The role of urbanization in the flooding and surface water chemistry of Puerto Rico’s mangroves

ABSTRACT

In this study, water level models are constructed to characterize mangrove flooding across urban gradients in Puerto Rico. The most urban sites exhibited 95% longer hydroperiods, 23% lower flood frequencies, and 110% lower depths than the least urban sites. Rainfall importance was explained more by geomorphology and tidal connectivity than by urbanization, but there was evidence for changes in tidal amplitudes along the urban gradient. Relationships between surface water chemical metrics and land cover contradicted previous studies by suggesting lower nutrients and biochemical oxygen demand with increasing urbanization. However, much of this changed with the exclusion of potential outlier sites, as well as under different statistical comparisons. These results reinforce the understanding that the most important drivers of urban mangrove hydrology and water quality in Puerto Rico are likely geomorphology and tidal connectivity, with some influence from surrounding land cover. Results should be considered alongside the reported errors stemming from digital elevation and rainfall response models.     

Verwitterung und Bodenbildung auf diluvialen Schotterterrassen

Ohne Zusammenfassung     

Does recent global warming suggest an enhanced greenhouse effect?

Considerable controversy has been generated by the observation that the Earth's climate has warmed over the last century. Public policy decisions hinge on the question of whether this trend is natural climate variability or the result of the increase in atmospheric concentrations of greenhouse gases. The strength of the enhanced greenhouse effect depends, in large part, on the uncertain value of climate sensitivity. In this paper climate sensitivity is estimated from the global temperature record by assuming models for greenhouse forcing, climate response to forcing, and climate variability. We find optimal estimates of climate sensitivity are remarkably insensitive to assumptions, at least for forcing excluding the effect of aerosols, and these values are considerably less than most predictions arising from General Circulation Models (GCM's). It is, however, the statistical significance of these estimates that is sensitive to assumptions about climate variability. Assuming climate variability with a time scale of a decade or less, climate sensitivity is estimated to be significantly greater than zero, but also significantly lower than that predicted by GCM's. Climate variability with a century time scale is consistent with both the recent temperature record and the pre-instrumental record for the last millenium; if this type of variability is assumed, the estimate of climate sensitivity has a confidence band wide enough to encompass both zero and typical values obtained by GCM's. With century time-scale variability it will be several decades before confident estimates can be made.     

A Continuous Conversion Technology from Top Coal Caving into Multi-Slice Mining for Thick Bifurcated Coal Seams

Geotechnical and Geological Engineering - This paper presents a mining technology that enables the continuous conversion from top coal caving (TCC) to multi-slice mining (MSM). The technology helps...     

A Synthetic Haematite Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Application to Iron Oxide‐Cu‐Au Systems

In both nature and synthetic experiments, the common iron oxide haematite (α‐Fe₂O₃) can incorporate significant amounts of U into its crystal structure and retain radiogenic Pb over geological time. Haematite is a ubiquitous component of many ore deposit types and, therefore, represents a valuable hydrothermal mineral geochronometer, allowing direct constraints to be placed on the timing of ore formation and upgrading. However, to date, no suitable natural haematite reference material has been identified. Here, a synthetic haematite U‐Pb reference material (MR‐HFO) is characterised using LA‐ICP‐MS and ID‐TIMS. Centimetre‐scale ‘chips’ of synthesised α‐Fe₂O₃ were randomly microsampled via laser ablation‐extraction and analysed using ID‐TIMS. Reproducible U/Pb and Pb/Pb measurements were obtained across four separate chips (n = 13). Subsequently, an evaluation of the suitability MR‐HFO in constraining U‐Pb data via LA‐ICP‐MS is presented using a selection of natural samples ranging from Cenozoic to Proterozoic in age. The MR‐HFO normalised U‐Pb ratios are more concordant and ages more accurate versus the same LA‐ICP‐MS spot analyses normalised to zircon reference material, when compared with independently acquired ID‐TIMS data from the same natural haematite grains. Results establish MR‐HFO as a suitable reference material for LA‐ICP‐MS haematite U‐Pb geochronology.     

Stress-driven Melt Segregation and Strain Partitioning in Partially Molten Rocks: Effects of Stress and Strain

The evolution of melt segregation in deforming partially moltenolivine-rich rocks has been studied in a series of laboratoryexperiments. During deformation, melt segregates into networksof anastamosing channels (or ‘bands’) surroundinglenses of melt-depleted material. We quantify the nature ofthe melt distribution in the samples, including thickness, angle,spacing, volume fraction, and melt fraction of melt-rich bands,to understand the dynamics of melt-network organization. Twoseries of experiments were designed to isolate the effects of(1) increasing shear strain (at similar stress levels), and(2) varying stress levels (deformed to similar shear strains).Melt-rich bands develop by a shear strain of unity. In samplesdeformed at varying stress levels, higher stress produces smallercharacteristic band spacings. We relate these variations tothe compaction length, _c, which varies only as a result of thereduction of matrix viscosity with increasing stress. Simpleapproaches to scaling from experimental to mantle conditionssuggest that stress-driven melt segregation can occur in theasthenosphere; if so, it will significantly affect rheological,transport and seismic properties, with enticing consequencesfor our understanding of plate–mantle interactions. KEY WORDS: melt segregation; rock rheology; magma transport; self-organization; mid-ocean ridges     

Crystallization and Breakdown of Metasomatic Phases in Graphite-bearing Peridotite Xenoliths from Marsabit (Kenya)

Mantle-derived xenoliths from the Marsabit shield volcano (easternflank of the Kenya rift) include porphyroclastic spinel peridotitescharacterized by variable styles of metasomatism. The petrographyof the xenoliths indicates a transition from primary clinopyroxene-bearingcryptically metasomatized harzburgite (light rare earth element,U, and Th enrichment in clinopyroxene) to modally metasomatizedclinopyroxene-free harzburgite and dunite. The metasomatic phasesinclude amphibole (low-Ti Mg-katophorite), Na-rich phlogopite,apatite, graphite and metasomatic low-Al orthopyroxene. Transitionalsamples show that metasomatism led to replacement of clinopyroxeneby amphibole. In all modally metasomatized xenoliths melt pockets(silicate glass containing silicate and oxide micro-phenocrysts,carbonates and empty vugs) occur in close textural relationshipwith the earlier metasomatic phases. The petrography, majorand trace element data, together with constraints from thermobarometryand fO₂ calculations, indicate that the cryptic and modal metasomatismare the result of a single event of interaction between peridotiteand an orthopyroxene-saturated volatile-rich silicate melt.The unusual style of metasomatism (composition of amphibole,presence of graphite, formation of orthopyroxene) reflects lowP –T conditions (850–1000°C at < 1·5GPa) in the wall-rocks during impregnation and locally low oxygenfugacities. The latter allowed the precipitation of graphitefrom CO₂. The inferred melt was possibly derived from alkalinebasic melts by melt–rock reaction during the developmentof the Tertiary–Quaternary Kenya rift. Glass-bearing meltpockets formed at the expense of the early phases, mainly throughincongruent melting of amphibole and orthopyroxene, triggeredby infiltration of a CO₂-rich fluid and heating related to themagmatic activity that ultimately sampled and transported thexenoliths to the surface. KEY WORDS: graphite; peridotite xenoliths; Kenya Rift; modal metasomatism; silicate glass