Microstructurally controlled monazite chronology of ultrahigh-temperature granulites from southern India: Implications for the timing of Gondwana assembly

Ultrahigh‐temperature (UHT) granulite facies rocks from the Achankovil Shear Zone area and the southern domain of the Madurai Granulite Block in South India contain monazite useful for in situ microprobe U–Pb dating. The UHT rocks examined consist of garnet + cordierite (retrograde) + quartz + mesoperthite + biotite + plagioclase + Fe‐Ti oxides ± orthopyroxene ± sillimanite and accessory zircon and monazite. Sillimanite occurs only as inclusions in garnet. Microstructural observations suggest garnet, orthopyroxene, spinel and mesoperthite are products of peak metamorphism. Post‐peak formation of cordierite ± orthopyroxene ± quartz and cordierite + spinel + Fe‐Ti oxides assemblages is also observed. Geothermobarometry on orthopyroxene and garnet‐orthopyroxene bearing assemblages suggest peak UHT conditions of T = 940–1040°C and P = 8.5–9.5 kbar. This was followed by a retrograde stage of 3.5–4.5 kbar and 720 ± 60°C, estimated from garnet‐cordierite assemblages. A small population of rounded, probably detrital, monazites in these rocks yield ages from Meso‐ to Neoproterozoic indicating a heterogeneous source. The youngest associated spot ages are 660–600 Ma suggesting protolith deposition up to ca 600 Ma. In contrast, the vast majority of monazites that crystallized during the latest metamorphic event show late Neoproterozoic to Cambrian ages. Probability‐density plots of monazite age data show a ‘peak’ between 533 and 565 Ma, but this peak need not reflect a particular thermal event. Collating ages from homogenous metamorphic monazites associated with minerals stable at peak P‐T conditions suggests peak metamorphism in these rocks occurred at 580–600 Ma. Together with a re‐evaluation of available data from adjacent granulite blocks in southern India, these data suggest the main metamorphic event coinciding with the suturing of India with the Gondwana amalgam probably occurred 580–600 Ma. The 500–550 Ma ages commonly reported in previous studies might represent post‐peak thermal events.     

Deep sea circulation of particulate organic carbon in the Japan Sea

Seasonal and spatial variations of particulate organic carbon (POC) flux were observed with sediment traps at three sites in the Japan Sea (western and eastern Japan Basin and Yamato Basin). In order to investigate the transport processes of POC, radiocarbon (¹⁴C) measurements were also carried out. Annual mean POC flux at 1 km depth was 30.7 mg m⁻²day⁻¹ in the western Japan Basin, 12.0 mg m⁻²day⁻¹ in the eastern Japan Basin and 23.8 mg m⁻²day⁻¹ in the Yamato Basin. At all stations, notably higher POC flux was observed in spring (March–May), indicating biological production and rapid sinking of POC in this season. Sinking POC in the high flux season showed modern Δ¹⁴C values (>0‰) and aged POC (Δ¹⁴C < −40‰) was observed in winter (December–January). The Δ¹⁴C values in sinking POC were negatively correlated with aluminum concentration, indicating that Δ¹⁴C is strongly related to the lateral supply of lithogenic materials. The Δ¹⁴C values also showed correlations with excess manganese (Mn_xs) concentrations in sinking particles. The Δ¹⁴C-Mn_xs relationship suggested that (1) the majority of the aged POC was advected by bottom currents and incorporated into sinking particles, and (2) some of the aged POC might be supplied from the sea surface at the trap site as part of terrestrial POC. From the difference in the Δ¹⁴C-Mn_xs relationships between the Japan Basin and the Yamato Basin, we consider that basin-scale transport processes of POC occur in the Japan Sea.     

Evaluation of a curve-fitting method for diffuse reflectance spectra in the UV–Visible–NIR wavelength region

The Modified Gaussian Method (MGM) proposed by Sunshine et al. [Sunshine, J.M., Pieters, C.M., Pratt, S.F., 1990. Deconvolution of mineral absorption bands: an improved approach. Journal of Geophysical Research 95, 6955–6966.] is generally used to decompose spectra in the UV–Visible–NIR wavelength region into the characteristic absorption bands of minerals. Here, we compare the optimized results obtained using different curve-fitting methods for this spectrum. The result obtained using the Gaussian function for the absorption band shows a better fit than that obtained using the Lorentzian function. The background continuum of a quadratic polynomial for the wavenumber provides a better result than does the linear function for the wavenumber. We successfully decomposed the spectra of ordinary chondrites and eucrites into the absorption bands of olivine and pyroxene. The wavelength positions of these absorption bands are broadly consistent with the Fe contents of olivine and pyroxene. Although the present results are derived from a limited number of spectra, they are of use in terms of the decomposition of diffuse reflectance spectra.     

