Curation protocol of Phobos sample returned by Martian Moons eXploration

Japan Aerospace Exploration Agency's Martian Moons eXploration (MMX) mission will launch a spacecraft in 2024 to return samples from Phobos in 2029. Curatorial work for the returned Phobos samples is critical for the sample allocation without degrading the sample integrity and subsequent sample analysis that will provide new constraints on the origin of Phobos and the evolution of the circum-Mars environment. The Sample Analysis Working Team of the MMX is designing the sample curation protocol. The curation protocol consists of three phases: (1) quick analysis (extraction and mass spectrometry for gases), (2) pre-basic characterization (bulk-scale observation), and (3) basic characterization (grain-by-grain observation and allocation of the sample aliquots). Nondestructive analyses within the clean chamber (e.g., visible and near-infrared spectral imaging) and outside the chamber (e.g., gas mass spectrometry) are incorporated into the curation flow in coordination with the MMX mission instrument teams for ground-truthing the remote-sensing data sets. The MMX curation/sample analysis flow enables the seamless integration between the sample and remote-sensing data sets to maximize the scientific value of the collected Phobos samples.     

Phytoplankton and ice-algal communities in the seasonal ice zone during January (Southern Ocean,Indian sector)

Journal of Oceanography - In the seasonal ice zone (SIZ), sea-ice algae have been hypothesized to influence phytoplankton species composition in seawater after melting from sea ice. However,...     

Concentrations of Trace Elements in Carbonate Reference Materials Coral JCp-1 and Giant Clam JCt-1 by Inductively Coupled Plasma-Mass Spectrometry

Trace elements in the Geological Survey of Japan carbonate reference materials Coral JCp-1 and Giant Clam JCt-1 were determined by inductively coupled plasma-mass spectrometry after digestion with 2% v/v HNO₃. A standard addition method was adopted in this determination in order to neutralise the Ca matrix effect. In addition, Sc, Y, In and Bi were used as internal standards to control the matrix effect and correct instrumental drift. Of the eighteen elements measured in JCp-1, precisions for fourteen elements, including Cu, Cd and Ba, were better than 10% RSD and concentrations ranged from 0.002 μg g^-1 (Cs) to 8.02 μg g^-1 (Ba). The concentrations of measured trace elements in JCt-1, except for Cu, were lower than those in JCp-1. Precisions for all elements with concentrations higher than 0.04 μg g^-1 in JCt-1 were also better than 10% RSD and concentrations were found to be between 0.001 μg g^-1 (Cs) and 4.84 μg g^-1 (Ba). The concentrations of more than fifteen trace elements in the aragonite reference materials are reported here for the first time. Both reference materials are suitable for use in geochemical studies of environmental reconstruction based upon biogenic carbonate materials.     

Near-field beam pattern measurement of qualification model of ALMA band 8 (385–500 GHz) cartridge receiver

We have developed a near-field vector beam measurement system covering the range of frequencies from 385 to 500 GHz. The measurement set-up is capable of measurements with dynamic range exceeding 50 dB and amplitude and phase stability respectively of 0.1 dB/h and 1 degree/5 min at room temperature. Beam patterns of the ALMA band 8 corrugated horns and receiver optics block were measured at room temperature and lately compared with physical optics calculations obtained in the far-field. Both co-polar and cross-polar beam patterns of a qualification model of the ALMA band 8 cartridge cooled in a cartridge-test-cryostat have also been measured in the near-field as a detector of a submillimeter vector network analyzer. The measurements presented in this work refer to the lowest, middle and upper frequencies of band 8. The comparisons between software model and experimental measurements at these frequencies show good agreement down to ?30 dB for the main polarization component. The cross-polarization level of the beam propagating through the receiver optics block was also characterized. We found that a cross-polarization level better than ?28 dB can be achieved at all measured frequencies. The measured beam pattern of this receiver corresponds to efficiency of greater than 92% at the sub reflector (diameter of 750 mm) of the ALMA 12 m optics.     

Short-term variability of Jupiter’s extended sodium nebula

Ground-based optical observations of D₁ and D₂ line emissions from Jupiter’s sodium nebula, which extend over several hundreds of jovian radii, were carried out at Mt. Haleakala, Maui, Hawaii using a wide field filter imager from May 19 to June 21, 2007. During this observation, the east-west asymmetry of the nebula with respect to the Io’s orbital motion was clearly identified. Particularly, the D₁+D₂ brightness on the western side of Jupiter is strongly controlled by the Io phase angle. The following scenario was developed to explain this phenomenon as follows: First, more ionospheric ions like NaX⁺, which are thought to produce fast neutral sodium atoms due to a dissociative recombination process, are expected to exist in Io’s dayside hemisphere rather than in the nightside one. Second, it is expected that more NaX⁺ ionospheric ions are picked up by the jovian co-rotating magnetic field when Io’s leading hemisphere is illuminated by the Sun. Third, the sodium atom ejection rate varies with respect to Io’s orbital position as a result of the first two points. Model simulations were performed using this scenario. The model results were consistent with the observation results, suggesting that Io’s ionosphere is expected to be controlled by solar radiation just like Earth.     

