Kinetic stability of a melted iron globule during chondrule formation. I. Non‐rotating model

Abstract— We have investigated the kinematics of the separation of iron globules from chondrules during chondrule formation. A simple model, which assumes that the system has no angular momentum, was used to calculate the energy of a system with an iron globule and a chondrule. The energies of three different states were calculated: 1) a melted iron globule fully embedded in a melted chondrule, 2) a melted iron globule on the surface of a melted chondrule, and 3) a melted iron globule being separated from a melted chondrule. We also calculated the lowest energy shape for a melted iron globule on the surface of a melted chondrule, and compared our result with the shapes of four natural samples of chondrules and iron globules in thin sections. The shapes were calculated using an assumed value for the interface energy between the four couples of melted chondrules and the iron globules, and agree well with the natural shapes of chondrules and iron globules. The results of our calculations show that the iron globules of these four samples would be strongly bound to the surface of the melted chondrule during chondrule formation, and separation would be difficult, if the iron globules had been on the surface of precursors of these chondrules. Our results also show that if these iron globules were initially inside and transported to the surface of the melted chondrule, most of them would be ejected from the inside to outside because of surface tension forces, as long as the energy losses due to viscous dissipation when the globules pass through the surface of melted chondrules were sufficiently small. Although further improvement of the model is required, our results demonstrate that this ejection process may be responsible for the depletion of siderophile elements in natural chondrules.     

Netplankton Chlorophyll Biomass along 175°E in the Pacific Ocean

An analysis is presented of data on chlorophyll a concentrations of the total and the netplankton (>10 μm), determined either in April to June or in August to September from 48°N to 15°S along 175°E in the Pacific Ocean during 6 years by the NOPACCS (Northwest Pacific Carbon Cycle Study). Particular attention was given to the variability of absolute concentrations of the netplankton chlorophyll a and their percentage shares of the total chlorophyll a concentration. Below 0.2 μg l⁻¹ of surface total chlorophyll a, the netplankton chlorophyll a showed low percentage shares (such as 12.7% on average) with a large variation, but above 0.2 μg l⁻¹ it was 35.9% on average with less variation, showing an accelerated increase at high total chlorophyll a concentrations. High netplankton chlorophyll a concentrations in surface waters were observed at high latitudes, in waters having high chlorophyll a concentrations at sub-surface depth, and in equatorial upwelling. The percentage shares of netplankton in the total chlorophyll a in the euphotic zone were 8.5% and 25.9% above and below 0.2 μg l⁻¹, respectively, although the data points scattered over a wide range (from 7.2% to 53.8%) depending on differences in water masses, depths and seasons. High chlorophyll a concentrations and high percentage shares of netplankton corresponded to high ambient nitrate plus nitrite concentrations. Integrated netplankton chlorophyll a concentrations in the euphotic zone varied from 0.7 to 19.5 mg m⁻² in waters below 0.2 μg l⁻¹ of surface total chlorophyll a, and from 2.0 to 29.5 mg m⁻² above 0.2 μg l⁻¹, and the percentage shares of netplankton for the former were 7.4% on average and 23.7% for the latter. This revised version was published online in July 2006 with corrections to the Cover Date.     

Characterization of the amorphous state in metamict silicates and niobates by EXAFS and XANES analyses

X-ray absorption spectroscopy using synchrotron radiation has been applied to the investigation of the coordination geometries around Y, Zr and Nb atoms in metamict zircon, gadolinite, fergusonite, euxenite and samarskite. EXAFS and XANES spectra of their crystalline counterparts and synthetic compounds including ZrO₂, Y₂O₃, YNbTiO₆, YNbO₄, LiNbO₃, and NiNb₂O₆ were also measured for comparison. Metamict zircon shows a significant decrease in its Zr-O bond distances accompanying an increase in distortion of the Zr-O coordination polyhedra as compared with crystalline zircon. On the contrary, the average Nb-O bond distances and the symmetry of the coordination polyhedra around the Nb atoms in metamict euxenite and samarskite resemble those in the crystalline euxenite. Compared with crystalline fergusonite, a decrease in the distortion of the Nb-O octahedra is observed in metamict fergusonite. The structures of the second nearest neighbors (the metal-metal interactions) are largely disrupted in the metamict specimens except for metamict zircon and samarskite with high trivalent iron concentration. Nb in metamict samarskite is in octahedral coordination by oxygen and is similar to that in euxenite.     

