Interdecadal temperature variations in the North Pacific Central Mode Water simulated by an OGCM

The North Pacific Central Mode Water (CMW) is a water mass that forms in the Kuroshio-Oyashio Extension (KOE) region with characteristic low potential vorticity. Recent studies have suggested that the CMW, as low potential vorticity water, plays an important role in the adjustment of the subtropical gyre and subsurface variability on decadal to interdecadal timescales. We have forced a realistic ocean general circulation model (OGCM) with observed wind stress and sea surface temperature (SST) forcing to investigate the decadal variations of the CMW. Associated with the large atmospheric changes after the mid-1970s climate regime shift, the upper thermocline experiences a cooling as negative SST anomalies in the central North Pacific are subducted and advected southward. In addition to this thermodynamic response, the CMW’s path shifts anomalously eastward in response to anomalous Ekman pumping. This eastward shift of the core of the CMW produces a lowering of the isotherms, and a consequent warming, on the path of the CMW core. This warming partially counteracts the cooling associated with subducted surface anomalies, and it may be responsible for the reduced temperature variations at the climatological position of the CMW when both anomalous wind and heat fluxes are given. Lateral induction across the sloping bottom of the winter mixed layer in the KOE is critical to the formation of the low potential vorticity CMW. Coarse resolution models, which are widely used in climate modeling, underestimate the horizontal gradient of the mixed layer depth and form only a weak CMW or none at all. We have conducted a coarse resolution experiment with the same OGCM, showing that the subsurface response is much reduced. In particular, there is no dynamic warming in the CMW and the thermodynamic response to the SST cooling dominates. The resultant total response differs substantially from that in the finer resolution run where a strong CMW forms. This sensitivity to the model resolution corroborates the important dynamical role that the CMW may play with its distinctive low potential vorticity character and calls for its improved simulation.     

Influence of bedrock groundwater on streamflow characteristics in a volcanic catchment

Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km²) and the Hosotani river (SR) catchment (4.0 km²) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 10³ years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km² and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km² at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.     

Crystal structures of Zn2SiO4 III and IV synthesized at 6.5–8 GPa and 1,273 K

We report the crystal structures determined under ambient condition for two Zn₂SiO₄ polymorphs synthesized at 6.5 GPa and 1,273 K (phase III) and 8 GPa and 1,273 K (phase IV) and also compare their ²⁹Si MAS NMR spectroscopic characteristics with those of other Zn₂SiO₄ polymorphs (phases I, II and V). Electron microprobe analysis revealed that both of phases III and IV are stoichiometric like the lower-pressure polymorphs (phases I and II), contrary to previous report. The crystal structures were solved using an ab initio structure determination technique from synchrotron powder X-ray diffraction data utilizing local structural information from ²⁹Si MAS NMR as constraints and were further refined with the Rietveld technique. Phase III is orthorhombic (Pnma) with a = 10.2897(5), b = 6.6711(3), c = 5.0691(2) Å. It is isostructural with the high-temperature (Zn_1.1Li_0.6Si_0.3)SiO₄ phase and may be regarded as a ‘tetrahedral olivine’ type that resembles the ‘octahedral olivine’ structure in the (approximately hexagonally close packed) oxygen arrangement and tetrahedral Si positions, but has Zn in tetrahedral, rather than octahedral coordination. Phase IV is orthorhombic (Pbca) with a = 10.9179(4), b = 9.6728(4), c = 6.1184(2) Å. It also consists of tetrahedrally coordinated Zn and Si and features unique edge-shared Zn₂O₆ dimers. The volumes per formula under ambient condition for phases III and IV are both somewhat larger than that of the lower-pressure polymorph, phase II, suggesting that the two phases may have undergone structural changes during temperature quench and/or pressure release.     

Comparison of the Clay Fraction of Ariake Clay Determined by Japanese and ASTM Standards

This study compares the clay fraction percentage determined by Japanese standard JIS A1204/JGS 0131 and ASTM standard D422-63 for the clay samples obtained from the surface of sea bottom sediments in Ariake Bay, Japan. These two standards differ in the amount of dispersant to be added for the dispersion of soil suspensions. The Japanese and ASTM standards suggest adding sodium hexametaphosphate solution as the dispersant so that the final concentration of the dispersant in soil suspension for hydrometer test becomes 2 and 5 g/L, respectively. The test results indicated that the treatment by the Japanese standard gave less dispersion in the soil suspension compared to the ASTM standard, and hence resulted in the underestimation of clay fraction percentage of all the samples.     