Precise estimation of pressure–temperature paths from zoned minerals using Markov random field modeling: theory and synthetic inversion

The chemical zoning profile in metamorphic minerals is often used to deduce the pressure–temperature (P–T) history of rock. However, it remains difficult to restore detailed paths from zoned minerals because thermobarometric evaluation of metamorphic conditions involves several uncertainties, including measurement errors and geological noise. We propose a new stochastic framework for estimating precise P–T paths from a chemical zoning structure using the Markov random field (MRF) model, which is a type of Bayesian stochastic method that is often applied to image analysis. The continuity of pressure and temperature during mineral growth is incorporated by Gaussian Markov chains as prior probabilities in order to apply the MRF model to the P–T path inversion. The most probable P–T path can be obtained by maximizing the posterior probability of the sequential set of P and T given the observed compositions of zoned minerals. Synthetic P–T inversion tests were conducted in order to investigate the effectiveness and validity of the proposed model from zoned Mg–Fe–Ca garnet in the divariant KNCFMASH system. In the present study, the steepest descent method was implemented in order to maximize the posterior probability using the Markov chain Monte Carlo algorithm. The proposed method successfully reproduced the detailed shape of the synthetic P–T path by eliminating appropriately the statistical compositional noises without operator’s subjectivity and prior knowledge. It was also used to simultaneously evaluate the uncertainty of pressure, temperature, and mineral compositions for all measurement points. The MRF method may have potential to deal with several geological uncertainties, which cause cumbersome systematic errors, by its Bayesian approach and flexible formalism, so that it comprises potentially powerful tools for various inverse problems in petrology.     

Induction of female‐to‐male sex change in a large protogynous fish,Choerodon schoenleinii

Most behavioral studies on hermaphroditic fishes have focused on small‐sized species, which are tractable for research. Although many species of large hermaphroditic fishes are important fishery resources, their proximate mechanisms (visual, chemical and/or behavioral cues) in the social regulation of sex change have not been determined. Determination of these would inform resource management and aquaculture. In order to get closer to understanding the proximate mechanisms underlying the social regulation of female‐to‐male sex change in large hermaphroditic fishes, this study reports situations that induced female‐to‐male sex change in black‐spot tuskfish, Choerodon schoenleinii, a species of large protogynous fish, in massive laboratory tanks. The situations differed in the possibility of male‐to‐female tactile contact and in the group sex ratio, enabling us to infer plausible proximate mechanisms underlying sex change induction. Tactile contact between individuals is suspected to be closely related to the incidence of female‐to‐male sex change in C. schoenleinii. Visual and chemical cues alone may be insufficient to inhibit such sex changes. Male‐to‐female tactile contact may have an important influence on female‐to‐male sex change, i.e., inhibition of this sex change, in this species. The effect of sex ratio of a social group on the incidence of sex change may be due to the relative frequency and intensity of male tactile contact with each female, which may vary with the number of females. In the absence of a dominant male, tactile contact among females may affect the incidence of sex change, as well as determine which individuals change sex.     

Effect of temperature on the methyl chloride production rate in a marine phytoplankton, <Emphasis Type="Italic">Phaeodactylum tricornutum</Emphasis>

Methyl halides such as methyl chloride (CH₃Cl) are known to be important carriers of halogen from the ocean to the atmosphere, and the halogens they release into the stratosphere by photolysis catalyze ozone depletion. Marine phytoplankton have been reported as a source of CH₃Cl, but the effects of environmental temperature on the CH₃Cl production by phytoplankton have not been investigated. In this study, we investigated the effects of temperature on the production of CH₃Cl in the culture of a marine diatom, Phaeodactylum tricornutum CCMP 630, incubated at 10, 15, 20, 25, and 30 °C. CH₃Cl concentrations in cultured samples were determined using purge and trap gas chromatograph–mass spectrometry. Phytoplankton growth was monitored by measuring the chlorophyll a concentrations. CH₃Cl production was observed for several weeks at four different temperatures ranging from 10 to 25 °C. The CH₃Cl production from P. tricornutum was increased with increasing temperature from 10 to 25 °C, and the maximum production rate for CH₃Cl was 0.21~0.26 μmol (g chlorophyll a)^?1 d^?1 at 25 °C, which was several times higher than that at 10 °C (~0.03 μmol (g chlorophyll a)^?1 d^?1). The Arrhenius equation was successfully used to characterize the effects of temperature on the production rates of CH₃Cl in the culture of P. tricornutum. Our results suggest that water temperature directly affects CH₃Cl production derived from P. tricornutum and that water temperature would be a significant factor for estimating the emissions of CH₃Cl from marine environments.     

Simulation of the Influence of Rate- and State-dependent Friction on the Macroscopic Behavior of Complex Fault Zones with the Lattice Solid Model

-- In order to understand the earthquake nucleation process, we need to understand the effective frictional behavior of faults with complex geometry and fault gouge zones. One important aspect of this is the interaction between the friction law governing the behavior of the fault on the microscopic level and the resulting macroscopic behavior of the fault zone. Numerical simulations offer a possibility to investigate the behavior of faults on many different scales and thus provide a means to gain insight into fault zone dynamics on scales which are not accessible to laboratory experiments. Numerical experiments have been performed to investigate the influence of the geometric configuration of faults with a rate- and state-dependent friction at the particle contacts on the effective frictional behavior of these faults. The numerical experiments are designed to be similar to laboratory experiments by Dieterich and Kilgore (1994) in which a slide-hold-slide cycle was performed between two blocks of material and the resulting peak friction was plotted vs. holding time. Simulations with a flat fault without a fault gouge have been performed to verify the implementation. These have shown close agreement with comparable laboratory experiments. The simulations performed with a fault containing fault gouge have demonstrated a strong dependence of the critical slip distance D_c on the roughness of the fault surfaces and are in qualitative agreement with laboratory experiments.