The spray contribution to net evaporation from the sea: A review of recent progress

The part that sea spray plays in the air-sea transfer of heat and moisture has been a controversial question for the last two decades. With general circulation models (GCMs) suggesting that perturbations in the Earth's surface heat budget of only a few W m^–2 can initiate major climatic variations, it is crucial that we identify and quantify all the terms in that heat budget. Thus, here we review recent work on how sea spray contributes to the sea surface heat and moisture budgets. In the presence of spray, the near-surface atmosphere is characterized by a droplet evaporation layer (DEL) with a height that scales with the significant-wave amplitude. The majority of spray transfer processes occur within this layer. As a result, the DEL is cooler and more moist than the atmospheric surface layer would be under identical conditions but without the spray. Also, because the spray in the DEL provides elevated sources and sinks for heat and moisture, the vertical heat fluxes are no longer constant with height. We use Eulerian and Lagrangian models and a simple analytical model to study the processes important in spray droplet dispersion and evaporation within this DEL. These models all point to the conclusion that, in high winds (above about 15 m/s), sea spray begins to contribute significantly to the air-sea fluxes of heat and moisture. For example, we estimate that, in a 20-m/s wind, with an air temperature of 20°C, a sea surface temperature of 22°C, and a relative humidity of 80%, the latent and sensible heat fluxes resulting from the spray alone will have magnitudes of order 150 and 15 W/m², respectively, in the DEL. Finally, we speculate on what fraction of these fluxes rise out of the DEL and, thus, become available to the entire marine boundary layer.     

Thermodynamic properties of the forsterite-fayalite (Mg2SiO4-Fe2SiO4) solid solution. determination of heat of formation

A high temperature calorimetric solution method involving the use of a sodium and lithium metaborate (NaBO₂+LiBO₂) molten bath at 1,180 K, has been developed in order to measure the enthalpy of formation of the forsterite-fayalite (Mg₂SiO₄-Fe₂SiO₄) system. The samples used for these measurements have been obtained by synthesis. They have been carefully controlled by chemical and X-ray analysis and Mössbauer spectroscopy. The results obtained for forsterite and fayalite agree closely with the data commonly found in the literature. Owing to the uncertainty of the experimental results, it is not possible to determine conclusively whether an enthalpy of mixing exists in this system.     

226Ra and222Rn contents of Galapagos Rift hydrothermal waters —the importance of low-temperature interactions with crustal rocks

Hydrothermal waters collected by “Alvin” from the Galapagos Spreading Center are enriched in²²²Rn by factors of 50–200 over bottom waters. The²²⁶Ra in the same samples, however, is enriched by less than a factor of four over bottom waters. Enrichments of²²²Rn result primarily from α-recoil from rock surfaces while²²⁶Ra enrichments are dominantly produced by high-temperature alteration of cooling ridge volcanics. The abundances of both nuclides exhibit positive correlations with temperature. The data extrapolate to bottom water temperatures and compositions, demonstrating the importance of seawater mixing. Different vents, however, have different mixing lines, and vents with high²²²Rn have low²²⁶Ra. We propose these patterns result from variations in the extent of low-temperature crustal interaction with the hydrothermal fluids. Low-temperature crustal waters can maintain high steady state²²²Rn contents due to the α-recoil additions to the fluids. The²²⁶Ra, however, is strongly adsorbed at low-temperatures resulting in low concentrations of this nuclide in low-temperature crustal waters. Thus, physical mixing of a crustal water component with hydrothermal waters or variable crustal path lengths of the hydrothermal fluids can account for the variable mixing lines and²²²Rn/²²⁶Ra values of the hot springs.The²²²Rn/²²⁶Ra value appears to be a sensitive indicator of low-temperature crustal interaction. Values > 100 have experienced extensive crustal interaction and are indicative of diffuse hydrothermal flow. Values between 1 and 10 are indicative of primary hydrothermal fluids which have not experienced significant interaction with the crust. Values of²²²Rn/²²⁶Ra between 10³ and 10⁴ are indicative of interaction of the hydrothermal fluids with sediments. Such values are observed in water samples from the Galapagos hydrothermal mounds.     

Genetic differentiation ofNiphargus rhenorhodanensis (Amphipoda) from interstitial and karst environments

Electrophoretic variation in proteins encoded by seven presumptive gene loci was analyzed in four populations of the stygobiont amphipodNiphargus rhenorhodanensis. The four populations occur in different habitats, including one in drainage canals, another from sediments of the Ain River, a tributary of the Rhône River, and the remaining two occur in a karstic massif (Dorvan, Ain, France) in the epikarstic and at the base level of the massif, respectively. Six of the seven loci were polymorphic within or among populations, with as many as three electromorphs segregating at the most variable loci. Significant deficiencies in the frequency of heterozygotes were common. Genetic divergence between the two populations of the Dorvan Massif and between the two of the Ain River (forest and sediment habitats) was large. This was highly unexpected, particularly in the case of the two hydrologically connected populations of the Dorvan Massif. It is suggested that either low migration rates or the presence of ecological barriers to gene flow may result in strong genetic differention among local populations ofNiphargus.     