Recent drastic changes in Lake Biwa bio-communities, with special attention to exploitation of the littoral zone

A change for the worse in water quality in Lake Biwa has led to musty odor of tap water, freshwater red tide and other water blooms by sudden propagations of nuisance planktonic algae since 1970. Further, some endemic and commercially important species of fish and molluscs decreased drastically in the last 10–30 years. These events seemed to be closely related to drainage of many small lakes channeled to Lake Biwa as part of an agricultural policy after World War 11, and to senseless exploitation of the littoral zone in the 1970s and 1980s as a link in the Comprehensive Development Project of Lake Biwa. Simplification of its littoral zone has led to a deterioration in its ecosystem through physical destruction of spawning habitats and increase in eutrophication.     

Influence of various factors on the difference in the liquid limit values determined by Casagrande’s and fall cone method

As there are many correlations linking the liquid limit directly or indirectly with various engineering properties of the soil, the accurate determination of the liquid limit is quite essential. Generally, two methods, i.e. Casagrande’s and fall cone are adopted to determine the liquid limit of soil. Research was carried out to study the influence of the properties of bentonite and the presence of the salt solution on the liquid limit values of soil-bentonite mixtures determined by the Casagrande’s and fall cone methods. The results showed that irrespective of the presence of the type of bentonite or salt solution, a higher value of the liquid limit was obtained by the Casagrande’s method as compared to the fall cone method. However, the difference between the two methods decreased with the decrease in the liquid limit, clay fraction, specific surface area and free swelling capacity of the bentonite present in the mixture. Similarly, the difference in the liquid limit values obtained by both these methods is reduced with an increase in the salt concentration.     

Geoarchaeological investigations at the upper Paleolithic site of Kamihoronai‐Moi,Hokkaido, Japan

In order to better understand modern human behavioral variability in Hokkaido, Japan, we consider the geoarchaeology of the Kamihoronai‐Moi site in terms of its geochronology, stratigraphy, depositional environments, and post‐depositional disturbances. A Paleolithic component is stratigraphically situated between the Eniwa‐a (15,000–17,000 ¹⁴C yr B.P.) and the Tarumae‐d (8000–9000 ¹⁴C yr B.P.) tephras. Moreover, six AMS ¹⁴C ages on charcoal from a Pleistocene‐aged hearth feature are between 14,400 and 14,800 ¹⁴C yr B.P. Quantitative examinations of patterns in artifact distributions show a low degree of vertical and horizontal displacement of chipped‐stone artifacts, suggesting that post‐depositional movement of the cultural material was insufficient to disrupt the original pattern of artifact distribution. © 2009 Wiley Periodicals, Inc.     

Effect of salt of various concentrations on liquid limit,and hydraulic conductivity of different soil-bentonite mixtures

Effect of the various concentrations of NaCl and CaCl₂ on the four different soil-bentonite mixtures has been evaluated. The results show that the liquid limit of the mixtures decreases with an increase in the salt concentration. Liquid limit decreased significantly with an increase in CaCl₂ concentration from 0 to 0.1 N. However, a further increase in the concentration did not produce any significant decrease in liquid limit. A quite opposite trend was observed for the NaCl solution. An increase in NaCl concentration from 0 to 0.1 N did not produce any major decrease in the liquid limit, but a further increase in concentration from 0.1 to 1 N decreased the liquid limit significantly. Consolidation tests were carried out on the mixtures to evaluate the effect of mineralogical composition of the bentonite on the hydraulic conductivity (k) of the mixture in the presence of various salts concentrations. The k for any mixtures was found to be decreasing with decrease in the salt concentration. At relatively low concentration, Ca²⁺ had more effect on the k in comparison to the same concentration of Na⁺. However, at 1 N of NaCl and CaCl₂ almost an equal value of k was observed. A comparison of the performance of four bentonites showed that the mixture with bentonite having highest exchangeable sodium percentage (ESP) exhibited the lowest k when permeated with de-ionized (DI) water, however, k increased with an increase in the salt concentration. Similarly, mixture with a bentonite of lower ESP exhibited a higher k with DI water but with the increase in the salt concentration alteration in the k, compared to all other mixtures, was relatively less.