function F calculated with chemical elements, which display a conservative behavior not controlled by the precipitation of a mineral phase. F is processed with seismic energy release (E_s) and effective rainfalls (R). Linear impulse responses of F to E_s and R have been calculated. Rapid responses (10 days) to rainwater inputs are evidenced, consisting in the recharge of the shallow karstic reservoir by fresh water. Complex impulse response of F to microseismic activity is also evidenced. It consists in a 2-phase hydrologic signal, with an inflow of saline water in the shallow reservoir with a response delay of 10 days, followed by an inflow of karstic water with a response delay of 70 days, the amount being higher than the saline inflow. Such a process probably results from changes in volumetric strain with subsequent microfracturation transient episodes allowing short inflow of deep salted water in the aquifer. This study demonstrates that groundwater systems in such environments are unstable systems that are highly sensitive to both rainfall inputs and microseismic activity. Impulse responses calculation of F to E_s is shown to be a powerful tool to identify transient anomalies. Similar processing is suggested to be potentially efficient to detect precursors of earthquakes when long time-series (5 years at least) are available in areas with high seismicity.