Aeolian sediment fingerprinting using a Bayesian mixing model

Identifying sand provenance in depositional aeolian environments (e.g. dunefields) can elucidate sediment pathways and fluxes, and inform potential land management strategies where windblown sand and dust is a hazard to health and infrastructure. However, the complexity of these pathways typically makes this a challenging proposition, and uncertainties on the composition of mixed‐source sediments are often not reported. This study demonstrates that a quantitative fingerprinting method within the Bayesian Markov Chain Monte Carlo (MCMC) framework offers great potential for exploring the provenance and uncertainties associated with aeolian sands. Eight samples were taken from dunes of the small (~58 km²) Ashkzar erg, central Iran, and 49 from three distinct potential sediment sources in the surrounding area. These were analyzed for 61 tracers including 53 geochemical elements (trace, major and rare earth elements (REE)) and eight REE ratios. Kruskal–Wallis H‐tests and stepwise discriminant function analysis (DFA) allowed the identification of an optimum composite fingerprint based on six tracers (Rb, Sr, ⁸⁷Sr, (La/Yb)_n, Ga and δCe), and a Bayesian mixing model was applied to derive the source apportionment estimates within an uncertainty framework. There is substantial variation in the uncertainties in the fingerprinting results, with some samples yielding clear discrimination of components, and some with less clear fingerprints. Quaternary terraces and fans contribute the largest component to the dunes, but they are also the most extensive surrounding unit; clay flats and marls, however, contribute out of proportion to their small outcrop extent. The successful application of these methods to aeolian sediment deposits demonstrates their potential for providing quantitative estimates of aeolian sediment provenances in other mixed‐source arid settings, and may prove especially beneficial where sediment is derived from multiple sources, or where other methods of provenance (e.g. detrital zircon U–Pb dating) are not possible due to mineralogical constraints. Copyright © 2017 John Wiley & Sons, Ltd.     

How many measurements are required to construct an accurate sand budget in a large river? Insights from analyses of signal and noise

Morphological change in river channels is frequently evaluated in the context of mass balance sediment budgets. In a closed sediment budget, measurements of sediment influx and efflux are coupled with measured changes in channel topography to provide both spatial and temporal resolution, and independent estimates of the mass balance. For sediment budgets constructed over long river segments (~10² channel widths or greater) and long periods (~2 years or longer), spatial and temporal accumulation of measurement uncertainty, compounded by inadequate sampling frequency or spatial coverage, may produce indeterminate results. The degree of indeterminacy may be evaluated in the context of a signal-to-noise ratio (SNR), which is a function of the magnitude of the mass balance and the magnitudes of potential systematic uncertainties associated with measurements and incomplete sampling. We report on a closed sand budget consisting of measurements of flux and two morphological surveys for a 50-km segment of a large river over a 3-year period. Accurate reporting of the magnitude and sign of the change in sand storage was only possible by using state-of-the-art techniques with high temporal frequency and large spatial extent. Together, a sand flux and morphological mass balance revealed that sand evacuation was temporally concentrated (~100% of mass change occurred during 19% of the study period) and highly localized (70% of mass change occurred in 12% of the study segment). A SNR analysis revealed that uncertainty resulting from undersampling may approach or exceed that caused by measurement uncertainty and that daily sampling of suspended-sand concentration or repeat mapping of at least 50% of the river segment was required to determine the sand budget with SNR > 1. The approach used here to analyze sand budget uncertainty is especially applicable to other river systems with large temporal variability in sediment transport and large spatial variability in erosion and deposition. © 2018 John Wiley & Sons, Ltd.     

The contribution of faint active galactic nuclei to the hard X-ray background

Hard X-ray selection is the most efficient way to discriminate between accretion-powered sources, such as active galactic nuclei (AGN), and sources dominated by starlight. Hard X-rays are also less affected than other bands by obscuration. We have therefore carried out the BeppoSAX High Energy Large Area Survey (HELLAS) in the largely unexplored 5–10 keV band, finding 180 sources in ∼50 deg² of sky with flux≳5×10⁻¹⁴ erg cm⁻² s⁻¹. After correction for the non-uniform sky coverage this corresponds to resolving about 30 per cent of the hard cosmic X-ray background (XRB). Here we report on a first optical spectroscopic identification campaign, finding 12 AGN out of 14 X-ray error boxes studied. Seven AGN show evidence for obscuration in X-ray and optical bands, a fraction higher than in previous ROSAT or ASCA – ROSAT surveys (at 95–99 and 90 per cent confidence levels respectively), thus supporting the scenario in which a significant fraction of the XRB is created by obscured AGN.     

