Content and distribution of trace metals in surface sediments from the northern Bering Sea, Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Geochemical evidence for abrupt changes in relative strength of the Arabian monsoons during a stadial/interstadial climate transition

The occurrence and propagation of abrupt climate change between the high and low-latitudes has become an important focus of paleoclimatic and paleoceanographic research. The causes of abrupt change have significant implications for understanding future manifestations of similar forcings under late Holocene (‘Anthropocene’) boundary conditions. Of particular interest are signals indicative of sub-millennial scale climate change in the sub-tropics of similar magnitude and frequency to those recorded in Greenland ice cores. Earlier research in the Arabian Sea has highlighted the sensitivity of sedimentary organic carbon and nitrogen isotope measurements for recording the state of the SW monsoon and associated Arabian Sea Oxygen Minimum Zone. In this study, we exploit the unprecedented fidelity of the sedimentary δ¹⁵N record to identify a 20 cm interval at ODP Site 723 containing a stadial/inter-stadial interval between 43-42 Kyr BP. We employ sedimentary nitrogen isotopes, chlorin pigment and alkenone abundances, major and minor element analyses of highly-resolved (2 mm ≈ 10 yr) samples across this interval to compare a comprehensive, multi-proxy data set to understand (a) the processes contributing to the δ¹⁵N signal in the longer records of denitrification; and (b) the associated climatic events, especially the relative intensity of summer and winter monsoons at these times. A lack of evidence for bioturbation in excess of our 2 mm sampling resolution facilitates decadal-scale oceanographic and climatic reconstructions. Using a four-component flux-dilution model, we show that the deposition of carbonate decreased in parallel with an increase in Total Organic Matter flux from stadial to inter-stadial time. This interval is also marked by a significant drop in lithogenic (dust) accumulation, analogous to a similar decrease noted during deglaciation in the Western Arabian Sea. Combined with alkenone U₃₇^K′-derived estimates for sea surface temperature (SST), we conclude that the climatological shift from stadial to inter-stadial conditions at low latitudes was characterized by repeated switches in mean monsoon state approximately every 200 yr. The winter monsoon was the dominant mode during maximum stadial conditions; conversely the summer monsoon was dominant during maximum interstadial-like conditions. However, each interval was separated by a distinct ‘inter-monsoon’ mode, indicated by a higher continental dust flux but warmer SST. Proxy records for changing bottom-water oxygenation show near-identical results down to the mm-scale, but hint at increased export production leading the onset of anoxia during the stadial/inter-stadial transition. The coherence of all sedimentary signals depicts a wholesale reorganization of the Arabian Sea climate and marine ecosystem over approximately 200 years, a period that may be associated with monsoon modulation by small oscillations in solar irradiance.     

Distribution and speciation of mercury in surficial sediments from main mangrove wetlands in China

The purpose of this study was to establish the distribution, speciation and bioavailability of mercury in mangrove sediments. A systemic survey of surficial sediments from 13 mangrove wetlands of China was carried out. Hg concentrations ranged from 2.3–903.6 ng g⁻¹, with an average value of 189.4 ng g⁻¹. Of the 13 areas surveyed, the Hg content in sediments was similar to background levels in 6 areas but was much higher in the other seven areas. Hg levels were affected by natural and anthropogenic factors, including terrestrial pollutants, geomorphic properties, and indirectly by economic status. Hg levels were positively correlated with organic matter, pH, and silt and clay fractions, but Hg was negatively correlated with sand fraction. In most mangrove wetlands, Hg existed primarily in the form of volatile Hg. Hg is easily bioaccumulated in mangrove wetlands and may be the natural source of Hg emissions to the atmosphere.