Raman microspectroscopy: A non-destructive tool for routine calibration of apatite crystallographic structure for fission-track analyses

Compositional control on the annealing kinetics of fission-tracks (FT) in apatite requires routine measurement of sample grain composition. However, for practical reasons the bulk composition of analysed grains is not routinely measured and instead grain chlorine content or etch-pit dimensions are used to characterise a samples annealing behaviour. A more desirable approach is to measure crystallographic parameters (i.e. unit cell dimension) of a grain as these represent the summed effect of all substitutions and crystal defects. We show how Raman microspectrometry can be used as a routine non-destructive tool to obtain rapid measurement of the crystallographic structure of apatite grains etched for FT analysis. Variations of unit cell parameter a are found to correspond to a systematic variation of Raman shift in the range of 452–440 cm^− 1 for measurements made on c-parallel sections of apatite where the direction of the polarized incident beam is parallel to the c axis.     

Parameterisation of the Planetary Boundary Layer for Diagnostic Wind Models

The planetary boundary-layer (PBL) parameterization is a key issue for the definition of initial wind flow fields in diagnostic models. However, PBL theories usually treat separately stable, neutral, and convective stability conditions, so that their implementation in diagnostic wind models is not straightforward. In the present paper, an attempt is made to adopt a comprehensive PBL parameterisation, covering stable/neutral and unstable atmospheric conditions, which appears suitable to diagnostic models. This parameterisation is implemented into our diagnostic mass-consistent code. A validation of the consistency between the implemented PBL parameterisations has been checked through an analysis of the sensitivity of the vertical wind profiles to atmospheric stability.     

POLARIX: a pathfinder mission of X-ray polarimetry

Since the birth of X-ray astronomy, spectral, spatial and timing observation improved dramatically, procuring a wealth of information on the majority of the classes of the celestial sources. Polarimetry, instead, remained basically unprobed. X-ray polarimetry promises to provide additional information procuring two new observable quantities, the degree and the angle of polarization. Polarization from celestial X-ray sources may derive from emission mechanisms themselves such as cyclotron, synchrotron and non-thermal bremsstrahlung, from scattering in aspheric accreting plasmas, such as disks, blobs and columns and from the presence of extreme magnetic field by means of vacuum polarization and birefringence. Matter in strong gravity fields and Quantum Gravity effects can be studied by X-ray polarimetry, too. POLARIX is a mission dedicated to X-ray polarimetry. It exploits the polarimetric response of a Gas Pixel Detector, combined with position sensitivity, that, at the focus of a telescope, results in a huge increase of sensitivity. The heart of the detector is an Application-Specific Integrated Circuit (ASIC) chip with 105,600 pixels each one containing a full complete electronic chain to image the track produced by the photoelectron. Three Gas Pixel Detectors are coupled with three X-ray optics which are the heritage of JET-X mission. A filter wheel hosting calibration sources unpolarized and polarized is dedicated to each detector for periodic on-ground and in-flight calibration. POLARIX will measure time resolved X-ray polarization with an angular resolution of about 20 arcsec in a field of view of 15 × 15 arcmin and with an energy resolution of 20% at 6 keV. The Minimum Detectable Polarization is 12% for a source having a flux of 1 mCrab and 10⁵ s of observing time. The satellite will be placed in an equatorial orbit of 505 km of altitude by a Vega launcher. The telemetry down-link station will be Malindi. The pointing of POLARIX satellite will be gyroless and it will perform a double pointing during the earth occultation of one source, so maximizing the scientific return. POLARIX data are for 75% open to the community while 25% + SVP (Science Verification Phase, 1 month of operation) is dedicated to a core program activity open to the contribution of associated scientists. The planned duration of the mission is one year plus three months of commissioning and SVP, suitable to perform most of the basic science within the reach of this instrument. A nice to have idea is to use the same existing mandrels to build two additional telescopes of iridium with carbon coating plus two more detectors. The effective area in this case would be almost doubled.     

