A new velocity field from the analysis of the Egyptian Permanent GPS Network (EPGN)

For studying recent crustal movements and their relation to earthquake occurrence in large scales, the National Research Institute of Astronomy and Geophysics (NRIAG), Helwan, Cairo, Egypt started in 2006 the establishment of the Egyptian Permanent GPS Network (EPGN). Beginning with 4 stations in 2007, 15 stations were operational at the end of 2011. In addition, a station in Alexandria of the French “Centre d'Études Alexandrines” (CEALX) was added as station to the EPGN. Nowadays, 16 stations are operational and an extension to 20 in the near future is expected. The collected EPGN data of the last 6 years are used in this work to throw light upon the present state of recent crustal movement of the whole of Egypt. Bernese software V. 5.0 was used for processing the collected data according to the IGS standards. In addition, selected IGS, AFREF, and EPN sites are processed for reference frame definition. In this first comprehensive analysis of the permanent network, a complete and consistent evaluation resulted in the first estimates of present day horizontal velocities and coordinate time series.     

Nickel abundance in stony cosmic spherules: Constraining precursor material and formation mechanisms

Abstract– We report bulk and olivine compositions in 66 stony cosmic spherules (Na₂O < 0.76 wt%), 200–800 μm in size, from the Transantarctic Mountains, Antarctica. In porphyritic cosmic spherules, relict olivines that survived atmospheric entry heating are always Ni‐poor and similar in composition to the olivines in carbonaceous or unequilibrated ordinary chondrites (18 spherules), and equilibrated ordinary chondrites (one spherule). This is consistent with selective survival of high temperature, Mg‐rich olivines during atmospheric entry. Olivines that crystallized from the melts produced during atmospheric entry have NiO contents that increase with increasing NiO in the bulk spherule, and that range from values similar to those observed in chondritic olivines (NiO generally <0.5 wt%) to values characteristic of olivines in meteoritic ablation spheres (NiO > 2 wt%). Thus, NiO content in olivine cannot be used alone to distinguish meteoritic ablation spheres from cosmic spherules, and the volatile element contents have to be considered. We propose that the variation in NiO contents in cosmic spherules and their olivines is the result of variable content of Fe, Ni metal in the precursor. NiO contents in olivines and in cosmic spherules can thus be used to discuss their parent body. Ni‐poor spherules can be derived from C‐rich and/or metal‐poor precursors, either related to CM, CI, CR chondrites or to chondritic fragments dominated by silicates, regardless of the parent body. Ni‐rich spherules (NiO > 0.7 wt%) that represent 55% of the 47 barred‐olivine spherules we studied, were derived from the melting of C‐poor, metal‐rich precursors, compatible with ordinary chondrite or CO, CV, CK carbonaceous chondrite parentages.     

Lithium isotope geochemistry of marine pore waters - Insights from cold seep fluids

Lithium concentration and isotope data (δ⁷Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ⁷Li (δ⁷Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ⁷Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite-illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a⁻¹) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.     

Cretaceous reactivation and intensified erosion in the Archean–Proterozoic Limpopo Belt,demonstrated by apatite fission track thermochronology

Cratons are generally assumed to be regions of long-lasting tectonic stability. In particular the study of the Phanerozoic exhumation history of cratons has been largely hampered by the scarcity of suitable stratigraphic controls onshore. This fact is even more pronounced in terranes lacking Mesozoic or younger penetrative structural fabrics and metamorphic overprinting. Our study in the Limpopo belt shows that modern apatite fission track thermochronology provides a hitherto unavailable perspective in the study of these rocks, and has profound implications for the crustal evolution of the Zimbabwe Craton.Apatite fission track data from 35 samples taken along two transects, in the southern edge of the Zimbabwe Craton and in the Central Zone of the Limpopo Belt, suggest that extensive regions experienced kilometer-scale exhumation in two discrete events, as recently as the Cretaceous. The first occurred at around 130 Ma, and the second at around 90 Ma. Basin subsidence and sedimentation loads on the Mozambique margin support the timing of these events and provide strong indications of the source and pathways for the eroded material. Further, the results indicate that young and old “surfaces” (in a geomorphological sense) may be structurally juxtaposed in regions of high elevation in Zimbabwe. This is contrary to early ideas of surface chronologies based on summit accordances or invoking pediplanation.     

