The Horizontal Reactive Media Treatment Well (HRX Well®) for Passive In‐Situ Remediation

A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well.     

A Review of Higher Order Ionospheric Refraction Effects on Dual Frequency GPS

Higher order ionospheric effects are increasingly relevant as precision requirements on GPS data and products increase. The refractive index of the ionosphere is affected by its electron content and the magnetic field of the Earth, so the carrier phase of the GPS L1 and L2 signals is advanced and the modulated code delayed. Due to system design the polarisation is unaffected. Most of the effect is removed by expanding the refractive index as a series and eliminating the first term with a linear combination of the two signals. However, the higher order terms remain. Furthermore, transiting gradients in refractive index at a non-perpendicular angle causes signal bending. In addition to the initial geometric bending term, another term allows for the difference that the curvature makes in electron content along each signal. Varying approximations have been made for practical implementation, mainly to avoid the need for a vertical profile of electron density. The magnetic field may be modelled as a tilted co-centric dipole, or using more realistic models such as the International Geomagnetic Reference Field. The largest effect is from the second term in the expansion of the refractive index. Up to several cm on L2, it particularly affects z-translation, and satellite orbits and clocks in a global network of GPS stations. The third term is at the level of the errors in modelling the second order term, while the bending terms appear to be absorbed by tropospheric parameters. Modelling improvements are possible, and three frequency transmissions will allow new possibilities.     

Temporal and life history related trends of perfluorochemicals in harbor porpoises from the Danish North Sea

Eighty-five stranded or bycaught harbor porpoises collected from the Danish North Sea between 1980 and 2005 were analyzed for perfluorochemicals in the liver. PFOS was the predominant compound, making up on average 88.9% of the ∑PFC, followed by PFOSA (7.8%). PFUnA (1.9%) and PFDA (1.2%) were detected in most samples. PFHxS, PFNA and PFOA were only found in a minority of the samples. We found substantial differences in PFC concentrations among life history stages, the highest concentrations were found in neonates, suckling juveniles and lactating females. Such differences should be considered when PFC levels in wildlife are evaluated. The high concentrations found in young porpoises are of concern as PFCs have known toxic effects on the development of the central nervous system and reproductive organs. Despite efforts to reduce PFC emissions, a decreasing temporal trend of concentrations was not detected for any compound. PFCA concentrations were found to be increasing.     

Assessing “Urban Karst” Effects from Groundwater–Storm Sewer System Interaction in a Till Aquitard

Storm sewer systems and their associated utility trenches may strongly influence the effects of urbanization on a groundwater system. This study was undertaken to identify the causes of district-wide basement infiltration in an aquitard system. It comprised widespread continuous monitoring of utility trench wells and dye tracing from storm sewer system exfiltration tests. The results indicate that a major effect of urbanization on shallow groundwater is related to storm sewer system exfiltration, which is marked by a characteristic pattern of head variations in the aquitard unrelated to distributed surface infiltration. The aquitard constrains flow from storm sewer system exfiltration to the utility trench, creating an urban flow path for groundwater discharge. Temporary buildup of water levels in the utility trench drives relatively high-velocity flow through the permeable sewer bedding material of the utility trench to a separate foundation drainage collector system, ultimately causing a severe “urban karst” effect that produces system surcharging and widespread basement water infiltration. The main conditions causing the “urban karst” are the large hydraulic conductivity ratio between the utility trench material and the aquitard, and the shallow depth and low gradient of the storm sewer system imposed by a very flat drainage basin.     

Detecting trends that are nonlinear and asymmetric on diurnal and seasonal time scales

Trends in climate time series are often nonlinear and temporally-asymmetric, i.e. the trend is different for different seasons and/or hours of the day. Here a method is developed that allows the nonlinearity and temporal asymmetry of a trend to be investigated simultaneously. First, nonlinear trend components are extracted from a univariate time series, by adapting a nonparametric dimension-reduction method. Then, the nonlinear trend components are substituted into a regression model in which the periodic mean component and the periodic variation in the amplitude of the nonlinear trend are modeled using harmonic functions of the seasonal and diurnal periods. Third, trend patterns in the positive and negative anomalies are investigated, by extending the nonlinear trend model using indicator variables. Fourth, a non-local inferential test is developed to test the statistical significance of the trend patterns. The nonlinear trend model is applied to a simulated time series, as well as to long-term high-resolution temperature records from five Southern Hemisphere sites: Lucas Heights, Sydney Airport, Cape Grim, Macquarie Island and Law Dome. Our method should be generally useful for identifying the effect of both climate-related factors and observation/site-related factors on seasonal and diurnal trends in meteorological data series.