Laboratory technique for quantitative thermal emissivity measurements of geological samples

Thermal infrared spectroscopy is a powerful technique for the compositional analysis of geological materials. The spectral feature in the mid-IR region is diagnostic of the mineralogy and spectral signatures of mixtures of minerals that add linearly, and therefore, can be used as an important tool to determine the mineralogy of rocks in the laboratory and remotely for planetary exploration. The greatest challenge in the emission measurement lies in the measurement of the weak thermal photons emitted from geological materials in a laboratory setup, and accurately records the temperature of the rock sample. The present work pertains to the details of a new Thermal Emission Spectrometer (TES) laboratory that has been developed under the ISRO Planetary Science and Exploration (PLANEX) programme, for emission related mineralogical investigations of planetary surfaces. The focus of the paper is on the acquisition and calibration technique for obtaining emissivity, and the deconvolution procedure to obtain the modal abundances of the thermal emission spectra in the range of 6–25 μm using Fourier Transform Infrared (FTIR) spectroscopy. The basic technique is adopted from the work of Ruff et al (1997). This laboratory at the Department of Earth Sciences, IIT-Bombay is currently developing pure end mineral library of mineral particulates (<65 μm), and adding new end members to the existing ASU spectral library. The paper argues the need for considering Lunar Orbiter Thermal Emission Spectrometer (LOTES) for future Indian Moon mission programme (Chandrayan-II) to determine evidences of varied lithologies on the lunar surface.     

Hydrography and water masses in the southeastern Arabian Sea during March–June 2003

This paper describes the hydrographic observations in the southeastern Arabian Sea (SEAS) during two cruises carried out in March–June 2003 as part of the Arabian Sea Monsoon Experiment. The surface hydrography during March–April was dominated by the intrusion of low-salinity waters from the south; during May–June, the low-salinity waters were beginning to be replaced by the highsalinity waters from the north. There was considerable mixing at the bottom of the surface mixed layer, leading to interleaving of low-salinity and high-salinity layers. The flow paths constructed following the spatial patterns of salinity along the sections mimic those inferred from numerical models. Time-series measurements showed the presence of Persian Gulf and Red Sea Waters in the SEAS to be intermittent during both cruises: they appeared and disappeared during both the fortnight-long time series.     

On the observed synoptic variability in the thermal structure of the upper northern Bay of Bengal during MONEX-79

The short-term variability observed in the near surface meteorological parameters and in the vertical thermal structure of the upper layers of the northern Bay of Bengal during a weak monsoonal regime is examined with the aid of time series measurements. The variability of the mixed layer depth is interpreted in terms of forced mixing caused by the surface wind stress and free mixing by buoyancy flux, Ekman pumping controlled by the curl of the surface wind stress, convergence associated with a clockwise gyral circulation and stratification caused by freshwater discharges from rivers. The daily-averaged current vectors in the upper layers indicate the presence of clockwise gyral circulation in the polygon area.     

Physical Properties of Umbral Dots Observed in Sunspots: A <Emphasis Type="Italic">Hinode</Emphasis> Observation

Umbral dots (UDs) are small-scale bright features observed in the umbral part of sunspots and pores. It is well established that they are manifestations of magnetoconvection phenomena inside umbrae. We study the physical properties of UDs in different sunspots and their dependence on decay rate and filling factor. We have selected high-resolution, G-band continuum filtergrams of seven sunspots from Hinode to study their physical properties. We have also used Michelson Doppler Imager (MDI) continuum images to estimate the decay rate of selected sunspots. An identification and tracking algorithm was developed to identify the UDs in time sequences. The statistical analysis of UDs exhibits an averaged maximum intensity and effective diameter of 0.26 \(I_{\mathrm{QS}}\) and 270 km. Furthermore, the lifetime, horizontal speed, trajectory length, and displacement length (birth–death distance) of UDs are 8.19 minutes, 0.5 km?s^?1, 284 km, and 155 km, respectively. We also find a positive correlation between intensity–diameter, intensity–lifetime, and diameter–lifetime of UDs. However, UD properties do not show any significant relation with the decay rate or filling factor.     

New quantitative approaches for classifying and predicting local-scale habitats in estuaries

This study has developed quantitative approaches for firstly classifying local-scale nearshore habitats in an estuary and then predicting the habitat of any nearshore site in that system. Both approaches employ measurements for a suite of enduring environmental criteria that are biologically relevant and can be easily derived from readily available maps. While the approaches were developed for south-western Australian estuaries, with a focus here on the Swan and Peel-Harvey, they can easily be tailored to any system.     