Assessing the impacts of climate change on rice yields in the main rice areas of China

This paper assesses the impact of climate change on irrigated rice yield using B2 climate change scenario from the Regional Climate Model (RCM) and CERES-rice model during 2071--2090. Eight typical rice stations ranging in latitude, longitude, and elevation that are located in the main rice ecological zones of China are selected for impact assessment. First, Crop Estimation through Resource and Environment Synthesis (CERES)-rice model is validated using farm experiment data in selected stations. The simulated results represent satisfactorily the trend of flowering duration and yields. The deviation of simulation within ± 10% of observed flowering duration and ± 15% of observed yield. Second, the errors of the outputs of RCM due to the difference of topography between station point and grid point is corrected. The corrected output of the RCM used for simulating rice flowering duration and yield is more reliable than the not corrected. Without CO₂ direct effect on crop, the results from the assessment explore that B2 climate change scenario would have a negative impact on rice yield at most rice stations and have little impacts at Fuzhou and Kunming. To find the change of inter-annual rice yield, a preliminary assessment is made based on comparative cumulative probability at low and high yield and the coefficient variable of yield between the B2 scenario and baseline. Without the CO₂ direct effect on rice yield, the result indicates that frequency for low yield would increase and it reverses for high yield, and the variance for rice yield would increase. It is concluded that high frequency at low yield and high variances of rice yield could pose a threat to rice yield at most selected stations in the main rice areas of China. With the CO₂ direct effect on rice yield, rice yield increase in all selected stations.     

差分主成分分析法在辽河三角洲景观变化中的应用

差分主成分分析法是应用遥感数据检测景观变化的一种新方法。为了提高检测精度,我们利用TM卫星遥感数据,改进了主成分分析法和图像差值法,提出了差分主成分分析法。并以辽河三角洲地区为例,对该方法进行了验证。研究结果表明：(1) 与传统的检测法-分类后比较法相比,差分主成分分析法具有较高的检测精度,总检测精度为0.89,Kappa指数为0.82;(2) 在1984~2000年的16年间,辽河三角洲地区有近22%的景观发生了变化,主要包括芦苇湿地的减少、水稻田的增加以及城镇用地的增加。     

Lethality of increasing CO2 levels on deep-sea copepods in the western North Pacific

The first CO₂ exposure experiments on several species of pelagic copepods inhabiting surface and deep layers in the western North Pacific were conducted. Living organisms were collected from two layers between the surface and 1,500 m between latitudes of 11 and 44°N, and they were exposed aboard ship to various pCO₂ up to about 98,000 μatm. Mortality of copepods from both shallow and deep layers in subarctic to subtropical regions increased with increasing pCO₂ and exposure time. Deep-living copepods showed higher tolerance to pCO₂ than shallow-living copepods. Furthermore, deep-living copepods from subarctic and transitional regions had higher tolerances than the subtropical copepods. The higher tolerances of the deep-living copepods from subarctic and transitional regions may be due to the adaptation to the natural pCO₂ conditions in the subarctic ocean.     

The role of the grain boundary at chemical and isotopic fronts in marble during contact metamorphism

Carbon and oxygen isotopic profiles around a low pressure metasomatic wollastonite reaction front in a marble of the Hida metamorphic terrain, central Japan, display typical metamorphic fluid-enhanced isotopic zonations. Isotopic profiles obtained from detailed microscale analyses perpendicular to the chemical reaction front in calcite marble show that diffusion-enhanced isotopic exchange may control these profiles. Carbon and oxygen isotopic behaviour in grain boundaries is remarkably different. Oxygen isotopic troughs (¹⁸O depleted rims) around the calcite-grain boundaries are widely observed in this contact aureole, demonstrating that diffusion of oxygen in calcite grain boundary dominates over lattice diffusion in calcite. In contrast, no difference is observed in carbon isotopic profiles obtained from grain cores and rims. There is thus no specific role of the grain boundary for diffusion of carbonic species in the metamorphic fluid during transportation. Carbon chemical species such as CO₂ and CO₃ ions in metamorphic fluid migrate mainly through lattice diffusion. The carbon and oxygen isotope profiles may be modelled by diffusion into a semi-infinite medium. Empirically lattice diffusion of oxygen isotopes is almost six times faster than that of carbon isotopes, and oxygen grain-boundary diffusion is ten times faster than oxygen lattice diffusion. Oxygen isotopic results around the wollastonite vein indicate that migration of the metamorphic fluid into calcite marble was small and was parallel to the aquifer. From the stability of wollastonite and the attainment of oxygen isotopic equilibrium, we suggest that diffusion of oxygen occurred through an aqueous fluid phase. The timescale of formation of the oxygen isotopic profile around the wollastonite vein is calculated to be about 0.76 × 10⁶ years using the experimentally determined diffusion constant. Received: 14 January 1997 / Accepted: 23 April 1998     

