Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

A Machine Learning Approach for Improving the Detection Capabilities at 3C Seismic Stations

We apply and evaluate a recent machine learning method for the automatic classification of seismic waveforms. The method relies on Dynamic Bayesian Networks (DBN) and supervised learning to improve the detection capabilities at 3C seismic stations. A time-frequency decomposition provides the basis for the required signal characteristics we need in order to derive the features defining typical “signal” and “noise” patterns. Each pattern class is modeled by a DBN, specifying the interrelationships of the derived features in the time-frequency plane. Subsequently, the models are trained using previously labeled segments of seismic data. The DBN models can now be compared against in order to determine the likelihood of new incoming seismic waveform segments to be either signal or noise. As the noise characteristics of seismic stations varies smoothly in time (seasonal variation as well as anthropogenic influence), we accommodate in our approach for a continuous adaptation of the DBN model that is associated with the noise class. Given the difficulty for obtaining a golden standard for real data (ground truth) the proof of concept and evaluation is shown by conducting experiments based on 3C seismic data from the International Monitoring Stations, BOSA and LPAZ.     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

Hydrological modelling for assessing spatio-temporal groundwater recharge variations in the water-stressed Amathole Water Supply System,Eastern Cape,South Africa

To increase the resilience of regional water supply systems in South Africa in the face of anticipated climatic changes and a constant increase in water demand, water supply sources require diversification. Many water-stressed metropolitan regions in South Africa depend largely on surface water to cover their water demand. While climatic and river discharge data is widely available in these regions, information on groundwater resources – which could support supply source diversification – is scarce. Groundwater recharge is a key parameter that is used to estimate groundwater amounts that can be sustainably exploited at a sub-watershed level. Therefore, the objective of this study was to develop a reliable hydrological modelling routine that enables the assessment of regional spatio-temporal variations of groundwater recharge to discern the most promising areas for groundwater development. Accordingly, we present a semi-distributed hydrological modelling approach that incorporates water balance routines coupled with baseflow modelling techniques to yield spatio-temporal variations of groundwater recharge on a regional level. The approach is demonstrated for the actively managed catchment areas of the Amathole Water Supply System situated in a semi-arid part of the Eastern Cape of South Africa. In the investigated study area, annual groundwater recharge exhibits a high spatio-temporal heterogeneity and is estimated to vary between ~0.5% and 8% of annual rainfall. Despite some uncertainties induced by limited data availability, calibration and validation of the model were found to be satisfactory and yielded model results similar to (point) data of annual groundwater recharge reported in earlier studies. Our approach is therefore found to derive crucial information for efficiently targeting more detailed groundwater exploration studies and could work as a blueprint for orientating groundwater potential exploration in similar environments.     

A GIS-based glacier inventory for the Antarctic Peninsula and the South Shetland Islands —A first case study on King George Island

The aim of the international project “Global Land Ice Measurements from Space (GLIMS)” headed by the US Geological Survey is to establish a world wide glacier inventory based on satellite imagery. This data set will form a first digital baseline study for future glacier monitoring. The presented GIS-based glacier inventory for King George Island is a case study for the area of the Antarctic Peninsula. In the database of the glacier inventory topographic information, specific glaciological parameters as well as metadata will be included. The topographic data consists of drainage basin limits, basin areas, altitudinal ranges, perimeters and mean lengths. Glaciological data sets should comprise information on glacier retreat in different periods, glacier velocities, ice thickness and bedrock topography as well as derived parameters. Modelled and measured mass balance parameters could be included as additional data layers. In particular, these metadata records must comprise background information on data accuracy and data sources and should be compatible with a future data model for the King George Island GIS (KGIS). Three examples illustrate that the GLIMS database will not only contain information valuable for glaciological applications, but also other environmental studies on the island will benefit from this standardised remote sensing data sets. Therefore, a very close link between the data models of KGIS and GLIMS has to be established to enable these synergisms. Finally, better access to historic aerial photography would enable a continuous record of glacier retreat from the beginning of the 1950's onward.     

Quantificational reductionism as a risk in geography and cartography

A reductionistic concept is being pursued in the 125 000 geomorphological mapping of the Federal Republic of Germany. Complex landscape elements with a base length greater than 100 m are broken down into partial elements and re-interpreted in terms of quantificational or abstractly defined, theoretically neutral map symbols. The genetic aspect is expressed by areal colouring. In this way it aims to achieve an interdisciplinary utilization of such information. This reduction has proved to be too drastic insofar as it gives rise to irretrievable loss of information. The claim that use-oriented, ecologically relevant information would be derivable from the GMM-25 has not been substantiated. As ecologically justifiable evaluation must also consider as its most fundamental indicators the quality and distribution of biotopes. These are not even rudimentarily included in the GMM-25. The uncontextualized blending of information units which only make sense in heterogeneous contexts to produce a single map is antithetical to the principle of subject related selection of relevant characteristics and prevents comprehension of the systematic relationships.The underlying concept of the GMM-25, derived from an uncritical incorporation of physico-mathematical total predictability principles, leads to an irreversible renunciation of the necessarily complex constituents of a high geomorphological level of integration.     

Processing and quality control of flux data during LITFASS-2003

Different aspects of the quality assurance and quality control (QA/QC) of micrometeorological measurements were combined to create a comprehensive algorithm which was then applied to experimental data from LITFASS-2003 (Lindenberg Inhomogeneous Terrain—Fluxes between Atmosphere and Surface: a long term Study). Eddy-covariance measurements of the latent heat flux were the main focus of the QA/QC efforts. The results of a turbulence sensor intercomparison experiment showed deviations between the different eddy-covariance systems on the order of 15%, or less than 30 W m⁻², for the latent heat flux and 5%, or less than 10 W m⁻², for the sensible heat flux. In order to avoid uncertainties due to the post-processing of turbulence data, a comprehensive software package was used for the analysis of experimental data from LITFASS-2003, including all necessary procedures for corrections and quality control. An overview of the quality test results shows that for most of the days more than 80% of the available latent heat flux data are of high quality so long as there are no instrumental problems. The representativeness of a flux value for the target land-use type was analysed using a stochastic footprint model. Different methods to calculate soil heat fluxes at the surface are discussed and a sensitivity analysis is conducted to select the most robust method for LITFASS-2003. The lack of energy balance closure, which was found for LITFASS-2003, can probably be attributed to the presence of low-frequency flux contributions that cannot be resolved with an averaging time of 30 min. Though the QA/QC system has been developed for the requirements of LITFASS-2003, it can also be applied to other experiments dealing with similar objectives.     

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.     

Pleistocene/Holocene climate change, re-establishment of fluvial drainage network and increase in relief in the Swiss Alps

ABSTRACT Data are presented about modern sediment discharge of the Swiss rivers and related to the size of catchments. The information reveals that the Central Alps have experienced denudation rates of ≈0.15 mm yr⁻¹ in the foreland, and ≈0.5 mm yr⁻¹ in the Alpine core. Mapping, however, indicates that modern erosion only affects 30–50% of the Alpine surface, and that fluvial and associated hillslope processes have focused erosion in 50–200-m-deep valleys. These valleys are incised into the glacial surface. If this limited spatial extent of erosion is considered, then effective erosion rates are significantly higher than average denudation rates. These effective rates equal or locally exceed modern rates of rock uplift. This implies that the modification of erosional processes related to the Pleistocene/Holocene climate change has resulted in an increase in the relief at a local scale. At a drainage basin scale, however, the relief appears not to change at present.