Sponges (Porifera) as living metazoan witnesses from the Neoproterozoic: biomineralization and the concept of their evolutionary success

The emergence of the Metazoa can be dated back to the Neoproterozoic Era which comprises the Cryogenian Period during which two major glaciations occurred, the Sturtian and the Varanger-Marinoan. At that time, the phylum Porifera (sponges) evolved as the first animals and developed a hard skeleton. The two classes of siliceous sponges, the Hexactinellida and the Demospongiae, are already provided with the major genetic repertoire and gene regulatory networks that also exist in modern multicellular animals. Besides these metazoan innovations, the siliceous sponges display one autapomorphic character, silicatein, an enzyme which mediates bio-silica formation. Well preserved siliceous sponge fossils have been excavated from the Cambrian Burgess Shale- and Chengjiang deposits. It is concluded that it was the hard skeleton of the siliceous sponges that contributed to the successful evolution and survival of the Porifera during the last 500 Ma.     

Molecular characterization of dissolved organic matter in pore water of continental shelf sediments

Dissolved organic matter (DOM) in sediment pore water is a complex molecular mixture reflecting various sources and biogeochemical processes. In order to constrain those sources and processes, molecular variations of pore water DOM in surface sediments from the NW Iberian shelf were analyzed by ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) and compared to river and marine water column DOM. Weighted average molecular element ratios of oxygen to carbon ((O/C)_wa) and hydrogen to carbon ((H/C)_wa) provided general information about DOM sources. DOM in local rivers was more oxygenated ((O/C)_wa 0.52) and contained less hydrogen ((H/C)_wa 1.15) than marine pore water DOM (mean (O/C)_wa 0.50, mean (H/C)_wa 1.26). The relative abundance of specific compound groups, such as highly oxygenated aromatic compounds or nitrogen-bearing compounds with low H/C ratios, correspond to a high concentration of lignin phenols (160 μg/g sediment dry weight) and a high TOC/TN ratio (13.3) in the sedimentary organic matter and were therefore assigned to terrestrial sources. The lower degree of unsaturation and a higher relative abundance of nitrogen-bearing compounds in the pore water DOM reflected microbial activity within the sediment. One sampling site on the shelf with a high sediment accumulation, and a humic-rich river sample showed a wide range of sulfur compounds in the DOM, accompanied by a higher abundance of lipid biomarkers for sulfate-reducing bacteria, probably indicating early diagenetic sulfurization of organic matter.     

Aggradation and carbonate accumulation of Holocene Norwegian cold‐water coral reefs