Glimpses of oceanic lithosphere of the Challenger Deep forearc segment in the southernmost Marianas: The 143°E transect, 5800–4200 m

We studied nine samples of igneous rocks from the inner wall of the Mariana Trench above the Challenger Deep from 4150 to 6100 m depth recovered by manned submersible and ROV. Samples from two regions that bracket the Moho were studied: (i) 7 samples from a N‐S transect a few km to the west of the Shinkai Seep Field; and (ii) 2 samples from the Shinkai Seep Field. Transect samples include olivine‐2 pyroxene hornblendites, amphibole basalts, basaltic andesite, and hornblende andesite. We analyzed three transect samples for ⁴⁰Ar/³⁹Ar ages; two yielded good plateau ages of 46.5 ±0.5 Ma (hornblendite) and 46.60 ±0.15 Ma (hornblende andesite). These results combined with previously published results, indicate that this crust formed during an intense 46–47 Ma magmatic episode that occurred 5–6 my after subduction initiation. Hornblendites and hornblende basalts formed from primitive magmas, as shown by high MgO (11–21 wt%), Ni (222–885 ppm) and Cr (412–1145 ppm) contents. Electron microprobe analyses indicate that hornblende is Na‐rich (up to 3.0 wt% Na₂O) and that many samples have an atypically large range in plagioclase composition (i.e. individual samples have An < 10 to An 90 plagioclase). Two subgroups can be identified: a mostly deeper depleted suite and a mostly shallower enriched suite. These results indicate that (i) the crust–mantle boundary in this region is transitional, occurring over a ~ 1.5 km interval, with interlayered peridotite and hornblendites between 5800 and 4300 m; and (b) extension to form the Challenger Deep forearc segment occurred by combined stretching of old crust and injection of young basaltic magmas. In contrast to the mostly fresh nature of transect samples, the two samples from the Shinaki Seep Field are intensely altered peridotite and basalt.     

The X-ray spectra of Compton-thick Seyfert 2 galaxies as seen by BeppoSAX

Results from BeppoSAX observations of Compton-thick Seyfert 2 galaxies are summarized and reviewed, and their general properties derived and discussed. In five out of the seven observed sources, the nucleus is directly visible at high X-ray energies, where the photons penetrate absorbers with column densities in the range 1.1–4.3×10²⁴ cm⁻² (in the other two sources, NGC 1068 and NGC 7674, the nucleus is instead totally obscured at all energies, implying even larger column densities). In most sources there is unambiguous evidence of a reflection component from optically thick, cold matter, while in two (or maybe four) cases there is also evidence of reflection from ionized matter. For the sources with a measured X-ray luminosity, a comparison with the infrared luminosity is made; while in two cases (the Circinus galaxy and NGC 4945) the IR emission appears to be dominated by starburst activity, in the other three sources (NGC 6240, Mrk 3 and TOL 0109-383) it is likely to be dominated by reprocessing of the UV and X-ray photons emitted by an active galactic nucleus.     

Strategies for High Precision Processing of GPS Measurements with Application to the Amery Ice Shelf,East Antarctica

A number of statistic Global Positioning System (GPS) measurement campaigns have been made on a floating Antarctic ice shelf, the Amery Ice Shelf, as part of ongoing glaciological studies designed to investigate the ice shelf dynamics, grounding zone definition, and ice shelf strain. Such studies ar fundamental to improving out knowledge of the Antarctic ice-sheet mass balance and dynamical models of ice sheet/ocean interaction. This article describes two techniques used to process the statistic GPS data. One approach uses a segmented version of the classical static methodology, and the other approach adopts a new sequential processing technique. Both approaches yield similar results for the station coordinates and demonstrate the potential of GPS for extracting the tidal signal on the ice shelves and giving information on the dynamical motion of the ice sheet. To verify our results for the vertical component, we compare the ice shelf GPS tidal signal with a tidal model derived from tide gauge measurements at nearby Beaver Lake. Comparison of the GPS results with the tide model give good agreement in amplitude at the few cm level (GPS results always larger) but clearly shows evidence of phase propagation of the ocean tidal wave under the ice shelf. Improving the resolution of the tides over the ice shelves will be of tremendous benefit for future satellite missions, such as Ice, Cloud and Land Elevation Satellite (ICESAT), and the integrated use of GPS and satellite data will be fundamental for any on-going Antarctic ice sheet mass balance studies. ? 2000 John Wiley & Sons, Inc.     