Partitioning Eddy-Covariance Methane Fluxes from a Shallow Lake into Diffusive and Ebullitive Fluxes

Methane (\(\mathrm {CH}_{4}\)) is known to be emitted from lakes to the atmosphere via processes such as diffusion and ebullition (i.e., bubble emission). We developed a practical method for partitioning eddy-covariance \(\mathrm {CH}_{4}\) fluxes from a shallow lake into diffusive and ebullitive fluxes using a wavelet analysis based on local scalar similarity between the \(\mathrm {CH}_{4}\) concentration and other reference scalars, such as the air temperature or water vapour concentration, in the wavelet time-scale domain, with the hypothesis that similar and dissimilar fluctuation components are related to diffusive and ebullitive \(\mathrm {CH}_{4}\) fluxes, respectively. Our method is applied to approximately two weeks of data obtained at a shallow mid-latitude lake. The partitioned diffusive flux has a physically sound relationship with wind speed, supporting the validity of the method. The ratio of the diffusive flux to the total flux is typically 0.11 with flow from an area of steady bubble emission, but otherwise 0.36. Further validation is required using a larger dataset and data from other lakes. The proposed method can be easily applied to historical data because it requires only 10-Hz data of \(\mathrm {CH}_{4}\) concentration and other reference scalars, along with an empirical parameter.     

Development of a numerical model for nitrates in groundwater in the reservoir area of the Komesu subsurface dam, Okinawa, Japan

A numerical model consisting of simplified equations was developed to simulate nitrate concentrations in groundwater in a reservoir area of a subsurface dam in a Quaternary limestone region. The model was composed of a water balance sub-model and a nitrogen balance sub-model; the water balance sub-model was built from tank models which can express the quick dilution near caves and the effect of dam construction; and the nitrogen balance sub-model was made to represent changes in nitrogen forms and movement of nitrogen in the soil and aquifer zones. The model was calibrated and verified by observed data before and after the dam construction and then applied to a predictive simulation under a simple assumption that rainfall descends gradually. The model seemed applicable to long-term prediction of changes in NO₃-N in the reservoir area.     

Two geomagnetic excursions during the Brunhes chron recorded in Chinese loess-palaeosol sediments

Detailed palaeomagnetic integrated with rock magnetic studies have been carried out on a loess-palaeosol sequence in Baoji, Shaanxi province, southern Chinese Loess Plateau. For most samples stepwise thermal demagnetization revealed two well-defined magnetization components. A low-temperature component (LTC), which was isolated between 100 and 200 °C, is consistent with the present geomagnetic field direction. A high-temperature component (HTC), which was isolated between 250 and 620–680 °C, shows normal, reversed or transitional polarities. Our new magnetostatigraphy revealed two distinct geomagnetic excursions recorded in loess unit of L5 and palaeosol unit of S7, respectively, and the Matuyama-Brunhes (M-B) polarity boundary in loess unit of L8. Rock magnetic experiments demonstrated that the specimens from the excursion zones have the same magnetic properties as those from the Brunhes normal or Matuyama reversed polarity zones. Measurements of anisotropy of magnetic susceptibility (AMS) showed that the sediments have primary sedimentary fabrics. Based on the palaeoclimatological and magnetostratigraphic age models, the middle Brunhes excursion in loess L5 is dated at 413–433 ka, and the early Brunhes excursion is estimated to occur 23–33 ka after the M-B reversal. Comparing with previously reported geomagnetic excursions in the Brunhes chron, the middle Brunhes excursion (L5) is likely global. For the early Brunhes excursion (S7), we need further studies to examine its global occurrence.     