Cold‐water coral ecosystems present common carbonate factories along the Atlantic continental margins, where they can form large reef structures. There is increasing knowledge on their ecology, molecular genetics, environmental controls and threats available. However, information on their carbo‐nate production and accumulation is still very limited, even though this information is essential for their evaluation as carbonate sinks. The aim of this study is to provide high‐resolution reef aggradation and carbonate accumulation rates for Norwegian cold‐water coral reefs from various settings (sunds, inner shelf and shelf margin). Furthermore, it introduces a new approach for the evaluation of the cold‐water coral preservation within cold‐water coral deposits by computed tomography analysis. This approach allows the differentiation of various kinds of cold‐water coral deposits by their macrofossil clast size and orientation signature. The obtained results suggest that preservation of cold‐water coral frameworks in living position is favoured by high reef aggradation rates, while preservation of coral rubble prevails by moderate aggradation rates. A high degree of macrofossil fragmentation indicates condensed intervals or unconformities. The observed aggradation rates with up to 1500 cm kyr^?1 exhibit the highest rates from cold‐water coral reefs so far. Reef aggradation within the studied cores was restricted to the Early and Late Holocene. Available datings of Norwegian cold‐water corals support this age pattern for other fjords while, on the shelf, cold‐water coral ages are reported additionally from the early Middle Holocene. The obtained mean carbonate accumulation rates of up to 103 g cm^?2 kyr^?1 exceed previous estimates of cold‐water coral reefs by a factor of two to three and by almost one order of magnitude to adjacent sedimentary environments (shelf, slope and deep sea). Only fjord basins locally exhibit carbonate accumulation rates in the range of the cold‐water coral reefs. Furthermore, cold‐water coral reef carbonate accumulation rates are in the range of tropical reef carbonate accumulation rates. These results clearly suggest the importance of cold‐water coral reefs as local, maybe regional to global, carbonate sinks.     

Regional- and district-level drivers of timber harvesting in European Russia after the collapse of the Soviet Union

After the collapse of the Soviet Union, the forestry sector in Russia underwent substantial changes: the state forestry sector was decentralized, the timber industry was privatized, and timber use rights were allocated through short- and long-term leases. To date, there has been no quantitative assessment of the drivers of timber harvesting in European Russia following these changes. In this paper we estimate an econometric model of timber harvesting using remote sensing estimations of forest disturbance from 1990–2000 to 2000–2005 as our dependent variable. We aggregate forest disturbance to administrative districts – equivalent to counties in the United States – and test the impact of several biophysical and economic factors on timber harvesting. Additionally, we examine the impact that regions – equivalent to states in the United States and the main level of decentralized governance in Russia – have on timber harvesting by estimating the influence of regional-level effects on forest disturbance in our econometric model. Russian regions diverged considerably in political and economic conditions after the collapse of the Soviet Union, and the question is if these variations impacted timber harvesting after controlling for district-level biophysical and economic drivers. We find that the most important drivers of timber harvesting at the district level are road density, the percent of evergreen forest, and the total area of forest. The influence of these variables on timber harvesting changed over time and there was more harvesting closer to urban areas in 2000–2005. Even though district-level variables explain more than 70 percent of the variation in forest disturbance in our econometric model, we find that regional-level effects remain statistically significant. While we cannot identify the exact mechanism through which regional-level effects impact timber harvesting, our results suggest that sub-national differences can have a large and statistically significant impact on land-use outcomes and should be considered in policy design and evaluation.     

An Attempt to Close the Daytime Surface Energy Balance Using Spatially-Averaged Flux Measurements

Single-tower eddy-covariance measurements represent the complete surface flux of a scalar only under idealized conditions. Therefore, we often find an underestimation of energy fluxes expressed as a lack of energy balance closure at many sites. In this study, a multi-tower approach to measure atmospheric energy fluxes based on spatial averaging is evaluated and possible mechanisms causing a lack of energy balance closure are analysed, focussing on daytime data only. It is shown that the multi-tower technique is also unable to measure the entire flux for our site, likely because the assumption of horizontal homogeneity is violated. Heterogeneity-induced and buoyancy-driven quasi-stationary circulations are probably the dominant processes causing the underestimation of energy fluxes. A dependence of the energy balance residual on stability is found, with residuals close to zero for stable stratification, a maximum under unstable to near-neutral conditions and still relatively large residuals for stronger instability. Assuming the processes transporting energy and CO₂ are similar, the implications on long-term CO₂ flux measurements are analysed. Accordingly, the resulting selective systematic error of cumulative net ecosystem exchange estimates for agricultural regions such as ours can be of the order of more than 100%, since mainly the fluxes during periods of net CO₂ uptake are underestimated while periods of net CO₂ release are much less affected by this bias. Further investigations about this issue are highly warranted.