Comment on " Volume of magma accumulation or withdrawal estimated from surface uplift or subsidence, with application to the 1960 collapse of Kīlauea volcano" by P. T. Delaney and D. F. McTigue

 In volcanoes that store a significant quantity of magma within a subsurface summit reservoir, such as Kīlauea, bulk compression of stored magma is an important mode of deformation. Accumulation of magma is also accompanied by crustal deformation, usually manifested at the surface as uplift. These two modes of deformation – bulk compression of resident magma and deformation of the volcanic edifice – act in concert to accommodate the volume of newly added magma. During deflation, the processes reverse and reservoir magma undergoes bulk decompression, the chamber contracts, and the ground surface subsides. Because magma compression plays a role in creating subsurface volume to accommodate magma, magma budget estimates that are derived from surface uplift observations without consideration of magma compression will underestimate actual magma volume changes. Received: 30 September 1998 / Accepted: 27 July 1999     

Landscape influences on aluminium and dissolved organic carbon in streams draining the Hubbard Brook valley,New Hampshire,USA

Concentrations of both aluminium (Al) and dissolved organic carbon (DOC) in stream waters are likely to be regulated by factors that influence water flowpaths and residence times, and by the nature of the soil horizons through which waters flow. In order to investigate landscape‐scale spatial patterns in streamwater Al and DOC, we sampled seven streams draining the Hubbard Brook valley in central New Hampshire. We observed considerable variation in stream chemistry both within and between headwater watersheds. Across the valley, concentrations of total monomeric aluminium (Al_m) ranged from below detection limits (<0·7 µmol l⁻¹) to 22·3 µmol l⁻¹. In general, concentrations of Al_m decreased as pH increased downslope. There was a strong relationship between organic monomeric aluminium (Al_o) and DOC concentrations (R² = 0·92). We observed the highest Al_m concentrations in: (i) a watershed characterized by a steep narrow drainage basin and shallow soils and (ii) a watershed characterized by exceptionally deep forest floor soils and high concentrations of DOC. Forest floor depth and drainage area together explained much of the variation in ln Al_m (R² = 0·79; N = 45) and ln DOC (R² = 0·87; N = 45). Linear regression models were moderately successful in predicting ln Al_m and ln DOC in streams that were not included in model building. However, when back‐transformed, predicted DOC concentrations were as much as 72% adrift from observed DOC concentrations and Al_m concentrations were up to 51% off. This geographic approach to modelling Al and DOC is useful for general prediction, but for more detailed predictions, process‐level biogeochemical models are required. Copyright © 2005 John Wiley & Sons, Ltd.     

Lagrangian air mass tracking with smart balloons during ACE‐2

A 3rd‐generation smart balloon designed at National Oceanic and Atmospheric Administration, Air Resources Laboratory Field Research Division, in collaboration with the University of Hawaii, was released from ship‐board during the recent Second Aerosol Characterization Experiment (ACE‐2) to provide Lagrangian air‐mass tracking data. ACE‐2 is the 3rd in a series of field experiments designed to study the chemical, physical, and radiative properties and processes of atmospheric aerosols and their role in climate and is organized by the international global atmospheric chemistry (IGAC) program. The adjective smart in the title of this paper refers to the fact that the buoyancy of the balloon automatically adjusts through the act of pumping air into or releasing air from the ballast portion of the balloon when it travels vertically outside a barometric pressure range set prior to release. The smart balloon design provides GPS location, barometric pressure, temperature, relative humidity, and other data via a transponder to a C130 research aircraft flying in the vicinity of the balloon. The addition of 2‐way communication allows interactive control of the balloon operating parameters by an observer. A total of 3 cloudy Lagrangian experiments were conducted during the ACE‐2 field program which lasted from 16 June through 26 July 1997. This paper reviews the design and capability of the smart balloons and their performance during the ACE‐2 Lagrangian experiments. Future development and applications of the technology are discussed.     