Taylor-Görtler vortices expected in the air flow on sea surface waves—II

The instability of Taylor-Görtler vortices which are expected in the air flow on water waves was studied in part I, under the assumption that the curvature around the crest or the trough of water waves, where the instability was expected to take place first, was constant, namely that the characteristics of the vortices were affected little by the local change of the curvature along the direction of the progress of water waves (the direction ofx-axis) However, the curvature actually varies from positive to negative, or vice versa. In order to study this effect, the instability of Taylor-Görtler vortices is examined with respect to the range of the part of a constant curvature, in the model in which the curvature is positive constant near the trough and negative constant near the crest, and zero in the intermediate regions, respectively. It is shown that as the region of the constant curvature becomes narrower, the instability tends to weaken. For the same example with part I, namely, when the wind of 12.2 m s^–1 is blowing over swells of 15 m in wavelength, if the range of constant curvature near the trough is taken as a quarter of one wave length, the critical wave height becomes 0.96 m instead of 0.50 m, and conversely, the wave length and the height of center of the vortex become 11.9 m and 2.1 m instead of 24 m and 3.7 m, respectively.Further, using the energy equations, quantitative estimates are performed of the intensity of the vortices which develop when the wave height of the swell is 1.05 m in the above described example, and also of the influence of the vortices upon the wind profile when the equilibrium state is reached. When the vortices are generated and grow to attain to an equilibrium state interacting with the mean flow, the maximumx-component of velocity in the vortices is about 1.04 m s^–1. Consequently, the wind profile undergoes a considerable distortion from the logarithmic one near the level of 2 m height. This distorted wind profile has a form similar to those sometimes observed above the sea surface.     

Phytoremediation of Sb,As, Cu,and Zn from Contaminated Water by the Aquatic Macrophyte Eleocharis acicularis

Sb, As, Cu, and Zn toxicity and contamination have become a growing concern in recent years. Phytoremediation, a plant based and cost effective technology, may be an effective approach in the cleanup of water contaminated by these metals. In this study, the aquatic macrophyte Eleocharis acicularis was used in laboratory and field experiments to assess its capability to accumulate Sb, As, Cu, and Zn, and thereby investigate its potential application in phytoremediation. The results showed that E. acicularis adapted well to water contaminated by these metals. The removal rates of Sb, As, Cu, and Zn in the laboratory experiment were 3.04, 2.75, 0.417, and 1.49 μg/L/day, respectively. The highest concentrations of these metals accumulated in E. acicularis after 10 days of the laboratory experiment were 6.29, 6.44, 20.5, and 73.5 mg/kg dry weight, respectively. Only 8% of As, 12% of Sb, 87% of Cu and 93% of Zn removed from the water were used by E. acicularis. The highest concentrations of Sb, As, Cu, and Zn accumulated in E. acicularis after 10 wk of the field experiment were 76.0, 22.4, 33.9, and 266 mg/kg dry weight, respectively. The results indicate that E. acicularis has the ability to accumulate Sb, As, Cu, and Zn from contaminated water.     

Wind Fields over Funka Bay and Their Effect on Water Circulation in the Bay

Horizontal wind fields over Funka Bay during cold air outbreaks were simulated using a 3-D meso-scale atmospheric model. The simulated wind fields over the bay have a positive curl in the north and a negative curl in the south. These wind fields were used to simulate the current in Funka Bay using a barotropic ocean model. The simulated current pattern was composed of two vortices—one with anti-clockwise vorticity in the north and the other with clockwise vorticity in the south—and was in the opposite direction to that simulated by the uniform wind fields. This is because the wind stress curl effect on the vorticity production in Funka Bay opposes and overwhelms the bathymetry torque effect during cold air outbreaks. These results show that the non-uniformity of the wind fields caused by the land topography around a shallow lake or bay cannot be neglected in simulating its currents.     

Evapotranspiration and water source of a tropical rainforest in peninsular Malaysia

To evaluate water use and the supporting water source of a tropical rainforest, a 4‐year assessment of evapotranspiration (ET) was conducted in Pasoh Forest Reserve, a lowland dipterocarp forest in Peninsular Malaysia. The eddy covariance method and isotope signals of rain, plant, soil, and stream waters were used to determine forest water sources under different moisture conditions. Four sampling events were conducted to collect soil and plant twig samples in wet, moderate, dry, and very dry conditions for the identification of isotopic signals. Annual ET from 2012 to 2015 was quite stable with an average of 1,182 ± 26 mm, and a substantial daily ET was observed even during drought periods, although some decline was observed, corresponding with volumetric soil water content. During the wet period, water for ET was supplied from the surface soil layer between 0 and 0.5 m, whereas in the dry period, approximately 50% to 90% was supplied from the deeper soil layer below 0.5‐m depth, originating from water precipitated several months previously at this forest. Isotope signatures demonstrated that the water sources of the plants, soil, and stream were all different. Water in plants was often different from soil water, probably because plant water came from a different source than water that was strongly bound to the soil particles. Plants showed no preference for soil depth with their size, whereas the existence of storage water in the xylem was suggested. The evapotranspiration at this forest is balanced and maintained using most of the available water sources except for a proportion of rapid response run‐off.