Presence of high nitrate to phosphate ratio subsurface water in the Tsushima Strait during summer

To identify water with an excess nitrate concentration to phosphate ratio and its potential source, the nutrient concentrations in the Tsushima Strait (TSS) were investigated over ten cruises in August and September 2007–2014, excluding 2010. On the basis of the Redfield ratio, water with an excess nitrate concentration of >1 μM (positive ExNOx water) was identified below the surface mixed layer during four cruises in 2011–2013. Positive ExNOx water was present mainly in less-saline (<34) waters with a density of 22–25 σ _θ , and 25–75 m depth. However, in August 2012, positive ExNOx was detected in dense (25–25.5 σ _θ ) and deep (50–110 m depth) waters near the salinity maximum, although the salinity during this period was significantly lower than that in other years. The horizontal length of positive ExNOx water was >100 km across the TSS during two cruises in August 2012 and September 2013, respectively. According to multi-regression analysis conducted on the silicate concentration, temperature, and salinity, the silicate concentration was increased in the less-saline subsurface water. The required amount of original freshwater was 10^8–9 m³ day^?1 based on the excess nitrate concentration. This evidence indicates that the positive ExNOx water originated from large river waters such as the Changjiang. Thus, discharged water from the rivers of the East Asia is contributing to the increased N:P ratio in the Tsushima Warm Current, southern Japan Sea.     

1-G model tests and hollow cylindrical torsional shear experiments on seismic residual displacements of fill dams from the viewpoint of seismic performance-based design

This paper concerns technological efforts for the general acceptance of performance-based seismic design principle of geotechnical structures. Among many problems to be solved, a particular emphasis was placed on the prediction of residual displacement that remains after a strong earthquake. Because of the complicated behavior of soils undergoing cyclic loading, the prediction is often either complicated/costly or not very accurate. The aim of this study is to examine the capability of existing prediction measures and propose some future scopes. To achieve these goals, shaking table model tests and laboratory shear tests were conducted by taking fill dams as an example target structure. It is concluded that performance-based design is possible if the necessary time and cost are spent and if the required accuracy of prediction is reasonable.     

Experimental study on the impact fragmentation of core-mantle bodies: Implications for collisional disruption of rocky planetesimals with sintered core covered with porous mantle

Impact experiments of inhomogeneous targets such as layered bodies consisting of a dense core and porous mantle were conducted to clarify the effect of the layered structure on impact strength. The layered structure of small bodies could be the result of the thermal evolution of planetesimals in the solar nebula. So, the impact disruption of thermally evolved bodies with core-mantle structure is important for the origin of small bodies such as asteroids. We investigated the impact strength of rocky-layered bodies with porous mantle-sintered cores, which could be formed at an initial stage of thermal evolution. Spherical targets composed of soda-lime glass or quartz core and porous gypsum mantle were prepared as an analog of small bodies with a core-mantle structure, and the internal structure was changed. A nylon projectile was impacted at the impact velocity from 1 to 5 km/s. The impact strength of the core-mantle targets decreases with the increase of the core/target mass ratio (RCM) in the specific energy range from 1×¹⁰³ to 4×¹⁰⁴ J/kg. We observed two distinct destruction modes characterized by the damage to the core: one shows a damaged core and fractured mantle, and the other shows an intact core and broken mantle. The former mode was usually observed with increasing RCM, and the boundary condition of the core destruction () was experimentally found to be , where is the specific energy required to disrupt a glass core. From this empirical equation, it might be possible to discuss the destruction conditions of a thermally evolved body with a porous mantle-sintered core structure. We speculate that the impact strength of the body could be significantly reduced with the progress of internal evolution at the initial stage of thermal evolution.     

The noble gas systematics of late-orogenic H2O-CO2 fluids, Mt Isa, Australia

The noble gases (He, Ne, Ar, Kr and Xe) are powerful geochemical tracers because they have distinctive isotopic compositions in the atmosphere, crust and mantle. This study illustrates how noble gases can be used to trace fluid origins in high-temperature metamorphic and mineralising environments; and at the same time provides new information on the composition of noble gases in deeper parts of the crust than have been sampled previously.We report data for H₂O and CO₂ fluid inclusions trapped at greenschist to amphibolite facies metamorphic conditions associated with three different styles of mineralisation and alteration in the Proterozoic Mt Isa Inlier of Australia. Sulphide fluid inclusions are dominated by crustal ⁴He. However, co-variations in fluid inclusion ²⁰Ne/²²Ne, ²¹Ne/²²Ne, ⁴⁰Ar/³⁶Ar and ¹³⁶Xe/¹³⁰Xe indicate noble gases were derived from three or more reservoirs. In most cases, the fluid inclusions elemental noble gas ratios (e.g. Ne/Xe) are close to the ranges expected in sedimentary and crystalline rocks. However, the elemental ratios have been modified in some of the samples providing evidence for independent pulses of CO_2, and interaction of CO₂ with high-salinity aqueous fluids.Compositional variation is attributed to mixing of: (i) magmatic fluids (or deeply sourced metamorphic fluids) characterised by basement-derived noble gases with ²⁰Ne/²²Ne ∼ 8.4, ²¹Ne/²²Ne ∼ 0.4, ⁴⁰Ar/³⁶Ar ∼ 40,000 and ¹³⁶Xe/¹³⁰Xe ∼ 8; (ii) basinal-metamorphic fluids with a narrow range of compositions including near-atmospheric values and (iii) noble gases derived from the meta-sedimentary host-rocks with ²⁰Ne/²²Ne ∼ 8-9.8, ²¹Ne/²²Ne < 0.1, ⁴⁰Ar/³⁶Ar < 2500 and ¹³⁶Xe/¹³⁰Xe ∼ 2.2.These data provide the strongest geochemical evidence available for the involvement of fluids from two distinct geochemical reservoirs in Mt Isa’s largest ore deposits. In addition the data show how noble gases in fluid inclusions can provide information on fluid origins, the composition of the crust’s major lithologies, fluid-rock interactions and fluid-fluid mixing or immiscibility processes.     