The radiocarbon budget for Mono Lake: an unsolved mystery

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.     

Coastal conglomerates around the Hadjer el Khamis inselbergs (western Chad,central Africa): new evidence for Lake Mega‐Chad episodes

This paper reports on a study dealing with the rhyolitic inselbergs of Hadjer el Khamis that formed palaeoislands during Lake Mega‐Chad events. Field observations have shown that: (1) conglomeratic patches of immature to mature clasts are preserved at the feet of the Hadjer el Khamis inselbergs; (2) in cross‐section, their pro?le reveals a well de?ned cliff–platform junction at a constant elevation (325 m). The monolithological clasts show all degrees of roundness, from angular cobbles to well rounded pebbles. This wide range of maturity suggests a coastal origin for these cobbles. The system was permanently fed with angular clasts, which were progressively worn by waves. Cobbles that were wave‐worked for the longest time are the best rounded. The cliff–platform junction is the result of erosion by waves, which attacked and undercut the inselberg cliffs during Lake Mega‐Chad events. Asymmetrical erosion pro?les moreover suggest a wind regime dominated by SW to NE oriented winds. These interpretations have two implications. The elevation of the cliff–platform junction is an indication of the highest water level of Lake Mega‐Chad at 320–325 m, which is in agreement with other observations elsewhere in the basin. The SW to NE oriented winds show that monsoon‐related winds were prevalent during Lake Mega‐Chad events, suggesting the Inter‐Tropical Convergence Zone was located higher in latitude than today. Copyright © 2003 John Wiley & Sons, Ltd.     

Genesis of a mottled horizon by Fe-depletion within a laterite cover in the Amazon BasinGenèse d'un horizon tacheté par déferruginisation dans une couverture à latérite du Bassin amazonien

A mottled horizon in a laterite cover (without any duricrust) was studied by microscopy and quantitative chemical microanalysis. Apart from the voids, light red spots consisting of Fe-rich particles (≈2 μm) are set in clayey plasma. Dark red spots consisted of concentrations of Fe-rich particles. These patterns are inherited. On the border of structural or biological voids, where Fe-depletion features are systematic, gray or yellow spots result from dissolution of the Fe-rich particles and impregnation of the plasma by iron, respectively. The present Fe-depletion is the dominant process that explains the mottled differentiation and the absence of lateritic duricrust. To cite this article: V. Rosolen et al., C. R. Geoscience 334 (2002) 187–195.     

Lacustrine wave-dominated clastic shorelines: modern to ancient littoral landforms and deposits from the Lake Turkana Basin (East African Rift System,Kenya)

This paper presents an overview of some of the most significant, recent to ancient, littoral morpho-sedimentary structures and deposits from the Lake Turkana Basin. We highlight the importance of wave-related sedimentary processes in lakes, and more specifically in rift lakes. In the published literature, references to wave-dominated shorelines are mainly in regards to coastal marine environments. However, numerous modern lakes exhibit typical wave-dominated littoral landforms, and related sedimentary deposits are known from several paleolake successions in the geological record. Wave-related processes are often of relatively minor importance in depositional models for lacustrine environments. Classical models emphasize clastics transported by rivers, which are then distributed by fan-deltas and/or deltas into a water body of fluctuating depth, where reworking of clastics is limited in the littoral domain, and episodic in deep waters. Modern processes in Lake Turkana and the exposed paleolake deposits of the Turkana Basin demonstrate that this view is incomplete. Wave-dominated shorelines are evident (1) for modern Lake Turkana based on prominent and active littoral landforms (e.g., beach ridges, sand spits, washover fans, and arcuate-cuspate deltas); (2) for the Holocene (African Humid Period) climate-driven highstand of Megalake Turkana and its subsequent forced regression based on conspicuous raised beach ridges and spits; and (3) for the Pliocene–Pleistocene (Omo Group, Nachukui Formation) from typical nearshore sedimentary facies and stratigraphic architectures associated with paleolake Turkana. These examples from the Turkana Basin coupled with examples from other lacustrine settings, suggest that wave-dominated clastic shorelines represent significant portions of existing and ancient lake-shores. As this view contrasts with classic depositional models for lakes, notably for those found in rift setting, we also present examples of wave-influenced littoral landforms from other lakes of the East African Rift System. Identifying lacustrine paleoshorelines from typical clastic landforms and deposits is the key to the spatial reconstruction of lakes over time, and to determine transgressive–regressive cycles. Waves action is an important agent in lakes for the erosion, transport, and deposition of clastics at the basin-scale, an aspect that needs to be integrated in sedimentary models.