Pleistocene recycling of copper at a porphyry system,Atacama Desert,Chile: Cu isotope evidence

We present Cu isotope data of hypogene and supergene minerals from the Late Paleocene Spence Cu-Mo porphyry in the Atacama Desert of northern Chile. Chalcopyrite displays a restricted range of δ⁶⁵Cu values within the values reported for primary porphyry Cu sulfides (+ 0.28‰ to + 0.34‰, n = 6). Supergene chalcocite samples show heavier and remarkably homogeneous δ⁶⁵Cu values, between + 3.91‰ and + 3.95‰ (n = 6), consistent with previous models of Cu leaching and enrichment in porphyry systems. Secondary Cu minerals from the oxide zone show a wider range of composition, varying from + 1.28‰ and + 1.37‰ for chrysocolla (n = 6) to very light Cu isotope signatures reported for atacamite between -5.72‰ to -6.77‰ (n = 17). These data suggest redox cycling of Cu during supergene enrichment of the Spence Cu deposit, characterized by a first stage of supergene chalcocite formation from acidic, isotopically-heavy leach fluids of meteoric origin down-flowing in a semi-arid climate (44 to ~ 15-9 Ma). Reworking of the initial supergene copper assemblage, during the Pleistocene, by rising neutral and chlorine-rich deep formation waters under well-established hyper-arid climate conditions lead to the formation of atacamite with extremely fractionated Cu compositions. Essentially coeval chrysocolla formed by dissolution of atacamite during short episodes of wetter climatic conditions occurring in the latest Pleistocene.     

Thallium isotopes in early diagenetic pyrite - A paleoredox proxy?

This paper presents the first study of Tl isotopes in early diagenetic pyrite. Measurements from two sections deposited during the Toarcian Ocean Anoxic Event (T-OAE, ∼183 Ma) are compared with data from Late Neogene (<10 Ma) pyrite samples from ODP legs 165 and 167 that were deposited in relatively oxic marine environments. The Tl isotope compositions of Late Neogene pyrites are all significantly heavier than seawater, which most likely indicates that Tl in diagenetic pyrite is partially sourced from ferromanganese oxy-hydroxides that are known to display relatively heavy Tl isotope signatures. One of the T-OAE sections from Peniche in Portugal displays pyrite thallium isotope compositions indistinguishable from Late Neogene samples, whereas samples from Yorkshire in the UK are depleted in the heavy isotope of Tl. These lighter compositions are best explained by the lack of ferromanganese precipitation at the sediment-water interface due to the sulfidic (euxinic) conditions thought to be prevalent in the Cleveland Basin where the Yorkshire section was deposited. The heavier signatures in the Peniche samples appear to result from an oxic water column that enabled precipitation of ferromanganese oxy-hydroxides at the sediment-water interface.The Tl isotope profile from Yorkshire is also compared with previously published molybdenum isotope ratios determined on the same sedimentary succession. There is a suggestion of an anti-correlation between these two isotope systems, which is consistent with the expected isotope shifts that occur in seawater when marine oxic (ferromanganese minerals) fluxes fluctuate.The results outlined here represent the first evidence that Tl isotopes in early diagenetic pyrite have potential to reveal variations in past ocean oxygenation on a local scale and potentially also for global oceans. However, much more information about Tl isotopes in different marine environments, especially in anoxic/euxinic basins, is needed before Tl isotopes can be confidently utilized as a paleo-redox tracer.     

BeppoSAX observations of GRS 1915+105

The galactic superluminal source GRS 1915+105 was observed byBeppoSAX at several occasions from October 1996 to April 2000. In April 1999 the 2–10 keV light curve showed a long series of quasi regular pulses with a recurrence time of about 50 s. Some preliminary results of a spectral analysis are presented.     

X-ray Spectroscopy of the Scattered Emission in NGC 1068

We discuss the iron K line complex in NGC 1068. The line complex basically consists of three components, as previously reported. A new analysis of the ASCA data shows that cold reflection appears to dominate the observed X-ray emission above 4 keV based on the detection of ‘Compton shoulder’, a weak red wing of the 6.4 keV fluorescence iron K line, and a very flat continuum. The other two weaker lines at higher energies can be identified with FeXXV and FeXXVI and suggest an highly ionized X-ray mirror as well, although the line energies are systematically lower than those expected from the resonant lines, consistent with a redshift by 1.5%. This revised version was published online in July 2006 with corrections to the Cover Date.     

UVES Abundances of Stars in Nearby Dwarf Spheroidal Galaxies

It is a truth universally acknowledged, that a galaxy in possession of a good quantity of gas must want to form stars. It is the details of how and why that baffle us all. The simplest theories either would have this process a carefully self-regulated affair, or one that goes completely out of control and is capable of wrecking the galaxy which hosts it. Of course the majority of galaxies seem to amble along somewhere between these two extremes, and the mean properties tend to favour a quiescent self-regulated evolutionary scenario. But there area variety of observations which require us to invoke transitory ‘bursts’ of star-formation at one time or another in most galaxy types. Several nearby dwarf spheroidal galaxies have clearly determined star-formation histories with apparent periods of zero star formation followed by periods of fairly active star formation. If we are able to understand what separated these bursts we would understand several important phenomena in galaxy evolution. Were these galaxies able to clear out their gas reservoir in a burst of star formation? How did this gas return? or did it? Have these galaxies receieved gas from the IGM instead? Could stars from these types of galaxy contribute significantly to the halo population in our Galaxy? To answer these questions we need to combine accurate stellar photometry and Colour-Magnitude Diagram interpretation with detailed metal abundances to combine a star-formation rate versus time with a range of element abundances with time. Different elements trace different evolutionary process (e.g., relative contributions of type I and II supernovae). We often aren't even sure of the abundance spread in these galaxies. We have collected detailed high resolution UVES spectra of four nearby dwarf spheroidal galaxies (Sculptor, Fornax, Leo I &; Carina) to begin to answer these questions. This is a precursor study to a more complete study with FLAMES. We presented at this meeting the initial results for the Sculptor and Fornax dwarf spheroidal galaxies which have been previously had single element (low resolution) calcium abundance studies (Tolstoy et al., 2001). See Figures 1 and 2.     