Relationship between sinking organic matter and minerals in the shallow zone of the western Subarctic Pacific

We used time-series sediment trap data for four major components, organic matter and ballast minerals (CaCO₃, opal, and lithogenic matter) from 150, 540, and 1000 m in the western subarctic Pacific (WSAP), where opal is the predominant mineral in sinking particles, to develop four simple models for settling particles, including the “ballast model”. The ballast model is based on the concept that most of the organic matter “rain” in the deep sea is carried by the minerals. These four models are designed to simultaneously reproduce the flux of each major component of settling particles at 540 and 1000 m by using the data for each component at 150 m as initial values. Among the four models, the ballast model, which considers the sinking velocity increase with depth, was identified as the best using the Akaike information criterion as a measure of the model fit to data. This model successfully reproduced the flux of organic matter at 540 and 1000 m, indicating that the ballast model concept works well in the shallow zone of the WSAP on a seasonal timescale. This also suggests that ballast minerals not only physically protect the organic matter from degradation during the settling process but also enhance the sinking velocity and reduce the degree of decomposition.     

Estimating of gas transfer velocity using triple isotopes of dissolved oxygen

The atmosphere-ocean exchange of climatically important gases is determined by the transfer velocity (k) and concentration gradient across the interface. Based on observations in the northwestern subarctic Pacific and Sagami Bay, we report here the results of the first ever application of the natural abundance of triple isotopes of dissolved oxygen (¹⁶O, ¹⁷O and ¹⁸O) for direct estimation of k and propose a new relationship with wind speed. The k values estimated from nighttime variations in oxygen isotopes are found to be higher than the direct estimations at low wind speed (<5 m s⁻¹) and lower at high wind speeds (>13 m s⁻¹) and showed significant spatial variability. The method presented here can be used to derive seasonal and spatial variations in k and the influence of surface conditions on the value, leading to improved estimates of biogenic/anthropogenic gas exchange at the air-sea interface.     

Statistical Estimation of the Production of Cosmic-Ray-Induced Nuclides in Meteorites*

Abstract— Among iron meteorites there is a simple relationship estimating, with two parameters, the production rates of spallation products of mass A, that range in ΔA from 2 to 36 (Cr to Ne), where ΔA is 56 — A. This paper describes further applications of this relation, extending it to chondrites, in terms of the effective ΔA. It is possible to systematize the production of common products in chondrites such as ³He, ²⁶Al,²²Ne, ²¹Ne and ³⁸Ar. For this purpose, data on products determined in the metal phases of chondrites are useful in correlating stones to irons. For general application to stone meteorites, statistical treatments for multielement target systems are employed, except for the lowest energy reaction products. Statistical methods for spallation products are thus now applicable for all iron and stone meteorites.     

Simulated biogeochemical responses to iron enrichments in three high nutrient, low chlorophyll (HNLC) regions

To fill temporal gaps in iron-enrichment experimental data and gain further understanding of marine ecosystem responses to iron enrichments, we apply a fifteen-compartment ecosystem model to three iron-enrichment sites, namely SEEDS (the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study; 48.5°N, 165°E) in the western North Pacific, SOIREE (the Southern Ocean Iron RElease Experiment; 61°S, 140°E) in the Southern Ocean, and IronExII (the second mesoscale iron enrichment experiment; 3.5°S, 104°W) in the Equatorial Pacific. The ecological effects of iron in the model are represented by changing two photosynthetic parameters during the iron-enrichment period. The model results successfully reproduce the observed biogeochemical responses inside and outside the iron patch at each site, such as rapid increases in plankton biomass and biological productivity, and decreases in surface nutrients and pCO₂, inside the patch. However, the modeled timing and magnitude of changes differ among the sites because of differences in both physical environments and plankton species. After the iron enrichment, the diatom productivity is strongly controlled by light at SOIREE and by silicate at IronExII and SEEDS. Light limitation due to self-shading by the phytoplankton is significant during the bloom at all sites. Sensitivity analysis of the model results to duration of the iron enrichment reveals that long-term multiple infusions over more than a week would not be effective at SEEDS because of strong silicate limitation on diatom growth. Sensitivity of the model to water temperature shows that export production is higher at lower temperatures, because of slower recycling of particulate organic carbon. Therefore, the e-ratio (the ratio of export production to primary production) is inversely correlated with temperature, and the relationship can be described with a linear function. Through this study, we conclude that ecosystem modeling is a powerful tool to help design future iron-enrichment experiments and observational plans.