Evaluation of the budget for silicic acid in Cascadia Basin deep water

Between 2 and 3 km depth, North Pacific deep waters contain a plume of water with high silicic acid concentrations. The plume extends outward from Cascadia Basin (the Washington Margin), where waters can contain in excess of 200 μM off the coast of Oregon and Washington. To identify the source of the high Si concentrations in Cascadia Basin, we measured silicic acid and germanium concentrations in deep waters, and their fluxes from sediments using incubated cores. The mean flux of silicic acid into bottom waters is 0.81±0.05 mmol/m²-day, and the Ge/Si ratio of this flux is 0.7±0.1 μmol/mol. A box model, incorporating these results with hydrographic data, indicates that (1) no more than 5% of the silicic acid added to Basin deep waters can have a hydrothermal source (either hot or warm seeps), and (2) the total input of silicic acid to Basin deep waters is 0.06±0.02 Tmol/y. This input is nearly all from remineralized biogenic debris and should contribute about 0.5% of the 14 Tmol/y that are estimated to be necessary to maintain the North Pacific plume.     

Wyville Thomson Ridge Overflow Water: Spatial and temporal distribution in the Rockall Trough

Wyville Thomson Ridge Overflow Water (WTOW), which is the only part of the outflow from the Norwegian Sea not to directly enter the Iceland Basin, is shown to be a significant water mass in the northern Rockall Trough. It is found primarily at intermediate depths (600–1200 m) beneath the northward flowing warm Atlantic waters, and above recirculating Mediterranean influenced waters and Labrador Sea Water (LSW). The bottom of the WTOW layer can be identified by a mid-depth inflexion point in potential temperature–salinity plots. An analysis of historical data reveals that WTOW has been present in all but eight of the last 31 years at 57.5°N in the Rockall Trough. A denser component of WTOW below 1500 m has also been present, although it appears to be less persistent (12 out of the 31 years) and limited to the west of the section. The signature of intermediate WTOW was absent in two periods, the mid-1980s and early 1990s, both of which coincided with a freshening, and probable increase in volume, of LSW in the trough. Potential temperature–salinity diagrams from historical observations indicate that WTOW persists at least as far south as 55°N (and as far west as 20°W in the Iceland Basin) although its signature is quickly lost on leaving the Rockall Trough. We suggest that a transport of WTOW down the western side of the trough exists, with WTOW at intermediate depths entering the eastern trough either via a cyclonic recirculation, or as a result of eddy activity. Further, WTOW is seen on the Rockall–Hatton Plateau and in the deep channels connecting with the Iceland Basin, suggesting additional possible WTOW transport pathways. These suggested transport routes remain to be confirmed by further observational or modelling studies.     

Ultraviolet photolysis of amino acids in a 100 K water ice matrix: Application to the outer Solar System bodies

We report the rates of decomposition by ultraviolet (UV) photolysis of four amino acids in millimeter-thick crystalline water ice matrices at 100 K to constrain the survivability of these important organic molecules within ice lying near the surfaces of outer Solar System bodies. We UV-irradiated crystalline ice samples containing known concentrations of the amino acids glycine, aspartic acid, glutamic acid, and phenylalanine, then we measured the surviving concentrations using high performance liquid chromatography (HPLC) with fluorescence detection. From these experiments, we determine photolytic decomposition rates and half-lives. The half-life varies linearly with the ice thickness for all acids studied here. For example, glycine is the most resistant to photolytic destruction with a half-life of 50, 12, and 3.7 h in 1.6, 0.28, and 0.14 mm thick ices, respectively. We explain this linear variation of half-life with thickness as a consequence of extinction, mostly due to scattering, within these macroscopically thick ice samples. Applied to low latitude surface ice on Jupiter's satellite Europa, this analysis indicates that the concentration of any of these amino acids within the top meter of similar ice will be halved within a ∼10 year timescale.     