The iron Kα Compton shoulder in transmitted and reflected spectra

We calculate the equivalent width of the core, and the centroid energy and relative flux of the first-order Compton shoulder of the iron Kα emission line from neutral matter. The calculations are performed with Monte Carlo simulations. We explore a large range of column densities for both transmitted and reflected spectra, and study the dependence on the iron abundance. The Compton shoulder is now becoming observable in many objects thanks to the improved sensitivity and/or energy resolution of the XMM – Newton and Chandra satellites, and the present work aims to provide a tool to derive information on the geometry and element abundances of the line-emitting matter from Compton shoulder measurements.     

Database of giant landslides on volcanic islands—first results from the Atlantic Ocean

Giant landslides on volcanic islands represent the largest formations which can be created in a single geological moment. Such landslides are distributed across the globe and have attracted a significant amount of research interest. Yet, no coherent attempts have been made to rationalise this information into a single online resource. This report summarises information about the structure of the recently created database of giant landslides on volcanic islands and presents some observations regarding the uncertainties inherent in the inventories. The database is being prepared over a 3-year period: the first year of the project has focused on rationalising information about giant landslides around the Atlantic Ocean while the second and third years will focus on rationalising information about such landslides from the Pacific Ocean and Indian Ocean, respectively. Using this database, it should be possible to interrogate the spatial and temporal patterns of land sliding and landslide reactivation as well as to better assess the hazard and potential risks posed by giant landslides on volcanic islands. It will be particularly interesting to see if any evidence can be found for global triggers, such as eustatic or climatic changes, instead of the more commonly expounded local triggers. Ultimately, it is hoped that the database will benefit both the geoscientific community and those agencies responsible for civil defence. This work is part of the activities of the International Consortium on Landslides, namely its International Programme on Landslides (Project n. 212). The database is available from the giant landslides project webpage: https://www.irsm.cas.cz/ext/giantlandslides.     

Saturn’s F ring grains: Aggregates made of crystalline water ice

We present models of the near-infrared (1-5 μm) spectra of Saturn’s F ring obtained by Cassini’s Visual and Infrared Mapping Spectrometer (VIMS) at ultra-high phase angles (177.4-178.5°). Modeling this spectrum constrains the size distribution, composition, and structure of F ring particles in the 0.1-100 μm size range. These spectra are very different from those obtained at lower phase angles; they lack the familiar 1.5 and 2 μm absorption bands, and the expected 3 μm water ice primary absorption appears as an unusually narrow dip at 2.87 μm. We have modeled these data using multiple approaches. First, we use a simple Mie scattering model to constrain the size distribution and composition of the particles. The Mie model allows us to understand the overall shapes of the spectra in terms of dominance by diffraction at these ultra-high phase angles, and also to demonstrate that the 2.87 μm dip is associated with the Christiansen frequency of water ice (where the real refractive index passes unity). Second, we use a combination of Mie scattering with Effective Medium Theory to probe the effect of porous (but structureless) particles on the overall shape of the spectrum and depth of the 2.87 μm band. Such simple models are not able to capture the shape of this absorption feature well. Finally, we model each particle as an aggregate of discrete monomers, using the Discrete Dipole Approximation (DDA) model, and find a better fit for the depth of the 2.87 μm feature. The DDA models imply a slightly different overall size distribution. We present a simple heuristic model which explains the differences between the Mie and DDA model results. We conclude that the F ring contains aggregate particles with a size distribution that is distinctly narrower than a typical power law, and that the particles are predominantly crystalline water ice.     

Three‐dimensional architecture and hydrostratigraphy of cross‐cutting buried valleys using airborne electromagnetics,glaciated Central Lowlands,Nebraska, USA

Buried valleys are characteristic features of glaciated landscapes, and their deposits host important aquifers worldwide. Understanding the stratigraphic architecture of these deposits is essential for protecting groundwater and interpreting sedimentary processes in subglacial and ice‐marginal environments. The relationships between depositional architecture, topography and hydrostratigraphy in dissected, pre‐Illinoian till sheets is poorly understood. Boreholes alone are inadequate to characterize the complex geology of buried valleys, but airborne electromagnetic surveys have proven useful for this purpose. A key question is whether the sedimentary architecture of buried valleys can be interpreted from airborne electromagnetic profiles. This study employs airborne electromagnetic resistivity profiles to interpret the three‐dimensional sedimentary architecture of cross‐cutting buried valleys in a ca 400 km² area along the western margin of Laurentide glaciation in North America. A progenitor bedrock valley is succeeded by at least five generations of tunnel valleys that become progressively younger northward. Tunnel‐valley infills are highly variable, reflecting under‐filled and over‐filled conditions. Under‐filled tunnel valleys are expressed on the modern landscape and contain fine sediments that act as hydraulic barriers. Over‐filled tunnel valleys are not recognized in the modern landscape, but where they are present they form hydraulic windows between deep aquifer units and the land surface. The interpretation of tunnel‐valley genesis herein provides evidence of the relationships between depositional processes and glacial landforms in a dissected, pre‐Illinoian till sheet, and contributes to the understanding of the complex physical hydrology of glacial aquifers in general.