Local And Global Diffusion Along Resonant Lines in Discrete Quasi-integrable Dynamical Systems

We detect and measure diffusion along resonances in a quasi-integrable symplectic map for different values of the perturbation parameter. As in a previously studied Hamiltonian case (Lega et al., 2003) results agree with the prediction of the Nekhoroshev theorem. Moreover, for values of the perturbation parameter slightly below the critical value of the transition between Nekhoroshev and Chirikov regime we have also found a diffusion of some orbits along macroscopic portions of the phase space. Such a diffusion follows in a spectacular way the peculiar structure of resonant lines.     

Finite element analysis of land subsidence above depleted reservoirs with pore pressure gradient and total stress formulations

The solution of the poroelastic equations for predicting land subsidence above productive gas/oil fields may be addressed by the principle of virtual works using either the effective intergranular stress, with the pore pressure gradient regarded as a distributed body force, or the total stress incorporating the pore pressure. In the finite element (FE) method both approaches prove equivalent at the global assembled level. However, at the element level apparently the equivalence does not hold, and the strength source related to the pore pressure seems to generate different local forces on the element nodes. The two formulations are briefly reviewed and discussed for triangular and tetrahedral finite elements. They are shown to yield different results at the global level as well in a three‐dimensional axisymmetric porous medium if the FE integration is performed using the average element‐wise radius. A modification to both formulations is suggested which allows to correctly solve the problem of a finite reservoir with an infinite pressure gradient, i.e. with a pore pressure discontinuity on its boundary. Copyright © 2001 John Wiley & Sons, Ltd.     

The thermal evolution of Corsica as recorded by zircon fission-tracks

New zircon fission-track (ZFT) ages from Corsica record multiple thermal events that can be tied to the structural evolution of the western Mediterranean region. The Corsican zircons have a wide scatter of ZFT grain ages (243–14 Ma), which together define several age domains. Western Corsica consists largely of stable Hercynian basement characterized by ZFT ages in the range 161–114 Ma. We interpret these ages (Late Jurassic–Early Cretaceous) as the product of a long-lived Tethyan thermal event related to continental rifting and subsequent drifting during the separation of the European and African plates and the formation of the Liguro–Piemontese ocean basin. In contrast to Hercynian Corsica, Alpine Corsica (northeast Corsica) experienced widespread deformation and metamorphism in Late Cretaceous(?)–Tertiary time. Dated samples from Alpine Corsica range in age from 112 to 19 Ma and all are reset or partially reset by one or more Alpine thermal events. The youngest ZFT grain ages are from the northernmost Alpine Corsica and define an age population at  24 Ma that indicates cooling after Tertiary thermal events associated with the Alpine metamorphism and the opening of the Liguro–Provençal basin. A less well-defined ZFT age population at  72 Ma is present in both Alpine Corsica and Hercynian basement rocks. The thermal history of these rocks is not clear. One interpretation is that the ZFT population at  72 Ma reflects resetting during a Late Cretaceous event broadly synchronous with the early Alpine metamorphism. Another interpretation is that this peak is related to variable fission-track annealing and partial resetting during the Tertiary Alpine metamorphic event across central to north-eastern Corsica. This partial age resetting supports the presence of a fossil ZFT partial annealing zone and limits the peak temperature in this area below 300 °C, for both the affected pre-Alpine and Alpine units.     

Converted phases analysis of the Campi Flegrei caldera using active seismic data

We applied a type of depth migration for converted seismic phases to active and passive seismic data sets from the Campi Flegrei volcanic region in southern Italy. The migration method is based on the diffraction summation migration technique. Travel times to grid points in a volume were calculated in smooth P and S-velocity models and trace energy near the calculated converted phase time was stacked over multiple sources at one receiver. Weighting factors based on Snell's Law at an arbitrarily oriented local interface were applied to better focus trace energy. PP reflection images from the active data set provide increased detail to images of the caldera rim from other studies. The migrated images also show features near 2–3 km in depth beneath Pozzuoli City, which may be associated with an over-pressured gas volume, as suggested by other geophysical investigations. Possible deeper features near 4 km depth may be related to the presence of the carbonate basement or may image a previously undetected feature, such as a small body of strongly thermometamorphosed volcanic rock. The current passive earthquake data set from the 1984 ground uplift episode was not well suited to the converted phases analysis due to narrow P–S windows and high noise levels in the traces. However, two stations provide confirmation and extension of imaged features in the active data.