High diversity of frenulates (Polychaeta: Siboglinidae) in the Gulf of Cadiz mud volcanoes: A DNA taxonomy analysis

Frenulates are the most poorly known members of the family Siboglinidae (Polychaeta: Canalipalpata). These thread-like worms occur in reducing marine sediments worldwide, but they are often overlooked in benthic samples or too poorly preserved for adequate taxonomic evaluations. We report on a remarkable diversity of frenulates that were recently sampled from 13 mud volcanoes (350–3902 m deep) in the Gulf of Cadiz, off southern Iberia. Sampled with benthic coring devices, the bodies of these long tubiculous worms were often broken or incomplete, making them difficult to identify morphologically. Consequently, we employed DNA taxonomic methods to assess their diversity. Mitochondrial cytochrome-c-oxidase subunit 1 (COI) sequences distinguished 15 evolutionary lineages inhabiting the Gulf of Cadiz. Only four of the lineages could be assigned to currently recognized Atlantic species; the remaining 11 may be new to science. This remarkable diversity of frenulates in a small geographical region is unprecedented and is hypothesized to result from environmental heterogeneity associated with the bathymetric and geochemical settings of these mud volcanoes.     

Multiwavelength XMM–Newton observations of the Laor et al. sample of PG quasars

We present XMM–Newton /EPIC spectra for the Laor et al. sample of Palomar Green (PG) quasars. We find that a power law provides a reasonable fit to the 2–5 keV region of the spectra. Excess soft X-ray emission below 2 keV is present for all objects, with the exception of those known to contain a warm absorber. However, a single power law is a poor fit to the 0.3–10.0 keV spectrum and instead we find that a simple model, consisting of a broken power law (plus an iron line), provides a reasonable fit in most cases. The equivalent width of the emission line is constrained in just 12 objects but with low (<2σ) significance in most cases. For the sources whose spectra are well fitted by the broken-power-law model, we find that various optical and X-ray line and continuum parameters are well correlated; in particular, the power-law photon index is well correlated with the FWHM of the Hβ line and the photon indices of the low- and high-energy components of the broken power law are well correlated with each other. These results suggest that the 0.3–10 keV X-ray emission shares a common (presumably non-thermal) origin, as opposed to suggestions that the soft excess is directly produced by thermal disc emission or via an additional spectral component. We present XMM–Newton Optical Monitor (OM) data, which we combine with the X-ray spectra so as to produce broad-band spectral energy distributions (SEDs), free from uncertainties due to long-term variability in non-simultaneous data. Fitting these optical–UV spectra with a Comptonized disc model indicates that the soft X-ray excess is independent of the accretion disc, confirming our interpretation of the tight correlation between the hard and soft X-ray spectra.     

Crystalline silicates in comets: How did they form?

Two processes have been proposed to explain observations of crystalline silicate minerals in comets and in protostellar sources, both of which rely on the thermal annealing of amorphous grains. First, high temperatures generated by nebular shock processes can rapidly produce crystalline magnesium silicate grains and will simultaneously produce a population of crystalline iron silicates whose average grain size is ∼10-15% that of the magnesium silicate minerals. Second, exposure of amorphous silicate grains to hot nebular environments can produce crystalline magnesium silicates that might then be transported outward to regions of comet formation. At the higher temperatures required for annealing amorphous iron silicates to crystallinity the evaporative lifetime of the grains is much shorter than a single orbital period where such temperatures are found in the nebula. Thermal annealing is therefore unable to produce crystalline iron silicate grains for inclusion into comets unless such grains are very quickly transported away from the hot inner nebula. It follows that observation of pure crystalline magnesium silicate minerals in comets or protostars is a direct measure of the importance of simple thermal annealing of grains in the innermost regions of protostellar nebulae followed by dust and gas transport to the outer nebula. The presence of crystalline iron silicates would signal the action of transient processes such as shock heating that can produce crystalline iron, magnesium and mixed iron-magnesium silicate minerals. These different scenarios result in very different predictions for the organic content of protostellar systems.