Simplified technique for the rapid determination of phytoplankton pigments by reverse-phase high-performance liquid chromatography

A simplified technique for the rapid analysis of photosynthetic pigments in marine phytoplankton is described. The pigments extracted in N,N-dimethylformamide (DMF) are injected directly into the reverse-phase high-performance liquid chromatograph fitted with a photodiode array detector. We developed a new stepwise program; that is methanol-water (7525 v/v), methanol, methanol-acetone (8020) and methanol-acetone (6535). This program gives a good separation of at least 13 carotenoids, and 10 chlorophylls and their derivatives, completed within 20 min. The quantitative precision is high; the maximum standard error was less than 6%. The stability of pigments in DMF were also considered for application of this technique to the lab work on board the ship.     

Physical dynamics and biological implications of a mesoscale eddy in the lee of Hawai’i: Cyclone Opal observations during E-Flux III

E-Flux III (March 10–28, 2005) was the third and last field experiment of the E-Flux project. The main goal of the project was to investigate the physical, biological and chemical characteristics of mesoscale eddies that form in the lee of Maui and the Island of Hawai’i, focusing on the physical–biogeochemical interactions. The primary focus of E-Flux III was the cyclonic cold-core eddy Opal, which first appeared in the NOAA GOES sea-surface temperature (SST) imagery during the second half of February 2005. During the experiment, Cyclone Opal moved over 160 km, generally southward. Thus, the sampling design had to be constantly adjusted in order to obtain quasi-synoptic observations of the eddy. Analyses of ship transect-depth profiles of CTD, optical and acoustic Doppler current profiler (ADCP) data revealed a well-developed feature characterized by a fairly symmetric circular shape with a radius of about 80 km. Depth profiles of temperature, salinity and density were characterized by an intense doming of isothermal, isohaline and isopycnal surfaces. Isopleths of nutrient concentrations were roughly parallel to isopycnals, indicating the upwelling of deep nutrient-rich water. The deep chlorophyll maximum layer (DCML) shoaled from a depth of about 130 m in the outer regions of the eddy to about 60 m in the center. Chlorophyll concentrations reached their maximum values in Opal's core region (about 40 km in diameter), where nutrients were upwelled into the euphotic layer. ADCP velocity data clearly showed the cyclonic circulation associated with Opal. Vertical sections of tangential velocities were characterized by values that increased linearly with radial distance from near zero close to the center to a maximum of about at roughly 25 km from the center, and then slowly decayed. The vertical extent of the cyclonic circulation was primarily limited to the upper mixed layer, as tangential velocities decayed quite rapidly within a depth range of 90–130 m. Potential vorticity analysis suggests that only a relatively small (about 50 km in diameter) and shallow (to a depth of approximately 70 m) portion of the eddy is isolated from the surrounding waters. Radial movements of water can occur between the center of the eddy and the outer regions along density surfaces within an isopycnal range of σ–t_23.6 () and σ–t_24.4 (). Thus the biogeochemistry of the system might have been greatly influenced by these lateral exchanges of water at depth, especially during Opal's southward migration. While the eddy was translating, deep water in front of the eddy might have been upwelled into the core region, leading to an additional injection of nutrients into the euphotic zone. At the same time, part of the chlorophyll-rich waters in the core region might have remained behind the translating eddy and, thus contributed to the formation of an eddy wake characterized by relatively high chlorophyll concentrations.