‘Thermohaline front’ off the east coast of India and its generating mechanism

Physical oceanography measurements reveal a strong salinity (0.18 psu km^?1) and temperature (0.07 °C km^?1) front off the east coast of India in December 1997. T–S diagrams suggest lateral mixing between the fresh water at the coast and the ambient warmer, saltier water. This front seems to be the result of southward advection of fresh and cool water, formed in the northern Bay of Bengal during the monsoon, by the East Indian Coastal Current, as suggested by the large-scale salinity structure in the SODA re-analysis and the anti-cyclonic gyre in the northwestern Bay of Bengal during winter. The data further reveals an offshore front in January, which appears to be the result of a meso-scale re-circulation around an eddy, bringing cold and freshwater from the northern Bay of Bengal further away from the shore. Our cruise data hence illustrates that very strong salinity fronts can appear in the Bay of Bengal after the monsoon, as a result of intense coastal circulation and stirring by eddies.     

Solar wind and other gases in the regoliths of the Pesyanoe parent object and the moon

We report new data from Pesyanoe‐90,1 (dark lithology) on the isotopic signature of solar wind (SW) Xe as recorded in this enstatite achondrite which represents a soil‐breccia of an asteroidal regolith. The low temperature (≤800°C) steps define the Pesyanoe‐S xenon component, which is isotopically consistent with SW Xe reported for the lunar regolith. This implies that the SW Xe isotopic signature was the same at two distinct solar system locations and, importantly, also at different times of solar irradiation. Further, we compare the calculated average solar wind “SW‐Xe” signature to Chass‐S Xe, the indigenous Xe observed in SNC (Mars) meteorites. Again, a close agreement between these compositions is observed, which implies that a mass‐dependent differential fractionation of Xe between SW‐Xe and Chass‐S Xe is >1.5%_o per amu. We also observe fractionated (Pesyanoe‐F) Xe and Ar components in higher temperature steps and we document a fission component due to extinct ²⁴⁴Pu. Interestingly, the Pesyanoe‐F Xe component is revealed only at the highest temperatures (>1200°C). The Pesyanoe‐F gas reveals Xe isotopic signatures that are consistent with lunar solar energetic particles (SEP) data and may indicate a distinct solar energetic particle radiation as was inferred for the moon. However, we cannot rule out fractionation processes due to parent body processes. We note that ratios ³⁶Ar/³⁸Ar≤5 are also consistent with SEP data. Calculated abundances of the fission component correlate well with radiogenic ⁴⁰Ar concentrations, revealing rather constant ²⁴⁴Pu/K ratios in Pesyanoe, and separates thereof, and indicate that both components were retained. We identify a nitrogen component (δ¹⁵N = 44%_o) of non‐solar origin with an isotopic signature distinct from indigenous N (δ¹⁵N = ?33%^o). While large excesses at ¹²⁸Xe and ¹²⁹Xe are observed in the lunar regolith samples, these excesses in Pesyanoe are small. On the other hand, significant ¹²⁶Xe isotopic excesses, comparable to relative excesses observed in lunar soils and breccias, are prominent in the intermediate temperature steps of Pesyanoe‐90,1.     

Development of a low-order Adaptive Optics system at Udaipur Solar Observatory

A low-order Adaptive Optics (AO) system is being developed at the Udaipur Solar Observatory and we present in this paper the status of the project, which includes the image stabilization system and calibration of wavefront sensor and deformable mirror. The image stabilization system comprises of a piezo driven tip-tilt mirror, a high speed camera (955 fps), a frame grabber system for sensing the overall tilt and a Linux based Intel Pentium 4 control computer with Red Hat Linux OS. The system operates under PID control. In the closed loop, an rms image motion of 0.1–0.2 arcsec was observed with the improvement factor varying from 10–20 depending on the external conditions. Error rejection bandwidth of the system at 0 dB is 80–100 Hz. In addition to that, we report the on-going efforts in the calibration of lenslet array and deformable mirror for sensing and correcting the local tilt of the wavefront.     

The dilution and dispersion of ballast water discharged into Goderich Harbor

Observations are presented on dilution and dispersion rates of ballast water discharged under normal operational conditions at the semi-enclosed port of Goderich, Ontario. The ballast water was tagged with Rhodamine-WT dye and microscopic magnetically-attractive tracer particles. Maximum concentrations of dye immediately after discharge were diluted to 1-5% of initial ballast tank concentrations, and within 3 days had decreased to less than 0.1% of initial concentrations. Inside the harbor, there was 10-20% of the ballast water still present after 2 days, consistent with a flushing rate of 0.8-1.15 day⁻¹. Magnetic particles were collected up to 7.5 km outside the harbor after one day, consistent with a dilution factor of order 10⁵ outside the harbor. The results of this study are discussed in the context of ballast water discharge standards proposed by the International Maritime Organization to minimize the introduction of aquatic nonindigenous species through ships’ ballast water and sediments.