Oil and gas in offshore tracts: Bias in estimates of reserves

Two independent data sets show that current means of estimating reserves of oil and gas in offshore fields are biased. The bias which is established here is that small fields (with less than about 10 million barrels of oil equivalent) are overestimated, and larger fields (at least up to 200 MMBOE) are underestimated. This systematic bias occurs with or without a significant overall bias, and in addition to a large scatter. Because bias (as opposed to scatter) has serious implications for national energy policy, and in particular for conduct of offshore lease sales, these results indicate that evaluation methods should be revised, or that ad hoc adjustments (based on historical data) should be applied.     

Vertical Land Motion in the Mediterranean Sea from Altimetry and Tide Gauge Stations

We have computed estimates of the rate of vertical land motion in the Mediterranean Sea from differences of sea level heights measured by the TOPEX/Poseidon radar altimeter and by a set of tide gauge stations. The comparison of data at 16 tide gauges, using both hourly data from local datasets and monthly data from the PSMSL dataset, shows a general agreement, significant differences are found at only one location. Differences of near-simultaneous, monthly and deseasoned monthly sea level height time-series have been considered in order to reduce the error in the estimated linear-term. In a subset of 23 tide gauge stations the mean accuracy of the estimated vertical rates is 2.3 ± 0.8 mm/yr. Results for various stations are in agreement with estimates of vertical land motion from geodetic methods. A comparison with vertical motion estimated by GPS at four locations shows a mean difference of -0.04 ± 1.8 mm/yr, however the length of the GPS time-series and the number of locations are too small to draw general conclusions.     

A review of present techniques and methodological advances in analyzing Th in aquatic systems

The short-lived thorium isotope ²³⁴Th (half-life 24.1 days) has been used as a tracer for a variety of transport processes in aquatic systems. Its use as a tracer of oceanic export via sinking particles has stimulated a rapidly increasing number of studies that require analyses of ²³⁴Th in both marine and freshwater systems. The original ²³⁴Th method is labor intensive. Thus, there has been a quest for simpler techniques that require smaller sample volumes. Here, we review current methodologies in the collection and analysis of ²³⁴Th from the water column, discuss their individual strengths and weaknesses, and provide an outlook on possible further improvements and future challenges. Also included in this review are recommendations on calibration procedures and the production of standard reference materials as well as a flow chart designed to help researchers find the most appropriate ²³⁴Th analytical technique for a specific aquatic regime and known sampling constraints.     

Geomorphology,hydrology, and aquatic vegetation drive seasonal hyporheic flow patterns across a gravel‐dominated floodplain

Across 1·7 km² of the Umatilla River floodplain (Oregon, USA), we investigated the influences of an ephemeral tributary and perennial ‘spring channel’ (fed only by upwelling groundwater) on hyporheic hydrology. We derived maps of winter and summer water‐table elevations from data collected at 46 monitoring wells and 19 stage gauges and used resulting maps to infer groundwater flow direction. Groundwater flow direction varied seasonally across the floodplain and was influenced by main channel stage, flooding, the tributary creek, and the location and direction of hyporheic exchange in the spring channel. Hyporheic exchange in the spring channel was evaluated with a geochemical mixing model, which confirmed patterns of floodplain groundwater movement inferred from water‐table maps and showed that the spring channel was fed predominantly by hyporheic water from the floodplain aquifer (87% during winter, 80% during summer), with its remaining flow supplied by upslope groundwater from the adjacent catchment aquifer. Summertime growth of aquatic macrophytes in the spring channel also influenced patterns of hyporheic exchange and groundwater flow direction in the alluvial aquifer by increasing flow resistance in the spring channel, locally raising surface water stage and adjacent water‐table elevation, and thereby altering the slope of the water‐table in the hyporheic zone. The Umatilla River floodplain is larger than most sites where hyporheic hydrology has been investigated in detail. Yet, our results corroborate other research that has identified off‐channel geomorphic features as important drivers of hyporheic hydrology, including previously published modeling efforts from a similar river and field observations from smaller streams. Copyright © 2007 John Wiley & Sons, Ltd.